Acetoxybis(imidazolyl)methylborate [B(ImN-Me)2(OC({double bond, long}O)Me)Me]-: Carboxylation of borane moiety of imidazolyl-based scorpionate

Inorganica Chimica Acta

Volumn 362, Issue 12, 2009, Pages 4472-4479

  Fujita, Koyu ^a   Akita, Munetaka ^a   Hikichi, Shiro ^a,b  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b KANAGAWA UNIVERSITY   (Japan)

Author keywords

Borate compounds; Nickel complexes; Scorpionate ligands; X ray crystal structures

Indexed keywords

BORON; CARBOXYLATION; ORGANOMETALLICS;

ACETATE ANIONS; BORATE COMPOUNDS; DOUBLE BONDS; FUNCTIONALIZED; METHYLBORATE; NICKEL COMPLEX; SCORPIONATE LIGAND; X RAY CRYSTAL STRUCTURES;

NICKEL COMPOUNDS;

EID: 68849094154     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2009.05.007     Document Type: Article

References (40)

1. Trofimenko S. Scorpionates - The Coordination Chemistry of Polypyrazolylborate Ligands (1999), Imperial College Press, London
2. Pettinari C. Scorpionates II: Chelating Borate Ligans (2008), Imperial College Press, London
3. Fujita K., Hikichi S., Akita M., and Moro-oka Y. J. Chem. Soc., Dalton Trans. (2000) 117
4. Fujita K., Hikichi S., Akita M., and Moro-oka Y. J. Chem. Soc., Dalton Trans. (2000) 1255
5. Hikichi S., Kaneko M., Miyoshi Y., Mizuno N., Fujita K., and Akita M. Top. Catal. 52 (2009) 845
6. Non-pyrazolyl scorpionate ligands (except our work): see Ref. [2] and follows:. Dunne J.F., Su J., Ellern A., and Sadow A.D. Organometallics 27 (2008) 2399
7. Mazet C., Köhler V., and Pfaltz A. Angew. Chem. Int. Ed. 44 (2005) 4888
8. Hodgkins T.G., and Powell D.R. Inorg. Chem. 35 (1996) 2140
9. Betley T.A., and Peters J.C. Inorg. Chem. 41 (2002) 6541
10. Barney A.A., Heyduk A.F., and Nocera D.G. Chem. Commun. (1999) 2379
11. Thomas J.C., and Peters J.C. J. Am. Chem. Soc. 123 (2001) 5100
12. Ge P., Haggerty B.S., Rheingold A.L., and Riordan C.G. J. Am. Chem. Soc. 116 (1994) 8406
13. Ohrenberg C., Ge P., Schebler P., Riordan C.G., Yap G.P.A., and Rheingold A.L. Inorg. Chem. 35 (1996) 749
14. Ghosh P., and Parkin G. J. Chem. Soc., Dalton Trans. (1998) 2281
15. Looney A., Han R., Gorrell I.B., Cornebise M., Yoon K., Parkin G., and Rheingold A.L. Organometallics 14 (1995) 274;
16. Dowling C., and Parkin G. Polyhedron 15 (1996) 2463
17. Ghosh P., and Parkin G. Chem. Commun. (1998) 413
18. Chowdhury S.K., Samanta U., Puranik V.G., and Sarkar A. Organometallics 16 (1997) 2618
19. Other selected examples of the functionalized (pyrazolyl)borate ligands:. Casado M.A., Hack V., Camerano J.A., Ciriano M.A., Tejel C., and Oro L.A. Inorg. Chem. 44 (2005) 9122
20. Reger D.L., Gardinier J.R., Gemmill W.R., Smith M.D., Shahin A.M., Long G.J., Rebbouh L., and Grandjean F. J. Am. Chem. Soc. 127 (2005) 2303
21. Perrin D.D., Armarego W.L., and Perrin D.R. Purification of Laboratory Chemicals. second ed. (1980), Pergamon, New York
22. texsan, Crystal Structure Analysis Package; MSC, Houston, 1985.
23. G.M. Sheldrick, shelxs-86: Program for Crystal Structure Determination, University of Göttingen, Göttingen, Germany, 1986.
24. Altomare A., Burla M.C., Camalli M., Cascarano M., Giacovazzo C., Guagliardi A., and Polidori G. J. Appl. Crystallogr. 27 (1994) 435
25. P.T. Beurskens, G. Admirral, G. Beurskens, W.P. Bosman, R. de Gelder, R. Israel, J.M.M. Smith, The dirdif-94 Program System, Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherland, 1994.
26. G.M. Sheldrick, shelxs-97: Program for Crystal Structure Determination, University of Göttingen, Göttingen, Germany, 1997.
27. Farrugia L.J. J. Appl. Crystallogr. 32 (1999) 837
28. Examples of alkoxybis(pyrazolyl)borate compounds: see Ref. [8] and follows:. Paulo A., Ascenso J., Domingos A., Galvão A., and Santos I. J. Chem. Soc., Dalton Trans. (1999) 1293;
29. Cano M., Heras J.V., Santamaria E., Pinilla E., Monge A., Jones C.J., and McCleverty J.A. Polyhedron 12 (1993) 1711
30. Trofimenko S. J. Am. Chem. Soc. 89 (1967) 6288;
31. Echols H.M., and Dennis D. Acta Crystallogr., Sect. B B30 (1974) 2173;
32. Echols H.M., and Dennis D. Acta Crystallogr., Sect. B B32 (1976) 267;
33. Cotton F.A., and Murillo C.A. Inorg. Chim. Acta 17 (1976) 121
34. Clemente D.A., and Cingi-Biagini M. Inorg. Chem. 26 (1987) 2350
35. Kokusen H., Sohrin Y., Matsui M., Hata Y., and Hasegawa H. J. Chem. Soc., Dalton Trans. (1996) 195
36. Kitajima N., Hikichi S., Tanaka M., and Moro-oka Y. J. Am. Chem. Soc. 115 (1993) 5496
37. Hikichi S., Yoshizawa M., Sasakura Y., Komatsuzaki H., Moro-oka Y., and Akita M. Chem. Eur. J. 7 (2001) 5011
38. Hikichi S., Sasakura Y., Yoshizawa M., Ohzu Y., Moro-oka Y., and Akita M. Bull. Chem. Soc. Jpn. 75 (2002) 1255
39. Das S., Incarvito C.D., Crabtree R.H., and Brudvig G.W. Science 312 (2006) 1941
40. Hull J.F., Sauer E.L.O., Incarvito C.D., Faller J.W., Brudvig G.W., and Crabtree R.H. Inorg. Chem. 48 (2009) 488