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We are well aware of the high toxicity of cadmium-containing compounds. The use of cadmium in this system leads to well-crystallized compounds, which assist in deriving chemical trends. For potential applications, cadmium can often be replaced by other divalent cations, such as calcium
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We are well aware of the high toxicity of cadmium-containing compounds. The use of cadmium in this system leads to well-crystallized compounds, which assist in deriving chemical trends. For potential applications, cadmium can often be replaced by other divalent cations, such as calcium.
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24
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CCDC 641071 (A), 641072 (B), and 641073 (C) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. Since compounds B and C were discovered previously in a HT experiment at higher temperature, detailed characterization will be published elsewhere.
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CCDC 641071 (A), 641072 (B), and 641073 (C) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. Since compounds B and C were discovered previously in a HT experiment at higher temperature, detailed characterization will be published elsewhere.
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34548735059
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Rodriguez
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The structure of A was refined with Fullprof2k using the Winplotr software package a J, Toulouse, France
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The structure of A was refined with Fullprof2k using the Winplotr software package a) J. Rodriguez, Collected Abstracts of Powder Diffraction Meeting, Toulouse, France, 1990, p. 127:
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(1990)
Collected Abstracts of Powder Diffraction Meeting
, pp. 127
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26
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0035184477
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T. Roisnel, J. Rodriguez-Carvajal, Mater. Sci. Forum 2001. 378, 118, The structure of the isotypic calcium compound[10] was used as starting model. Crystal data: M, 824.53 g mol-1, monoclinic P21/c, a, 16.932(1, b, 7.293(1, c, 13.905(1) Å β, 113.99(1)°, V= 1568.6(3) × 106 pm3, Z, 2, ρcalcd, 3.491, Rp, 10.7, R wp, 13.1, Rexp, 3.45, RF, 4.92, RBragg, 6.11; λCuKα1, 154.06pm; 2θ range: 3.0-70.0°; number of reflections: 725; number of atoms: 24; number of structural parameters: 69; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information
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Kα1) = 154.06pm; 2θ range: 3.0-70.0°; number of reflections: 725; number of atoms: 24; number of structural parameters: 69; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information.
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27
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0036895497
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The structure of B was solved from powder data using the FOX program (V. Favre-Nicolin, R. Cerny, J Appl. Crystallogr. 2002, 35, 734) and refined with Fullprof2k using the Winplotr software package, 41] Crystal data: M, 760.53 g moL-1, monoclinic P21,/c, a, 14.913(1, b, 8.702(1, c, 10.477(1) Å β, 95.60(1)°, V= 1353.0(2) × 106 pm3, Z, 2, ρcalcd, 1.867, R p, 19.3, Rwp, 18.4, Rexp, 14.75, RF, 6.97, RBragg, 6.42; λ Cu Kα1, 154.06 pm; 2θ range: 4.0-80.0°; number of reflections: 1204; number of atoms: 22; number of structural parameters: 62; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information
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Kα1) = 154.06 pm; 2θ range: 4.0-80.0°; number of reflections: 1204; number of atoms: 22; number of structural parameters: 62; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information.
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28
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34548771546
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The structure of C was refined with Fullprof2k using the Winplotr software package.[14] The structure of the isotypic calcium compound[10] was used as starting model. Crystal data: M, 467.58 g mol-1, monoclinic P21/n, a, 5.654(1, b, 7.874(1, c, 31.532(1) Å, β, 94.58(1)°, V= 1399.3(3) × 106 pm3, Z, 4, ρcalcd, 2.148, Rp, 14.1, Rwp;, 15.0, Rexp, 4.83, R F, 10.6, RBragg, 9.44; λCu Kα1, 154.06 pm; 2θ range: 4.0-80.0°; number of reflections: 950; number of atoms: 23; number of structural parameters: 69; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information
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Kα1) = 154.06 pm; 2θ range: 4.0-80.0°; number of reflections: 950; number of atoms: 23; number of structural parameters: 69; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information.
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29
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34548806756
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Due to the sensitivity of the position of the reflections in the powder pattern of D to the water content, all attempts to index the powder pattern failed. The composition is based on energydispersive X-ray EDX, elemental, and thermogravimetric analyses
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Due to the sensitivity of the position of the reflections in the powder pattern of D to the water content, all attempts to index the powder pattern failed. The composition is based on energydispersive X-ray (EDX), elemental, and thermogravimetric analyses.
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30
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34548766359
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3; F(30) = 44.8 (0.009, 71).
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3; F(30) = 44.8 (0.009, 71).
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31
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34548720123
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No structure could be determined so far. The composition was derived from EDX, elemental, and thermogravimetric analyses
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No structure could be determined so far. The composition was derived from EDX, elemental, and thermogravimetric analyses.
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32
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34548745527
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M. Forster, A. R. Burbank, C. Livage, G. Férey, A. K. Cheetham, Chem.Commun. 2004, 368.
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(2004)
Chem.Commun
, pp. 368
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Forster, M.1
Burbank, A.R.2
Livage, C.3
Férey, G.4
Cheetham, A.K.5
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