Crystals as molecules: Postsynthesis covalent functionalization of zeolitic imidazolate frameworks

Journal of the American Chemical Society

Volumn 130, Issue 38, 2008, Pages 12626-12627

  Morris, William ^a   Doonan, Christian J ^a   Furukawa, Hiroyasu ^a   Banerjee, Rahul ^a   Yaghi, Omar M ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

IMIDAZOLE DERIVATIVE; N,N DIMETHYLFORMAMIDE; NATURAL PRODUCT; POLYMER; TRIETHYLAMINE;

ARTICLE; CHEMICAL MODIFICATION; COVALENT BOND; CRYSTAL STRUCTURE; DRUG SYNTHESIS; ELECTROSPRAY MASS SPECTROMETRY; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLARIZATION; X RAY DIFFRACTION;

ALDEHYDES; CRYSTALLIZATION; IMIDAZOLES; MODELS, MOLECULAR; NITRATES; THERMOGRAVIMETRY; X-RAY DIFFRACTION; ZEOLITES; ZINC COMPOUNDS;

EID: 52449121242     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja805222x     Document Type: Article

References (16)

1. (a) Seo, J. S.; Whang, D.; Lee, H.; Jun, S. I.; Oh, J.; Jeon, Y. J.; Kim, K. Nature 2000, 404, 982.
2. (b) Wang, Z.; Cohen, S. M. J. Am. Chem. Soc. 2007, 129, 12368.
3. (c) Tanabe, K. K.; Wang, Z.; Cohen, S. M. J. Am. Chem. Soc. 2008, 130, 8508.
4. (d) Costa, J. S.; Gamez, P.; Black, C. A.; Roubeau, O.; Teat, S. J.; Reedijk, J. Eur. J. Inorg. Chem. 2008, 1551.
5. (e) Wang, Z.; Cohen, S. M. Angew. Chem., Int. Ed. 2008, 47, 4699.
6. (f) Ingelson, M. J.; Barrio, J. P.; Guilbaud, J.-B.; Khimyak, Y. Z.; Rosseinsky, M. J. Chem. Commun. 2008, 23, 2680.
7. (g) Dugan, E.; Wang, Z.; Okamura, M.; Medina, A.; Cohen, S. M. Chem. Commun. 2008, 29, 3366.
8. For synthetic modification of guests within a framework scaffold see: Haneda, T.; Kawano, M.; Kawamichi, T.; Fujita, M. J. Am. Chem. Soc. 2008, 130, 1578.
9. (a) Banerjee, R.; Phan, A.; Wang, B.; Knobler, C.; Furukawa, H.; O'Keeffe, M.; Yaghi, O. M. Science 2008, 319, 939.
10. (b) Park, K. S.; Ni, Z.; Côté, A. P.; Choi, J. Y.; Huang, R. D.; Uribe-Romo, F. J.; Chae, H. K.; O'Keeffe, M.; Yaghi, O. M. Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 10186.
11. Expressed by J. Fraser Stoddart in reference to reticular chemistry of MOFs, Reading, U.K. (June 26, 2008).
12. 2Zn: C, 37.60; H, 2.37; N, 21.92%. Found; C, 37.63; H, 2.76; N, 20.48%.
13. See Supporting Information for full experimental details.
14. int = 0.0297) led to R1 = 0.1447 [I > 2σ(I)], wR2 = 0.3474 (all data) and GOF = 1.836; CCDC 693596.
15. Three letter designations are assigned to net topologies as in the Reticular Chemistry Structure Resource; http://rcsr.anu.edu.au.
16. 2 software (version 4.2; MatSci; Accelrys, Inc., San Diego) and on the single crystal X-ray structure of ZIF-90 with guests removed and disorder effects averaged.