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2 +) cation from acidic solutions, which is relevant to reprocessing of nuclear fuels
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This report describes an example of coordinatively saturated nitrate anion included in a coordination polymer with a fascinating interpenetrated Borromean structure
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Byrne P., Lloyd G.O., Clarke N., and Steed J.W. A "compartmental" borromean weave coordination polymer exhibiting saturated hydrogen bonding to anions and water cluster inclusion. Angew Chem Int Ed 47 (2008) 5761-5764 This report describes an example of coordinatively saturated nitrate anion included in a coordination polymer with a fascinating interpenetrated Borromean structure
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Custelcean R., Moyer B.A., Bryantsev V.S., and Hay B.P. Anion coordination in metal-organic frameworks functionalized with urea hydrogen-bonding groups. Cryst Growth Des 6 (2006) 555-563
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Custelcean R., Haverlock T.J., and Moyer B.A. Anion separation by selective crystallization of metal-organic frameworks. Inorg Chem 45 (2006) 6446-6452
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56549123795
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Hydrogen-bonded helices for anion binding and separation
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A new approach to anion separation from water is described, based on crystallization of solid solutions of hydrogen-bonded helices. The fundamental factors governing anion selectivity in competitive crystallizations of these organic solids are analyzed
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Custelcean R., Jiang D., Hay B.P., Luo W., and Gu B. Hydrogen-bonded helices for anion binding and separation. Cryst Growth Des 8 (2008) 1909-1915 A new approach to anion separation from water is described, based on crystallization of solid solutions of hydrogen-bonded helices. The fundamental factors governing anion selectivity in competitive crystallizations of these organic solids are analyzed
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2 - occupy the capsules. As a result crystallization of these frameworks provides a promising approach towards sulfate separation from competitive aqueous environments, which is relevant to nuclear waste cleanup
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2 - occupy the capsules. As a result crystallization of these frameworks provides a promising approach towards sulfate separation from competitive aqueous environments, which is relevant to nuclear waste cleanup
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This paper describes the separation of nitrate and sulfate by selective encapsulation inside organic frameworks that provide a saturated hydrogen-bonding environment to the anions. Unlike previous examples where the frameworks were assembled via strong metal-ligand coordinative bonds or charge-assisted hydrogen-bonds, these structures are held together solely by weaker CH⋯O and CH⋯π interactions
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Uzarevic K., Dilovic I., Matkovic-Calogovic D., Sisak D., and Cindric M. Anion-directed self-assembly of flexible ligands into anion-specific and highly symmetrical organic solids. Angew Chem Int Ed 47 (2008) 7022-7025 This paper describes the separation of nitrate and sulfate by selective encapsulation inside organic frameworks that provide a saturated hydrogen-bonding environment to the anions. Unlike previous examples where the frameworks were assembled via strong metal-ligand coordinative bonds or charge-assisted hydrogen-bonds, these structures are held together solely by weaker CH⋯O and CH⋯π interactions
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Uzarevic, K.1
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