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Crystal data for [Ge(Me3-tacn)]Br[GeBr3, C 9H21Br4Ge2N3, M r, 636.11, monoclinic, space group P21/c (no. 14, a, 12.6486(10, b, 8.7022(10, c, 17.446(3) Å, β, 109.520(10)°, U= 1809.9(4) Å3, Z, 4, μ= 12.14 mm-1, T, 120K, 26441 total reflections, 4146 unique reflections, Aint, 0.059, R1 (I > 2σ(I, 0.031, R1 (all data, 0.040, wR2 (I>2σ(I, 0.061, wR2 (all data, 0.064. Crystal data for [Ge(Me4-cyclam, GeCl3]2CH2Cl 2: C15H34Cl8Ge 3N4, Mr= 771.83, triclinic, space group P1 (no. 2, a, 9.5581(15, b, 10.1021(15, c, 16.563(2) Å, α, 77.10910
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2 were not successful, and attempts to model split-site C atom positions in the disordered crown did not lead to a statistically significant improvement in the refinement and hence were not pursued. CCDC 722697, 722698, and 722699 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac. uk/data-request/cif.
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