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It has been reported by Selke and Valentine that binding of a solvent molecule as an axial ligand (e.g, DMSO) increases the nucleophilic reactivity of a ferric peroxo porphyrin complex in the epoxidation of electron-deficient olefins. The authors proposed that axial ligands push the side-on-binding peroxo group open and make the peroxo ligand more nucleophilic. See M. Selke, J. S. Valentine, J. Am. Chem. Soc. 1998, 120, 2652-2653
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It has been reported by Selke and Valentine that binding of a solvent molecule as an axial ligand (e.g., DMSO) increases the nucleophilic reactivity of a ferric peroxo porphyrin complex in the epoxidation of electron-deficient olefins. The authors proposed that axial ligands push the side-on-binding peroxo group open and make the peroxo ligand more nucleophilic. See M. Selke, J. S. Valentine, J. Am. Chem. Soc. 1998, 120, 2652-2653.
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