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Volumn 11, Issue 20, 2009, Pages 4492-4495

Rapid assembly of vinigrol's unique carbocyclic skeleton

Author keywords

[No Author keywords available]

Indexed keywords

DITERPENE; PYROGALLOL; VINIGROL;

EID: 70349909599     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol901519k     Document Type: Article
Times cited : (53)

References (36)
  • 30
    • 70349911997 scopus 로고    scopus 로고
    • 3P/PhSeCl
    • 3P/PhSeCl.
  • 33
    • 70349918094 scopus 로고    scopus 로고
    • Bromide 32 was obtained from a route identical the one shown in Scheme 5, the only difference being the use of Br-BBN. For further information, see the Supporting Information
    • Bromide 32 was obtained from a route identical the one shown in Scheme 5, the only difference being the use of Br-BBN. For further information, see the Supporting Information.
  • 34
    • 70349909818 scopus 로고    scopus 로고
    • When tris(trimethylsilyl)silane (TTMSS) was used as reducing agent instead of tributylstannane, the radical cyclization proceeded smoothly, but analysis of the product revealed that both the exo-methylene and methyl ketone groups had isomerized during the reaction to a trisubstituted endoolefln and an enaio-ketone, respectively
    • When tris(trimethylsilyl)silane (TTMSS) was used as reducing agent instead of tributylstannane, the radical cyclization proceeded smoothly, but analysis of the product revealed that both the exo-methylene and methyl ketone groups had isomerized during the reaction to a trisubstituted endoolefln and an enaio-ketone, respectively.
  • 36
    • 29044439970 scopus 로고    scopus 로고
    • The use of benzoquinone was necessary to suppress competing isomerization of the allyl group
    • The use of benzoquinone was necessary to suppress competing isomerization of the allyl group. Hong, S. H.: Sanders, D. P.; Lee, C. W.: Grubbs, R. H. J. Am. Chem. Soc. 2005, 127, 17160-1716L
    • (2005) J. Am. Chem. Soc. , vol.127
    • Hong, S.H.1    Sanders, D.P.2    Lee, C.W.3    Grubbs, R.H.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.