Molecular composition of organic aerosols formed in the α-pinene/O3 reaction: Implications for new particle formation processes

Journal of Geophysical Research Atmospheres

Volumn 103, Issue D19, 1998, Pages 25569-25578

  Hoffmann, Thorsten ^a   Bandur, Rolf ^a   Marggraf, Ulrich ^a   Linscheid, Michael ^a  

^a LEIBNIZ INSTITUT FÜR ANALYTISCHE WISSENSCHAFTEN ISAS E V   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL FORMATION; OXIDATION; VOLATILE ORGANIC COMPOUND;

EID: 0032454574     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/98JD01816     Document Type: Article

References (32)

1. Andreae, M.O., Climatic effects of changing atmospheric aerosol levels, in World Survey of Climatology: Future Climates of the World, edited by A. Henderson-Sellers, pp. 341-392, Elsevier Science, New York, 1995.
2. Andreae, M.O., and P. Crutzen, Atmospheric aerosols: Biogeochemical sources and role in atmospheric chemistry, Science, 276, 1052-1058, 1997.
3. Aschmann, S.M., Y. Shu, J. Arey, and R. Atkinson, Products of the gasphase reactions of cis-3-hexen-1-ol with OH radicals and ozone, Atmos. Environ., 31, 3551-3560, 1997.
4. Atkinson, R., E.S.C. Kwok, J. Arey, and S.M. Aschmann, Reactions of alkoxy radicals in the atmoshere, Faraday Discuss. Chem. Soc., 100, 23-37, 1995.
5. Bailey, P.S., Ozonation in Organic Chemistry, Vol. 1, Olefinic Compounds, Academic, San Diego, Calif., 1978.
6. Bowman, F.M., J.R. Odum, J.H. Seinfeld, and S.N. Pandis, Mathematical model for gas-particle partitioning of secondary organic aerosol, Atmos. Environ., 31, 3921-3931, 1997.
7. Christofferson, T.S., et al., Cis-pinic acid, a possible precursor for organic aerosol formation from ozonolysis of α-pinene, Atmos. Environ., 32, 1657-1661, 1998.
8. Fehsenfeld, F., et al., Emissions of volatile organic compounds from vegetation and the implications for atmospheric chemistry. Global Biogeochem. Cycles, 6, 389-430, 1992.
9. Grosjean, D., E.L. Williams, and J.H. Seinfeld, Atmospheric oxidation of selected terpenes and related carbonyls: Gas-phase carbonyl products, Environ. Sci. Technol., 26, 1526-1533, 1992.
10. Guenther, A., et al., A global model of natural volatile organic compound emissions, J. Geophys. Res., 100, 8873-8892, 1995.
11. Hagerman, L.M., V.P. Aneja, and W.A. Lonneman, Characterization of non-methane hydrocarbons in the rural southeast United States, Atmos. Environ., 31, 4017-4038, 1997.
12. Hakola, H., J. Arey, S.A. Aschmann, and R. Alkinson, Product formation from the gas-phase reactions of OH-radicals and O3 with a series of monoterpenes, J. Atmos. Chem., 18, 15-102, 1994.
13. Hatakeyama, S., K. Izumi, T. Fukuyama, and H. Akimoto, Reactions of ozone with alpha-pinene and β-pinene in air: Yields of gaseous and particulate products, J. Geophys. Res., 94, 13013-13024, 1989.
14. Hoffmann, T., J.R. Odum, F. Bowman, D. Collins, D. Klockow, R.C. Flagan, and J.H. Seinfeld, Formation of organic aerosols from the oxidation of biogenic hydrocarbons, J. Atmos. Chem., 26, 189-222, 1997a.
15. Hoffmann, T., R. Bandur, and J.H. Seinfeld, Experimental and theoretical studies on the aerosol formation potential of natural VOCs, paper presented at the Workshop on Biogenic Hydrocarbons in the Atmospheric Boundary Layer, Am. Meteorol. Soc., Charlottesville, Va., Aug. 24-27, 1997b.
16. Johnson, J.V., R.A. Yost, P.E. Kelley, and D.C. Bradford, Tandem-inspace and tandem-in-time mass spectrometrie: Triple quadrupoles and quadrupole ion traps. Anal. Chem., 62, 2162-2172, 1990.
17. Jonas, P.R., R.J. Charlson, and H. Rohde, Aerosols, in Climate Change 1994. Reports of Working Groups I and III of the IPCC, edited by J.T. Houghton et al., pp. 130-161, Cambridge Univ. Press, New York, 1995.
18. Katz, J.L., J.A. Fisk, and M.M. Rudek, Nucleation of single component supersaturated vapors, in Nucleation and Atmospheric Aerosols, Proceedings of the 14th International Conference on Nucleation and Atmospheric Aerosols, Helsinki, Finland, August 26-30, edited by M. Kulmala and P.E. Wagner, pp. 1-10, Elsevier Science, New York, 1996.
19. Mäkelä, J.M., P. Aalto, V. Jokinen, T. Pohja, A. Nissinen, S. Palmroth, T. Markkanen, K. Seitsonen, H. Lihavainen, and M. Kulmala, Observations of ultrafine aerosol particle formation and growth in boreal forest, Geophys. Res. Lett., 24, 1219-1222, 1997.
20. National Research Council, Aerosol Radiative Forces and Climate Change, Nat. Acad. Press, Washington, D.C., 1996.
21. Odum, J.R., T. Hoffmann, F. Bowman, D. Collins, R.C. Flagan, and J.H. Seinfeld, Gas/particle partitioning and secondary aerosol formation, Environ. Sci. Technol., 30, 2580-2585, 1996.
22. Odum, J.R., T.P.W. Jungkamp, R.C. Griffin, R.C. Flagan, and J.H. Seinfeld, The atmospheric aerosol-forming potential of whole gasoline vapor, Science, 276, 96-99, 1997.
23. Olson, T., and P. Hamill, A time-dependent approach to the kinetics of homogeneous nucleation, J. Chem. Phys., 104, 210-224, 1996.
24. Palen, E.J., D.T. Allen, S.N. Pandis, S.E. Paulson, J.H. Seinfeld, and R.C. Flagan, Fourier transform infrared analysis of aerosol formed in the photo-oxidation of isoprene and β-pinene, Atmos. Environ., 26 Part A, 1239-1251, 1992.
25. Pandis, S.N., S.E. Paulson, J.H. Seinfeld, and R.C. Flagan, Aerosol formation in the photooxidation of isoprene and β-pinene, Atmos. Environ., 25 Part A , 997-1008, 1991.
26. Pilinis, C., S. Pandis, and J.H. Seinfeld, Sensitivity of direct climate forcing by atmospheric aerosols to aerosol size and composition, J. Geophys. Res., 100, 18739-18754, 1995.
27. Raes, F., Aspects of tropospheric aerosols: Questions and ACE-2, in Nucleation and Atmospheric Aerosols, Proceedings of the 14th International Conference on Nucleation and Atmospheric Aerosols, Helsinki, Finland, August 26-30, edited by M. Kulmala and P.E. Wagner, pp. 749-758, Elsevier Science, New York, 1996.
28. Simpson, D., Biogenic emissions in Europe, 2, Implications for ozone control strategies, J. Geophys. Res., 100, 22891-22906, 1995.
29. Simpson, D., A. Guenther, C.N. Hewitt, and R. Steinbrecher, Biogenic emissions in Europe, 1, Estimates and uncertainties, J. Geophys. Res., 100, 22875-22890, 1995.
30. Went, F.W., Blue hazes in the atmosphere. Nature, 187, 641-643, 1960.
31. Wilson, W.E., W.E. Schwartz, and G.W. Kinzer, Haze formation - Its nature and origin, CRC-APRAC-CAPA-6-68-3, Batelle Columbus Lab., Columbus, Ohio, 1972.
32. Yokouchi, Y., and Y. Ambe, Aerosols formed from the chemical reaction of monoterpenes and ozone, Atmos. Environ., 19, 1271-1276, 1985.