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Although not used in our work, we also note that multivalent counterions lead to collapse and/or aggregation and/or phase separation by effects of bridging, specific adsorption and displacing of monovalent counterions, neutralization, or even polyion charge reversal.
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Although not used in our work, we also note that multivalent counterions lead to collapse and/or aggregation and/or phase separation by effects of bridging, specific adsorption and displacing of monovalent counterions, neutralization, or even polyion charge reversal.
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The polymer-poor phase is almost pure solvent while the polymerrich phase comprises of an aggregate in which all chains from the simulation box are aggregated. Authors conclude that these aggregates represent a macrophase separation since when the simulation was performed with a larger simulation box with more chains, the size of the aggregate increased as well. We note, however, that the number of chains in the box was only 64. For comparison, our aggregation numbers in PEA nanoparticles are on the order of 2000. We note also the difference that we have salt in the system.
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