Mechanisms of abiotic degradation and soil-water interactions of pesticides and other Hydrophobic organic compounds. Part 3. Nucleophilic displacement at the phosphorus centre of the pesticide fenitrothion [O,O-dimethyl O-(3-methyl-4-nitrophehyl) phosphorothioate] by oxygen nucleophiles in aqueous solution: α-effect and mechanism

Journal of the Chemical Society, Perkin Transactions 2

Volumn , Issue 3, 2001, Pages 324-330

  Buncel, Erwin ^a  

^a QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALINITY; DEGRADATION; NEGATIVE IONS; PESTICIDES; PHOSPHORUS; RATE CONSTANTS; SOLUTIONS; SUBSTRATES;

SOIL-WATER INTERACTIONS;

ORGANIC COMPOUNDS;

EID: 0035768152     PISSN: 14701820     EISSN: None     Source Type: Journal    
DOI: 10.1039/b008615k     Document Type: Article

References (5)

1. H. W. Rosesky, R. Ahlrichs and S. Brode, Angew. Chem., Int. Ed. Engl., 1986, 25, 82.
2. N. L. Wolfe, Chemosphere, 1980, 9, 571.
3. A. J. Kirby and W. P. Jencks, J. Am. Chem. Soc., 1965, 87, 3217.
4. A. D. F. Toy and E. N. Walsh, Phosphorus in Everyday Living, American Chemical Society, Washington, DC, 1987, 2nd Edn., pp. 309-333.
5. E. Buncel and J. E. Omakor, unpublished results.