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Volumn 46, Issue 36, 2007, Pages 6857-6860

Implementation of a temperature-gradient reactor system for high-throughput investigation of phosphonate-based inorganic-organic hybrid compounds

Author keywords

Combinatorial chemistry; High throughput screening; Hydrothermal synthesis; Inorganic organic hybrid compounds; Phosphonates

Indexed keywords

COLOR; CRYSTALLIZATION; HYBRID MATERIALS; HYDROTHERMAL SYNTHESIS;

EID: 34548742317     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200701575     Document Type: Article
Times cited : (76)

References (33)
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    • (1998) Chem. Int. Ed , vol.37 , pp. 3369
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    • Angew. Chem. Int. Ed. 1999, 38, 2891-2894.
    • (1999) Chem. Int. Ed , vol.38 , pp. 2891-2894
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    • Angew. Chem. Int. Ed. 2005, 44, 7608.
    • (2005) Chem. Int. Ed , vol.44 , pp. 7608
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    • We are well aware of the high toxicity of cadmium-containing compounds. The use of cadmium in this system leads to well-crystallized compounds, which assist in deriving chemical trends. For potential applications, cadmium can often be replaced by other divalent cations, such as calcium
    • We are well aware of the high toxicity of cadmium-containing compounds. The use of cadmium in this system leads to well-crystallized compounds, which assist in deriving chemical trends. For potential applications, cadmium can often be replaced by other divalent cations, such as calcium.
  • 24
    • 34548739345 scopus 로고    scopus 로고
    • CCDC 641071 (A), 641072 (B), and 641073 (C) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. Since compounds B and C were discovered previously in a HT experiment at higher temperature, detailed characterization will be published elsewhere.
    • CCDC 641071 (A), 641072 (B), and 641073 (C) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. Since compounds B and C were discovered previously in a HT experiment at higher temperature, detailed characterization will be published elsewhere.
  • 25
    • 34548735059 scopus 로고
    • Rodriguez
    • The structure of A was refined with Fullprof2k using the Winplotr software package a J, Toulouse, France
    • The structure of A was refined with Fullprof2k using the Winplotr software package a) J. Rodriguez, Collected Abstracts of Powder Diffraction Meeting, Toulouse, France, 1990, p. 127:
    • (1990) Collected Abstracts of Powder Diffraction Meeting , pp. 127
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    • 0035184477 scopus 로고    scopus 로고
    • T. Roisnel, J. Rodriguez-Carvajal, Mater. Sci. Forum 2001. 378, 118, The structure of the isotypic calcium compound[10] was used as starting model. Crystal data: M, 824.53 g mol-1, monoclinic P21/c, a, 16.932(1, b, 7.293(1, c, 13.905(1) Å β, 113.99(1)°, V= 1568.6(3) × 106 pm3, Z, 2, ρcalcd, 3.491, Rp, 10.7, R wp, 13.1, Rexp, 3.45, RF, 4.92, RBragg, 6.11; λCuKα1, 154.06pm; 2θ range: 3.0-70.0°; number of reflections: 725; number of atoms: 24; number of structural parameters: 69; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information
    • Kα1) = 154.06pm; 2θ range: 3.0-70.0°; number of reflections: 725; number of atoms: 24; number of structural parameters: 69; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information.
  • 27
    • 0036895497 scopus 로고    scopus 로고
    • The structure of B was solved from powder data using the FOX program (V. Favre-Nicolin, R. Cerny, J Appl. Crystallogr. 2002, 35, 734) and refined with Fullprof2k using the Winplotr software package, 41] Crystal data: M, 760.53 g moL-1, monoclinic P21,/c, a, 14.913(1, b, 8.702(1, c, 10.477(1) Å β, 95.60(1)°, V= 1353.0(2) × 106 pm3, Z, 2, ρcalcd, 1.867, R p, 19.3, Rwp, 18.4, Rexp, 14.75, RF, 6.97, RBragg, 6.42; λ Cu Kα1, 154.06 pm; 2θ range: 4.0-80.0°; number of reflections: 1204; number of atoms: 22; number of structural parameters: 62; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information
    • Kα1) = 154.06 pm; 2θ range: 4.0-80.0°; number of reflections: 1204; number of atoms: 22; number of structural parameters: 62; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information.
  • 28
    • 34548771546 scopus 로고    scopus 로고
    • The structure of C was refined with Fullprof2k using the Winplotr software package.[14] The structure of the isotypic calcium compound[10] was used as starting model. Crystal data: M, 467.58 g mol-1, monoclinic P21/n, a, 5.654(1, b, 7.874(1, c, 31.532(1) Å, β, 94.58(1)°, V= 1399.3(3) × 106 pm3, Z, 4, ρcalcd, 2.148, Rp, 14.1, Rwp;, 15.0, Rexp, 4.83, R F, 10.6, RBragg, 9.44; λCu Kα1, 154.06 pm; 2θ range: 4.0-80.0°; number of reflections: 950; number of atoms: 23; number of structural parameters: 69; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information
    • Kα1) = 154.06 pm; 2θ range: 4.0-80.0°; number of reflections: 950; number of atoms: 23; number of structural parameters: 69; number of profile parameters: 14. The final Rietveld plot is given in the Supporting Information.
  • 29
    • 34548806756 scopus 로고    scopus 로고
    • Due to the sensitivity of the position of the reflections in the powder pattern of D to the water content, all attempts to index the powder pattern failed. The composition is based on energydispersive X-ray EDX, elemental, and thermogravimetric analyses
    • Due to the sensitivity of the position of the reflections in the powder pattern of D to the water content, all attempts to index the powder pattern failed. The composition is based on energydispersive X-ray (EDX), elemental, and thermogravimetric analyses.
  • 30
    • 34548766359 scopus 로고    scopus 로고
    • 3; F(30) = 44.8 (0.009, 71).
    • 3; F(30) = 44.8 (0.009, 71).
  • 31
    • 34548720123 scopus 로고    scopus 로고
    • No structure could be determined so far. The composition was derived from EDX, elemental, and thermogravimetric analyses
    • No structure could be determined so far. The composition was derived from EDX, elemental, and thermogravimetric analyses.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.