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Volumn 48, Issue 18, 2009, Pages 8856-8862

New insights into solvolysis and reorganization energy from gas-phase, electrochemical, and theoretical studies of Oxo-Tp Mov molecules

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; MOLYBDENUM HYDROTRIS (3,5 DIMETHYL 1 PYRAZOLYL)BORATE; MOLYBDENUM HYDROTRIS-(3,5-DIMETHYL-1-PYRAZOLYL)BORATE; ORGANOMETALLIC COMPOUND; OXYGEN; SOLVENT;

EID: 70349322714     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9011058     Document Type: Article
Times cited : (11)

References (32)
  • 1
    • 0000273676 scopus 로고    scopus 로고
    • Hille, R. Chem. Rev. 1996, 96, 2757-2816.
    • (1996) Chem. Rev. , vol.96 , pp. 2757-2816
    • Hille, R.1
  • 6
    • 0001225946 scopus 로고    scopus 로고
    • Characterization of the electronic structure of transition metal carbonyls and metallocenes
    • John Wiley & Sons Ltd.: Chichester, U.K.
    • Gruhn, N. E.; Lichtenberger, D. L. Characterization of the Electronic Structure of Transition Metal Carbonyls and Metallocenes. Inorganic Electronic Structure and Spectroscopy; John Wiley & Sons Ltd.: Chichester, U.K., 1999; Vol. 2, pp 533-574.
    • (1999) Inorganic Electronic Structure and Spectroscopy , vol.2 , pp. 533-574
    • Gruhn, N.E.1    Lichtenberger, D.L.2
  • 13
    • 70349361901 scopus 로고    scopus 로고
    • note
    • Upon estimation of the adiabatic ionization energy from the onset of the ionization intensity, account should also be taken for the possibility of appreciable hot bands on the low ionization energy side of the band from thermal population of higher-quantum vibrational states in the neutral molecule. This estimate of the adiabatic ionization energy also presumes that the vibrational manifold of the neutral molecule maps sufficiently to the optimum geometry of the cation such that the adiabatic ionization is observed on the fast (vertical) time scale of photoelectron spectroscopy. Otherwise, the onset of the ionization intensity is an upper bound to the true adiabatic ionization energy.
  • 18
    • 51849156693 scopus 로고    scopus 로고
    • Vrije Universiteit: Amsterdam, The Netherlands
    • ADF2006.01d, SCM, Theoretical Chemistry; Vrije Universiteit: Amsterdam, The Netherlands, 2006, http://www.scm.com.
    • (2006) ADF2006.01d, SCM, Theoretical Chemistry


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.