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Volumn 48, Issue 23, 2009, Pages 4150-4153

Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex

Author keywords

Axial ligand effects; Bioinorganic chemistry; Enzyme models; Manganese; Nucleophilic reactions

Indexed keywords

ANIONIC LIGANDS; AXIAL LIGAND; AXIAL LIGAND EFFECTS; BIOINORGANIC CHEMISTRY; ENZYME MODELS; LIGAND BINDING; MACRO-CYCLIC LIGANDS; NONHEME; NUCLEOPHILIC REACTIONS; NUCLEOPHILIC REACTIVITY; NUCLEOPHILICITIES; PEROXO GROUP; PEROXO LIGANDS; PEROXOCOMPLEXES; STRUCTURAL CHANGE; STRUCTURAL CHARACTERIZATION;

EID: 70349952287     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200900118     Document Type: Article
Times cited : (106)

References (33)
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    • (2008) Angew. Chem. Int. Ed , vol.47 , pp. 3356-3359
  • 23
    • 0032565110 scopus 로고    scopus 로고
    • It has been reported by Selke and Valentine that binding of a solvent molecule as an axial ligand (e.g, DMSO) increases the nucleophilic reactivity of a ferric peroxo porphyrin complex in the epoxidation of electron-deficient olefins. The authors proposed that axial ligands push the side-on-binding peroxo group open and make the peroxo ligand more nucleophilic. See M. Selke, J. S. Valentine, J. Am. Chem. Soc. 1998, 120, 2652-2653
    • It has been reported by Selke and Valentine that binding of a solvent molecule as an axial ligand (e.g., DMSO) increases the nucleophilic reactivity of a ferric peroxo porphyrin complex in the epoxidation of electron-deficient olefins. The authors proposed that axial ligands push the side-on-binding peroxo group open and make the peroxo ligand more nucleophilic. See M. Selke, J. S. Valentine, J. Am. Chem. Soc. 1998, 120, 2652-2653.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.