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Volumn 48, Issue 13, 2009, Pages 2394-2397

Tellus in, Tellus out: The chemistry of the vanadium bis(telluride) functionality

Author keywords

Alkylidenes; Chalcogens; N; Oxidation; P ligands; Tellurium

Indexed keywords

LIGANDS; NITROGEN; OXIDATION; TELLURIUM; TELLURIUM COMPOUNDS;

EID: 70349914178     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200806022     Document Type: Article
Times cited : (26)

References (38)
  • 10
    • 0000596575 scopus 로고    scopus 로고
    • 1) to be prone to loss of Te°, see J. M.Fischer, W. E. Piers, T. Ziegler, L. R. MacGillivray, M. J. Zaworotko, Chem.Eur. J. 1996, 2, 1221.
    • 1) to be prone to loss of Te°, see J. M.Fischer, W. E. Piers, T. Ziegler, L. R. MacGillivray, M. J. Zaworotko, Chem.Eur. J. 1996, 2, 1221.
  • 15
    • 85036798484 scopus 로고    scopus 로고
    • See the Supporting Information for details
    • See the Supporting Information for details.
  • 24
    • 85036779996 scopus 로고    scopus 로고
    • int, = 0.0304,GoF = 1.055, R = 0.0209 [I>2σ(I)], wR2 = 0.0522[I>2σ(I)]. CCDC 706518, 706519, 706520, 706521, 706522(2-5 and 8) contain the supplementary crystallographic data forthis paper. These data can be obtained free of charge from The CambridgeCrystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
    • int, = 0.0304,GoF = 1.055, R = 0.0209 [I>2σ(I)], wR2 = 0.0522[I>2σ(I)]. CCDC 706518, 706519, 706520, 706521, 706522(2-5 and 8) contain the supplementary crystallographic data forthis paper. These data can be obtained free of charge from The CambridgeCrystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
  • 25
    • 85036784901 scopus 로고    scopus 로고
    • Crystal data for 3: C10H20Te3, M= 523.06, monoclinic, P21/n, α, 12.7214(7) Å, b, 5.9309(3)Å, c, 19.0338(11) Å, β, 96.5310(10)°, V= 1426.77(13) Å′, Z, 4, ρcalcd, 2.435 Mgm3, T= 150(2) K, Mo Kα, 0.71073 Å, absorption coefficient 6.058 mm 1, F(000, 944, 24037 reflections collected, 3230 independentreflections, Rint, 0.0195, GoF, 1.074, R, 0.0147[I>2α(I)J, wR2, 0.0319 [I>2α I
    • int = 0.0195, GoF = 1.074, R = 0.0147[I>2α(I)J, wR2 = 0.0319 [I>2α (I).
  • 26
    • 85036777494 scopus 로고    scopus 로고
    • A search of the Cambridge Structural Database on 10/27/08 using Conquest1.10 suggests an average Te-Te bond length of approximately 2.7 Å formolecules containing C-Te-Te-C moieties.
    • A search of the Cambridge Structural Database on 10/27/08 using Conquest1.10 suggests an average Te-Te bond length of approximately 2.7 Å formolecules containing C-Te-Te-C moieties.
  • 28
    • 85036797895 scopus 로고    scopus 로고
    • Crystal data for 4: C2H40.NP2Te 2 Mr, 734.67, monoclinic, P21I c, α =7.2758(4) Å, b, 14.7745(10) Å, c, 27.0582(18) Å, β =95.3410(10)°, V=2896.0(3) Å3′, Z, 4, ρcalod =1.685 Mgnr3, T= 150(2) K, MoKα, 0.71073 Å,absorption coefficient 2.442 mnr1, F(000, 1440, 33700 reflectionscollected, 8801 independent reflections, Rmt, 0.0337, GoF, 1.013, R= 0.0293 {I 2σ(I, wR2, 0.0609 [I2σI
    • mt = 0.0337, GoF = 1.013, R= 0.0293 {I 2σ(I)}, wR2 = 0.0609 [I2σ(I)].
  • 31
    • 85036782785 scopus 로고    scopus 로고
    • Crystal data for 5: C46H70N3P 2V-C6H12-0.5C6 H14,M r, 905.17, monoclinic, P21/c, α, 12.6324(13) Å, 6 =36.310(4) Å, c, 11.6032(13) Å, β, 101.219(2)°,V=5220. 4(10) Å3, Z, 4, ρcalcd, 1.152 Mgnr3, T=123(2) K, MoKαl, 0.71073 Å, absorption coefficient0.289 mnr1, F(000, 1972, 63610 reflections collected, 9229independent reflections, Rint, 0.0611, GoF, 1.039, R =0.0479 [I>2σ(I, wR2, 0.0988 [I>2σI
    • int = 0.0611, GoF = 1.039, R =0.0479 [I>2σ(I)], wR2 = 0.0988 [I>2σ(I)].
  • 32
    • 85036792892 scopus 로고    scopus 로고
    • Few examples of vanadium bis(imide) complexes (transient or stableentities) have been reported;
    • Few examples of vanadium bis(imide) complexes (transient or stableentities) have been reported;
  • 33
    • 85178745755 scopus 로고    scopus 로고
    • F. Preuss, H. Becker, T. Wieland, Z. Naturforsch. B1990, 45, 191;
    • a) F. Preuss, H. Becker, T. Wieland, Z. Naturforsch. B1990, 45, 191;
  • 38
    • 85036785946 scopus 로고    scopus 로고
    • Crystal data for 8: C4H58N3P 2Te1 (I9V, M, 880.58, monoclinic, P21/c, α =12.439(3) Å, 6, 18.092(4) Å, c, 20.004(4) Å, β =106.380(4)°, V= 4319.2(17) Å3, Z, 4, ρcak.d, 1.354MgnT3, T= 150(2) K, MoKα, 0.71073 Å,absorption coefficient 1.056 mm1 F(000, 1810, 31624 reflectionscollected, 7713 independent reflections, Rint, 0.0800, GoF, 1.047,R, 0.0574 [I>2σ(I, wR2, 0.1453 [I >2σI, The crystals of 8 were found to contain co-crystalsof complex G44H58N3Te2V in a 9:1ratio. The Te disorder was refined with a set of restraints and constraints
    • 2V in a 9:1ratio. The Te disorder was refined with a set of restraints and constraints.


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