-
3
-
-
70349957789
-
-
[6] species, there has been no evidence to date for monomeric radicals.
-
[6] species, there has been no evidence to date for monomeric radicals.
-
-
-
-
7
-
-
0032381380
-
-
A. Ecker, E. Baum, M. A. Friesen, M. A. Junker, C. Üffing, R. Koppe, H. Schnöckel, Z. Anorg. Allg. Chem. 1998, 624 513.
-
(1998)
Z. Anorg. Allg. Chem.
, vol.624
, pp. 513
-
-
Ecker, A.1
Baum, E.2
Friesen, M.A.3
Junker, M.A.4
Üffing, C.5
Koppe, R.6
Schnöckel, H.7
-
8
-
-
70349973328
-
-
2Al-bridged bonding) were to be trapped.
-
2Al-bridged bonding) were to be trapped.
-
-
-
-
11
-
-
55249109776
-
-
T. Pankewitz, W. Klopper, P. Henke, H. Schnöckel, Eur. J. Inorg. Chem. 2008, 4879.
-
(2008)
Eur. J. Inorg. Chem.
, pp. 4879
-
-
Pankewitz, T.1
Klopper, W.2
Henke, P.3
Schnöckel, H.4
-
12
-
-
70349954674
-
-
Complex Math Equation
-
Complex Math Equation
-
-
-
-
14
-
-
70349973330
-
-
At the same time, an amorphous colorless solid is formed that makes the separation of the green crystals challenging.
-
At the same time, an amorphous colorless solid is formed that makes the separation of the green crystals challenging.
-
-
-
-
15
-
-
0035913763
-
-
C Klemp, M. Bruns, J. Gauss, U. Häussermann, G. Stößer, L. Van Wüllen, M. Jansen, H. Schnöckel, J. Am. Chem. Soc. 2001, 123 9099.
-
(2001)
J. Am. Chem. Soc.
, vol.123
, pp. 9099
-
-
Klemp, C.1
Bruns, M.2
Gauss, J.3
Häussermann, U.4
Stößer, G.5
Van Wüllen, L.6
Jansen, M.7
Schnöckel, H.8
-
16
-
-
70349961375
-
-
The computational results, also employing further functionals and basis sets, are reported in great detail in Ref. [9]. Even shorter Al-Al distances are calculated with other functionals.
-
The computational results, also employing further functionals and basis sets, are reported in great detail in Ref. [9]. Even shorter Al-Al distances are calculated with other functionals.
-
-
-
-
20
-
-
0000351951
-
-
C. Klemp, G. Stößer, I. Krossing, H. Schnöckel, Angew. Chem. 2000, 112 3834
-
(2000)
Angew. Chem.
, vol.112
, pp. 3834
-
-
Klemp, C.1
Stößer, G.2
Krossing, I.3
Schnöckel, H.4
-
22
-
-
70349959778
-
-
[17]
-
[17]
-
-
-
-
25
-
-
70349973342
-
-
3 is formed under these conditions by continuous dispro-portionation and precipitation of solid Al.
-
3 is formed under these conditions by continuous dispro-portionation and precipitation of solid Al.
-
-
-
-
26
-
-
67849116113
-
-
P. Henke, M. Huber, J. Steiner, K. Bowen, B. Eichhorn, H. Schnöckel, J. Am. Chem. Soc. 2009, 131 5698.
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 5698
-
-
Henke, P.1
Huber, M.2
Steiner, J.3
Bowen, K.4
Eichhorn, B.5
Schnöckel, H.6
-
27
-
-
70349928538
-
-
[21]
-
[21]
-
-
-
-
28
-
-
70349967580
-
-
The elongation of an existing Al-Al s bond (e.g. in 5) and subsequent formation of compound 1 is not possible from a thermodynamic point of view.
-
The elongation of an existing Al-Al s bond (e.g. in 5) and subsequent formation of compound 1 is not possible from a thermodynamic point of view.
-
-
-
-
29
-
-
70349939275
-
-
[26]
-
[26] These authors attribute the Ga-H bond formation to hydrogen abstraction from the solvent by radical intermediates under their drastic reaction conditions.
-
-
-
-
32
-
-
43049098067
-
-
P. Yang, R. Koppe, T. Duan, J. Hartig, G. Hadiprono, B. Pilawa, I. Keilhauer, H. Schnöckel, Angew. Chem. 2007, 119 3650
-
(2007)
Angew. Chem.
, vol.119
, pp. 3650
-
-
Yang, P.1
Koppe, R.2
Duan, T.3
Hartig, J.4
Hadiprono, G.5
Pilawa, B.6
Keilhauer, I.7
Schnöckel, H.8
-
34
-
-
79051469458
-
-
S. D. Köhler, B. Pilawa, D. S. d. Jauregui, G Fischer, R. Koppe, A. Schnepf, H. Schnöckel, E. Dormann, EPL 2008, 82 37002.
-
(2008)
EPL
, vol.82
, pp. 37002
-
-
Köhler, S.D.1
Pilawa, B.2
Jauregui, D.S.D.3
Fischer, G.4
Koppe, R.5
Schnepf, A.6
Schnöckel, H.7
Dormann, E.8
-
35
-
-
70349975489
-
-
[9]
-
[9]
-
-
-
-
39
-
-
0035969759
-
-
a) W. W. Schoeller, C. Begemann, E. Niecke, D Gudat, J. Phys. Chem. A 2001, 105 10731
-
(2001)
J. Phys. Chem. A
, vol.105
, pp. 10731
-
-
Schoeller, W.W.1
Begemann, C.2
Niecke, E.3
Gudat, D.4
-
40
-
-
0001375705
-
-
E. Niecke, A. Fuchs, F. Baumeister, M. Nieger, W. W. Schöller, Angew. Chem. 1995, 107 640
-
(1995)
Angew. Chem.
, vol.107
, pp. 640
-
-
Niecke, E.1
Fuchs, A.2
Baumeister, F.3
Nieger, M.4
Schöller, W.W.5
-
44
-
-
49449095454
-
-
a) A. Rodriguez, G. Fuks, J.-B. Bourg, D. Bourissou, F. S. Tham, G. Bertrand, Dalton Trans. 2008, 4482
-
(2008)
Dalton Trans.
, pp. 4482
-
-
Rodriguez, A.1
Fuks, G.2
Bourg, J.-B.3
Bourissou, D.4
Tham, F.S.5
Bertrand, G.6
-
45
-
-
0037040584
-
-
D. Scheschkewitz, H. Amii, H. Gornitzka, W. W. Schöller, D. Bourissou, G. Bertrand, Science 2002, 295 1880
-
(2002)
Science
, vol.295
, pp. 1880
-
-
Scheschkewitz, D.1
Amii, H.2
Gornitzka, H.3
Schöller, W.W.4
Bourissou, D.5
Bertrand, G.6
-
46
-
-
3042530961
-
-
D. Scheschkewitz, H. Amii, H. Gornitzka, W. W. Schöller, D. Bourissou, G. Bertrand, Angew. Chem. 2004, 116 595
-
(2004)
Angew. Chem.
, vol.116
, pp. 595
-
-
Scheschkewitz, D.1
Amii, H.2
Gornitzka, H.3
Schöller, W.W.4
Bourissou, D.5
Bertrand, G.6
-
48
-
-
27144523520
-
-
A. Rodriguez, R. A. Olsen, N. Ghaderi, D. Scheschkewitz, F. S. Tham, L. J. Mueller, G. Bertrand, Angew. Chem. 2004, 116 4988
-
(2004)
Angew. Chem.
, vol.116
, pp. 4988
-
-
Rodriguez, A.1
Olsen, R.A.2
Ghaderi, N.3
Scheschkewitz, D.4
Tham, F.S.5
Mueller, L.J.6
Bertrand, G.7
-
50
-
-
33846855697
-
-
A. Rodriguez, F. S. Tham, W. W. Schoeller, G. Bertrand, Angew. Chem. 2004, 116 4984
-
(2004)
Angew. Chem.
, vol.116
, pp. 4984
-
-
Rodriguez, A.1
Tham, F.S.2
Schoeller, W.W.3
Bertrand, G.4
-
52
-
-
16444381771
-
-
H. Cox, P. B. Hitchcock, M. F. Lappert, L. J.-M. Pierssens, Angew. Chem. 2004, 116 4600
-
(2004)
Angew. Chem.
, vol.116
, pp. 4600
-
-
Cox, H.1
Hitchcock, P.B.2
Lappert, M.F.3
Pierssens, L.J.-M.4
-
54
-
-
2542612143
-
-
C. Cui, M. Brynda, M. M. Olmstead, P. P. Power, J. Am. Chem. Soc. 2004, 126 6510.
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 6510
-
-
Cui, C.1
Brynda, M.2
Olmstead, M.M.3
Power, P.P.4
-
55
-
-
70349971276
-
-
The above-mentioned difficulties in the synthesis and isolation of 1 and its low stability at room temperature even in crystalline form did not allow for a definite experimental determination of the triplet state by ESR and SQUID measurements. Analyses of 1 in solution are less promising, as dissolving the crystals does not restore the green color of the solution the crystals were originally obtained from. Apparently, compound 1 is only formed in stationary low concentrations within the reaction solution according to Equation (1) and is immediately stabilized by the crystallization process. This process seems to circumvent a spin flip and the thermodynamically favored formation of compound 2.
-
The above-mentioned difficulties in the synthesis and isolation of 1 and its low stability at room temperature even in crystalline form did not allow for a definite experimental determination of the triplet state by ESR and SQUID measurements. Analyses of 1 in solution are less promising, as dissolving the crystals does not restore the green color of the solution the crystals were originally obtained from. Apparently, compound 1 is only formed in stationary low concentrations within the reaction solution according to Equation (1) and is immediately stabilized by the crystallization process. This process seems to circumvent a spin flip and the thermodynamically favored formation of compound 2.
-
-
-
-
56
-
-
70349956368
-
-
a development of University of Karlsruhe (TH) and Forschungszentrum Karlsruhe GmbH, 1989-2007, TURBOMOLE GmbH since 2007
-
a) TURBOMOLE V5.9 V6.0 2006-2009, a development of University of Karlsruhe (TH) and Forschungszentrum Karlsruhe GmbH, 1989-2007, TURBOMOLE GmbH since 2007; http://www.turbomole.com
-
TURBOMOLE V5.9 V6.0 2006-2009
-
-
-
57
-
-
4243539377
-
-
R. Ahlrichs, M. Bär, M. Häser, H. Horn, C. Kölmel, Chem. Phys. Lett. 1989, 162 165
-
(1989)
Chem. Phys. Lett.
, vol.162
, pp. 165
-
-
Ahlrichs, R.1
Bär, M.2
Häser, M.3
Horn, H.4
Kölmel, C.5
-
62
-
-
70349973340
-
-
Erratum
-
Erratum
-
-
-
-
64
-
-
0242593713
-
-
a) J. Tao, J. P. Perdew, V. N. Staroverov, G. E. Scuseria, Phys. Rev. Lett. 2003, 91 146401
-
(2003)
Phys. Rev. Lett.
, vol.91
, pp. 146401
-
-
Tao, J.1
Perdew, J.P.2
Staroverov, V.N.3
Scuseria, G.E.4
-
71
-
-
0031285825
-
-
K. Eichkorn, F. Weigend, O. Treutler, R. Ahlrichs, Theor. Chem. Acc. 1997, 97 119.
-
(1997)
Theor. Chem. Acc.
, vol.97
, pp. 119
-
-
Eichkorn, K.1
Weigend, F.2
Treutler, O.3
Ahlrichs, R.4
-
74
-
-
0346339719
-
-
P. Deglmann, K. May, F. Furche, R. Ahlrichs, Chem. Phys. Lett. 2004, 384 103.
-
(2004)
Chem. Phys. Lett.
, vol.384
, pp. 103
-
-
Deglmann, P.1
May, K.2
Furche, F.3
Ahlrichs, R.4
-
75
-
-
3743098842
-
-
a) K. Eichkorn, O. Treutler, H. Ohm, M. Häser, R. Ahlrichs, Chem. Phys. Lett. 1995, 242 652
-
(1995)
Chem. Phys. Lett.
, vol.242
, pp. 652
-
-
Eichkorn, K.1
Treutler, O.2
Ohm, H.3
Häser, M.4
Ahlrichs, R.5
-
78
-
-
70349957890
-
-
PhD Thesis University of Karlsruhe (TH)
-
M. Kattannek, PhD Thesis 2006, University of Karlsruhe (TH)
-
(2006)
-
-
Kattannek, M.1
|