Use of N-methylformamide as a solvent in indium-promoted barbier reactions en route to enediyne and epoxy diyne formation: Comparison of rate and stereoselectivity in C-C bond-forming reactions with water

Journal of Organic Chemistry

Volumn 74, Issue 16, 2009, Pages 5861-5870

  Frimpong, Kwame ^a   Wzorek, Joseph ^a   Lawlor, Claire ^a   Spencer, Katharine ^a   Mitzel, Thomas ^a  

^a TRINITY COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; ALDEHYDES; CHEMICAL BONDS; STEREOSELECTIVITY;

C-C BOND FORMING REACTION; CHEMICAL EQUATIONS; COUPLING REACTION; EN-ROUTE; ENEDIYNES; INDIUM METAL; N-METHYLFORMAMIDE; PROPARGYL; REGIOCONTROL; SKELETAL STRUCTURES; STEREOCONTROL;

INDIUM;

ALKYNE DERIVATIVE; CARBON; ENEDIYNE; INDIUM; N METHYLFORMAMIDE; SOLVENT; SULFIDE; WATER; ALDEHYDE; EPOXIDE; FORMAMIDE DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONFORMATION; STEREOCHEMISTRY; CATALYSIS; CHEMISTRY; ENZYME SPECIFICITY; KINETICS; STEREOISOMERISM;

ALDEHYDES; CARBON; CATALYSIS; ENEDIYNES; EPOXY COMPOUNDS; FORMAMIDES; INDIUM; KINETICS; SOLVENTS; STEREOISOMERISM; SUBSTRATE SPECIFICITY; SULFIDES; WATER;

EID: 70349120917     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo900763u     Document Type: Article

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