Effect of cross-linker and cross-linker concentration on porosity, surface morphology and thermal behavior of metal alginates prepared from algae (Undaria pinnatifida)

Carbohydrate Polymers

Volumn 78, Issue 4, 2009, Pages 717-724

  Pathak, Tara Sankar ^a   Yun, Jung Ho ^a   Lee, Se Jong ^b   Baek, Dae Jin ^c   Paeng, Ki Jung ^a  

^a Yonsei University Wonju   (South Korea)

^b Kyungsung University   (South Korea)

^c Hanseo University   (South Korea)

Author keywords

Algae; Kinetics; Metal alginates; Porosity; Scanning electron microscopy (SEM); Thermal degradation

Indexed keywords

ALGINIC ACID; ASYMMETRIC STRETCHING; ATOMIC WEIGHTS; CARBOXYL GROUPS; CROSSLINKER; DEGRADATION PROCESS; EXTRACTION METHOD; FT-IR SPECTRUM; KINETIC ANALYSIS; ORDER REACTIONS; RAPID DEGRADATION; THERMAL BEHAVIORS; THERMAL DEGRADATION; THERMAL DEGRADATIONS; UNDARIA PINNATIFIDA; WEIGHT LOSS;

ACIDS; CADMIUM; CADMIUM COMPOUNDS; DEGRADATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; METAL RECOVERY; METALS; MORPHOLOGY; PHOTODEGRADATION; PHYTOPLANKTON; PORE SIZE; SCANNING; SCANNING ELECTRON MICROSCOPY; SURFACE MORPHOLOGY; THERMOGRAVIMETRIC ANALYSIS; ZINC;

ALGINATE;

ALGAE; UNDARIA; UNDARIA PINNATIFIDA;

EID: 69749105603     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2009.06.011     Document Type: Article

References (42)

1. Abu Al-Rub F.A., El Naas M.H., Benyahia F., and Ashour I. Biosorption of nickel on blank alginate beads, free and immobilized algal cells. Process Biochemistry 39 11 (2004) 1767-1773
2. Aksu Z., Eretli G., and Kutsal T.A. Comparative study of copper(II) biosorption on Ca-alginate, agarose and immobilized C. vulgaris in a packed-bed column. Process Biochemistry 33 4 (1998) 393-400
3. Angyal S.J. Complexes of metal cations with carbohydrates in solution. Advances in Carbohydrate Chemistry and Biochemistry 47 (1989) 1-43
4. 2+ by Ca-alginate and immobilized wood-rotting fungus Funalia trogii. Journal of Hazardous Material 109 1-3 (2004) 191-199
5. Aslani P., and Kennedy R.A. Effect of gelation conditions and dissolution media on the release of paracetamol from alginate gel beads. Journal of Microencapsulation 13 5 (1996) 601-614
6. Carr T.E., Harrison G.E., Humphreys E.R., and Sutton A. Reduction in the absorption and retention of dietary strontium in man by alginate. International Journal of Radiation Biology and Related Studies in Physics Chemistry and Medicine 14 (1968) 225-233
7. Chan L.W., Jin Y., and Heng P.W.S. Cross-linking mechanisms of calcium and zinc in production of alginate microspheres. International Journal of Pharmaceutics 242 1-2 (2002) 255-258
8. Chan L.W., Lee H.Y., and Heng P.W.S. Production of alginate microspheres by internal gelation using an emulsification method. International Journal of Pharmaceutics 242 1-2 (2002) 259-262
9. Chanda S.K., Hirst E.L., Percival B.G.V., and Ross A.G. The structure of alginic acid Part II. Journal of Chemical Society 183 (1952) 3-1837
10. Chattopadhyay J., Kim C., Kim R., and Pak D. Thermogravimetric characteristics and kinetic study of biomass co-pyrolysis with plastics. Korean Journal of Chemical Engineering 25 5 (2008) 1047-1053
11. Chen J.P., Hong L., Wu S., and Wang L. Elucidation of interactions between metal ions and Ca alginate-based ion-exchange resin by spectroscopic analysis and modeling simulation. Langmuir 18 24 (2002) 9413-9421
12. Chen J.P., Tendeyong F., and Yiacoumi S. Equilibrium and kinetic studies of copper ion uptake by calcium alginate. Environmental Science and Technology 31 5 (1997) 1433-1439
13. Coats A.W., and Redfern J.F. Kinetic parameters from thermogravimetric data. Nature 201 4914 (1964) 68-69
14. Davis T.A., Volesky B., and Mucci A. A review of the biochemistry of heavy metal biosorption by brown algae. Water Research 37 (2003) 4311-4330
15. Gombotz W., and Wee S.W. Protein release from alginate matrices. Advanced Drug Delivery Reviews 31 3 (1998) 267-285
16. Gotoh T., Matsushima K., and Kikuchi K.I. Adsorption of Cu and Mn on covalently cross-linked alginate gel beads. Chemosphere 55 1 (2004) 57-64
17. Grant G.T., Morris E.R., Rees D.A., Smith P.J.C., and Thom D. Biological interactions between polysaccharides and divalent cations: The egg-box model. FEBS Letters 32 1 (1973) 195-198
18. Jeon C., Nah I.W., and Hwang K.Y. Adsorption of heavy metals using magnetically modified alginic acid. Hydrometallurgy 86 3-4 (2007) 140-146
19. Kierstan M., and Bucke C. The immobilization of microbial cells, subcellular organelles, and enzymes in calcium alginate gels. Biotechnology and Bioengineering 19 3 (1977) 387-397
20. Kneafsey B., Shaughnessy M.O., and Condon K.C. The use of calcium alginate dressings in deep hand burns. Burns 22 1 (1996) 40-43
21. Kohn R., and Furda I. Binding of calcium ions to acetyl derivatives of pectin. Collection of Czechoslovak Chemical Communications 33 (1968) 2217-2225
22. Konoshi Y., Asai S., Midoh Y., and Oku M. Recovery of zinc, cadmium, and lanthanum by biopolymer gel particles of alginic acid. Separation Science and Technology 28 9 (1993) 1691-1702
23. Korotaev G.K., Chlenov M.A., Kirianov A.V., Arazashvili A.I., Kuznetsova E.K., Ivannikov A.T., et al. Modified calcium alginate-a highly effective agent for eliminating radioactive strontium. Radiobiologiia 32 (1992) 126-129
24. Lazaro M.J., Moliner R., and Suelves I. Non-isothermal versus isothermal technique to evaluate kinetic parameters of coal pyrolysis. Journal of Analytical and Applied Pyrolysis 47 2 (1998) 111-125
25. Lee K.Y., Rowley J.A., Eiselt P., Moy E.M., Bouhadir K.H., and Mooney D.J. Controlling mechanical and swelling properties of alginate hydrogels independently by cross-linker type and cross-linking density. Macromolecules 33 11 (2000) 4291-4294
26. Lee Y.H., Sookim J., and Dokim H. A study of biodegradable superabsorbent materials based on acrylonitrile grafted sodium alginate. Key Engineering Material 277-279 (2005) 450-454
27. McDowell, R. H. (1978). Properties of Alginates. London: Alginate Industries Ltd.
28. Mimura H., Ohta H., Akiba K., and Onodera Y. Uptake behavior of americium on alginic acid and alginate polymer gels. Journal of Radioanalytical and Nuclear Chemistry 247 1 (2001) 33-38
29. Morris E.R., Rees D.A., Thom D., and Boyd J. Chiroptical and stoichiometric evidence of a specific, primary dimerisation process in alginate gelation. Carbohydrate Research 66 1 (1978) 145-154
30. Muzzarelli, R. A. A (1973). In Natural chelating polymers international series of monographs in analytical chemistry. Oxford, UK: Pergamon Press.
31. Pandey A., Bera D., Shukla A., and Ray L. Studies on Cr(VI), Pb(II) and Cu(II) adsorption-desorption using calcium alginate as biopolymer. Chemical Separation and Bioavailability 19 1 (2007) 17-24
32. Pathak T.S., Kim J.S., Lee S.J., Baek D.J., and Paeng K.J. Preparation of alginic acid and metal alginate from algae and their comparative study. Journal of Polymers and the Environment 16 3 (2008) 198-204
33. Polona S., Marija B., Anamarija Z., Odon P., and Ales M. Shape optimization and characterization of polysaccharide beads prepared by ionotropic gelation. Journal of Microencapsulation 25 2 (2007) 90-105
34. Rees D.A., and Welsh E.J. Secondary and tertiary structure of polysaccharides in solutions and gels. Angewandte Chemie International Edition in English 16 4 (1977) 214-224
35. Roy A., Bajpai J., and Bajpai A.K. Dynamics of controlled release of chlorpyrifos from swelling and eroding biopolymeric microspheres of calcium alginate and starch. Carbohydrate Polymers 76 2 (2009) 222-231
36. Sanchez-Machado D.I., Lopez-Cervantes J., Lopez-Hernandez J., Paseiro-Losada P., and Simal-Lozano J. Determination of the uronic acid composition of seaweed dietary fibre by HPLC. Biomedical Chromatography 18 (2004) 90-97
37. Segal H.C., Hunt B.J., and Gilding K. The effects of alginate and non-alginate wound dressings on blood coagulation and platelet activation. Journal of Biomaterials Application 12 3 (1998) 249-257
38. Singh A., Singh D.K., and Kushwaha V.B. Alginates as binding matrix for bio-molluscides against harmful snails lymnaea acuminate. Journal of Applied Polymer Science 105 3 (2007) 1275-1279
39. Suckow M.A., Park K., Siger L., Turek J., Bore D., and Van Horn D. Immunogenicity of antigens in boiled alginate microspheres. Journal of Biomater Science, Polymer Edition 11 1 (2000) 55-68
40. Sutton A., Humphreys E.R., Shepherd H., and Howells G.R. Reduction in the retention of radioactive barium in rats following the addition of sodium alginate derivatives to the diet. International Journal of Radiation Biology and Related Studies in Physics, Chemistry and Medicine 22 (1972) 297-300
41. Zheng H. Interaction mechanism in sol-gel transition of alginate solutions by addition of divalent cations. Carbohydrate Research 302 1-2 (1997) 97-101
42. Zhou L., Wang Y., Huang Q., and Cai J. Thermogravimetric characteristics and kinetic of plastic and biomass blends co-pyrolysis. Fuel Processing Technology 87 11 (2006) 963-969