Free radical reactions of stable silylenes and germylenes

Organometallics

Volumn 23, Issue 26, 2004, Pages 6330-6332

  Naka, Akinobu ^a   Hill, Nicholas J ^b   West, Robert ^b  

^a KURASHIKI UNIVERSITY OF SCIENCE AND THE ARTS   (Japan)

^b UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOND DISTANCES; ELLIPSOIDS; REACTING MIXTURES; SILANONE;

ADDITION REACTIONS; CHEMICAL BONDS; CRYSTAL STRUCTURE; DIMERIZATION; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREE RADICALS; MOLECULAR STRUCTURE; ORGANOMETALLICS; REACTION KINETICS;

COMPLEXATION;

EID: 11044221349     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049233f     Document Type: Article

References (8)

1. For reviews see: (a) Gaspar, P. P.; West, R. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: New York, 1999; Vol. 2, Part 3, pp 2463-2568.
2. (b) Haaf, M.; Schmedake, T. A.; West, R. Acc. Chem. Res. 2000, 33, 704.
3. (c) Gehrhus, B.; Lappert, M. F. J. Orgonomet. Chem. 2001, 617, 209.
4. Tumanskii, B.; Pine, P.; Apeloig, Y.; Hill, N. J.; West, R. J. Am. Chem. Soc. 2004, 126, 7786.
5. Kira, M.; Ishida, S.; Iwamoto, T.; Kabuto, C. J. Am. Chem. Soc. 1999, 121, 9722.
6. Iwamoto, T.; Masuda, H.; Ishida, S.; Kabuto, C.; Kira, M. J. Am. Chem. Soc. 2003, 125, 9300.
7. Iwamoto, T.; Masuda, H.; Ishida, S.; Kabuto, C.; Kira, M. J. Organomet. Chem. 2004, 689, 1337.
8. The silylene analogous to the saturated gennylene 10 also reacts with TEMPO, to give a complex reaction mixture which has so far proved intractable.