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For examples of papers on coordination networks and s-block metals
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For examples of papers on coordination networks and s-block metals, see: a) D. Braga, F. Grepioni, G. R. Desiraju, Chem. Rev. 1998, 98, 1375;
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For examples of work on coordination networks of metal sulfonates
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For examples of work on coordination networks of metal sulfonates, see: a) B. D. Chandler, G. D. Enright, K. A. Udachin, S. Pawsey, J. A. Ripmeester, D. T. Cramb, G. K. H. Shimizu, Nat. Mater. 2008, 7, 229;
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0033585541
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Sulfonated azo dye anions have also been used to engineer layered structures with complex organic cations
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Sulfonated azo dye anions have also been used to engineer layered structures with complex organic cations, see : C. C. Evans, L. Sukavto, M. D. Ward, J. Am. Chem. Soc. 1999, 121, 320.
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70349302190
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The structure of Sr14 (unit cell a = 14.82, b = 15.12, c = 17.09 Â, a = 109.86, /3 = 111.66, γ = 100.82°) is believed to be very similar to that of Cal4 but extensive crystal twinning precludes full analysis.
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The structure of Sr14 (unit cell a = 14.82, b = 15.12, c = 17.09 Â, a = 109.86, /3 = 111.66, γ = 100.82°) is believed to be very similar to that of Cal4 but extensive crystal twinning precludes full analysis.
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Interestingly, introducing a Li cation to the calculations does give the expected para > meta > ortho order for the total sulfonate Oatom charges (-1.536, -1.534 and -1.502, respectively). However, the optimized Li ortto-sulfonate geometry has Li bonded to both the sulfonate and the azo groups. Thus the model does not accurately reflect the experimentally observed geometry.
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Interestingly, introducing a Li cation to the calculations does give the expected para > meta > ortho order for the total sulfonate Oatom charges (-1.536, -1.534 and -1.502, respectively). However, the optimized Li ortto-sulfonate geometry has Li bonded to both the sulfonate and the azo groups. Thus the model does not accurately reflect the experimentally observed geometry.
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