Electron attachment to halomethanes at high temperature: CH2 Cl2, CF2 Cl2, CH3 Cl, and CF 3 Cl attachment rate constants up to 1100 K

Journal of Chemical Physics

Volumn 131, Issue 8, 2009, Pages

  Miller, Thomas M ^a,b   Friedman, Jeffrey F ^a,c   Schaffer, Linda C ^a   Viggiano, A A ^a  

^a AIR FORCE RESEARCH LABORATORY   (United States)

^b BOSTON COLLEGE   (United States)

^c UNIVERSITY OF PUERTO RICO   (Puerto Rico)

Author keywords

[No Author keywords available]

Indexed keywords

ARRHENIUS BEHAVIORS; ATTACHMENT RATE; ELECTRON ATTACHMENT; G-3 CALCULATIONS; HALOMETHANES; HIGH TEMPERATURE; LANGMUIRS; PARENT ANIONS; REACTION ENERGETICS; ROOM TEMPERATURE; TEMPERATURE RANGE;

ACTIVATION ENERGY; ARRHENIUS PLOTS; ELECTRONS; RATE CONSTANTS;

CHLORINE COMPOUNDS;

EID: 69549107427     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3212598     Document Type: Article

References (37)

1. T. M. Miller, J. F. Friedman, J. S. Williamson, L. C. Schaffer, and A. A. Viggiano, Rev. Sci. Instrum. 0034-6748 80, 034104 (2009). 10.1063/1.3097185
2. L. A. Curtiss, K. Raghavachari, P. C. Redfern, V. Rassolov, and J. A. Pople, J. Chem. Phys. 0021-9606 109, 7754 (1998).
3. M. J. Frisch, G. W. Trucks, H. B. Schlegel, GAUSSIAN-03W, Revision C.02, Gaussian, Inc., Wallingford, CT, 2004.
4. L. A. Curtiss, P. C. Redfern, and K. Raghavachari, J. Chem. Phys. 0021-9606 123, 124107 (2005). 10.1063/1.2039080 (Pubitemid 41407773)
5. A. Kühn and E. Illenberger, J. Phys. Chem. 0022-3654 93, 7060 (1989). 10.1021/j100357a009
6. J. Langer, S. Mott, M. Meinke, P. Tegeder, A. Stamatovic, and E. Illenberger, J. Chem. Phys. 0021-9606 113, 11063 (2000). 10.1063/1.1326849 (Pubitemid 32087594)
7. G. B. Ellison, P. C. Engelking, and W. C. Lineberger, J. Am. Chem. Soc. 0002-7863 100, 2556 (1978). 10.1021/ja00476a054
8. H. -J. Deyerl, L. S. Alconcel, and R. E. Continetti, J. Phys. Chem. A 1089-5639 105, 552 (2001). 10.1021/jp003137k (Pubitemid 32159662)
9. C. Blondel, C. Delsart, and F. Goldfarb, J. Phys. B 0953-4075 34, L281 (2001). 10.1088/0953-4075/34/9/101 (Pubitemid 32497741)
10. J. F. Friedman, T. M. Miller, L. C. Schaffer, A. A. Viggiano, and I. I. Fabrikant, Phys. Rev. A 1050-2947 79, 032707 (2009). 10.1103/PhysRevA.79.032707
11. D. Smith, N. G. Adams, and E. Alge, J. Phys. B 0953-4075 17, 461 (1984). 10.1088/0022-3700/17/3/015
12. T. Su and W. J. Chesnavich, J. Chem. Phys. 0021-9606 76, 5183 (1982) 10.1063/1.442828;
13. T. Su, J. Chem. Phys. 0021-9606 89, 5355 (1988) 10.1063/1.455750;
14. D2. 10.1063/1.453817
15. M. Larsson and A. E. Orel, Dissociative Recombination of Molecular Ions (Cambridge University Press, Cambridge, 2008), pp. 267-271. The correction of the present data for electron-ion recombination events used a rough average of rate constants for polyatomic ions.
16. -1 (500 K). 10.1063/1.478820
17. D. L. McCorkle, A. A. Christodoulides, L. G. Christophorou, and I. Szamrej, J. Chem. Phys. 0021-9606 72, 4049 (1980) 10.1063/1.439685;
18. D. L. McCorkle, A. A. Christodoulides, L. G. Christophorou, and I. Szamrej, J. Chem. Phys. 0021-9606 76, 753 (1982). 10.1063/1.443581
19. S. J. Burns, J. M. Matthews, and D. L. McFadden, J. Phys. Chem. 0022-3654 100, 19436 (1996). 10.1021/jp962529h
20. J. L. Le Garrec, O. Sidko, J. L. Queffelec, S. Hamon, J. B. A. Mitchell, and B. R. Rowe, J. Chem. Phys. 0021-9606 107, 54 (1997). 10.1063/1.474352
21. J. D. Skalny, S. Matejcik, T. Mikoviny, and T. D. Märk, Int. J. Mass Spectrom. 223-224, 217 (2003). 10.1016/S1387-3806(02)00792-3 0021-9606
22. L. G. Christophorou and J. K. Olthoff, Fundamental Electron Interactions with Plasma Processing Gases (Kluwer Academic, New York / Plenum, New York, 2004), pp. 553-554.
23. L. G. Christophorou, D. L. McCorkle, and A. A. Christodoulides, in Electron-Molecule Interactions and Their Applications, edited by, L. G. Christophorou, (Academic, New York, 1984), Vol. 1, Chap..
24. A preliminary description of the Boston College experiments, in an apparatus capable of reaching 1200 K, was given by D. L. McFadden, " Chemical kinetics and atmospheric modification.," Final Report No. PL-TR-94-2164, 1994, available online from the Defense Technical Information Center at http://handle.dtic.mil/100.2/ADA283304.
25. I. I. Fabrikant, J. Phys. B 0953-4075 27, 4325 (1994). 10.1088/0953-4075/27/18/026
26. R. S. Wilde, G. A. Gallup, and I. I. Fabrikant, J. Phys. B 0953-4075 33, 5479 (2000). 10.1088/0953-4075/33/24/302 (Pubitemid 32130729)
27. A. A. Christodoulides, R. Schumacher, and R. N. Schindler, Int. J. Chem. Kinet. 0538-8066 10, 1215 (1978). 10.1002/kin.550101204
28. R. W. Fessenden and K. M. Bansal, J. Chem. Phys. 0021-9606 53, 3468 (1970). 10.1063/1.1674519
29. Y. Wang, L. G. Christophorou, J. K. Olthoff, and J. K. Verbrugge, Chem. Phys. Lett. 0009-2614 304, 303 (1999). 10.1016/S0009-2614(99)00338-3
30. G. K. Jarvis, C. A. Mayhew, L. Singleton, and S. M. Spyrou, Int. J. Mass Spectrom. Ion Process. 0168-1176 164, 207 (1997). 10.1016/S0168-1176(97)00060-8
31. Y. -R. Luo, in Handbook of Chemistry and Physics, 88th ed., edited by, D. R. Lide, (CRC, Boca Raton, FL, 2008), pp. 56-80.
32. -1 exp [-125.9/kT (meV)].
33. I. I. Fabrikant and H. Hotop, J. Chem. Phys. 0021-9606 128, 124308 (2008). 10.1063/1.2841079
34. I. Hahndorf and E. Illenberger, Int. J. Mass Spectrom. 167/168, 87 (1997). 10.1016/S0168-1176(97)00035-9 1387-3806
35. E. I. Dashevskaya, I. Litvin, E. E. Nikitin, and J. Troe, Phys. Chem. Chem. Phys. 1463-9076 10, 1270 (2008). 10.1039/b713530k
36. 3 (CF3 Cl).
37. Handbook of Chemistry and Physics, 88th ed., edited by, D. R. Lide, (CRC, Boca Raton, FL, 2008), Sec. 9, pp. 47-55. The dipole moments are 1.60±0.03 D (CH2 Cl2), 0.51±0.05 D (CF2 Cl2), 1.8963±0.0002 D (CH3 Cl), and 0.50±0.01 D (CF3 Cl).