Endo- and exo-configured cyclopropylidenes incorporated into the norbornadiene skeleton: Generation, rearrangement to allenes, and the effect of remote substituents on carbene stability

Journal of Organic Chemistry

Volumn 74, Issue 18, 2009, Pages 7075-7083

  Kílbaş, Benan ^a   Azizoǧlu, Akin ^a,b   Balci, Metin ^a  

^a MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

^b BALIKESIR UNIVERSITY   (Turkey)

Author keywords

[No Author keywords available]

Indexed keywords

ALLENES; B3LYP/6-31G; CARBENE STABILITY; CARBENES; CHEMICAL EQUATIONS; CYCLOPROPANE DERIVATIVE; DOUBLE BONDS; HALOGEN ATOMS; METHOXY GROUP; NORBORNADIENE; PYRAMIDALIZATION ANGLE; RELATIVE ENERGIES;

BROMINE; HYDROGEN; PROPANE; SYNTHESIS (CHEMICAL);

CHEMICAL BONDS;

ALLENE DERIVATIVE; BENZENE DERIVATIVE; BRIDGED COMPOUND; BROMINE; CARBENE; CHLORINE DERIVATIVE; CYCLOPROPANE DERIVATIVE; FURAN DERIVATIVE; HALOGEN; HYDROGEN; NORBORNANE DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; DOERING MOORE SKATTEBOL REACTION; ENERGY; MOLECULAR STABILITY; REACTION ANALYSIS; SYNTHESIS;

EID: 70249109247     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo901398w     Document Type: Article

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