Elaboration of the bis(pyrazolyl)hydroborato ligand [BpBut,pri] into the NNO donor ligand, [(MeO)BpBut,pri]: Structural characterization of a complex in which the [(MeO)BpBut,pri] ligand models the binding of zinc to the peptide backbone in thermolysin

Polyhedron

Volumn 15, Issue 14, 1996, Pages 2463-2465

  Dowling, Conor ^a   Parkin, Gerard ^a  

^a Columbia University ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001631498     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/0277-5387(96)00014-9     Document Type: Article

References (33)

1. (a) B. L. Vallee and D. S. Auld, Acc. Chem. Res. 1993, 26, 543;
2. (b) B. L. Vallee and D. S. Auld, in Matrix Metalloprotinases and Inhibitors, (Edited by H. Birkedal-Hansen, Z. Werb, H. G. Welgus and H. E. van Wart), pp. 5-19. Gustav Fischer Verlag, New York (1992);
3. (c) I. Bertini, C. Luchinat, W. Maret and M. Zeppezauer (Eds), Zinc Enzymes, in Progress Inorganic Biochemistry and Biophysics, Vol 1. Birkhäuser, Boston (1986);
4. (d) B. L. Vallee and A. Galdes, Adv. Enzymol. Relat. Areas Mol. Biol. 1984, 56, 283.
5. R. S. Brown, J. Huguet and N. J. Curtis, in Role of Metal Ions in Biological Systems (Edited by H. Sigel), Vol. 5, pp. 55-99. Marcel Dekker, New York (1983).
6. C. Kimblin, W. E. Allen and G. Parkin, J. Chem. Soc., Chem. Commun. 1995, 1813.
7. R,R′), with the 1- and 4-alkyl substituents listed respectively as superscripts.
8. (a) A. E. Eriksson, T. A. Jones and A. Liljas, Proteins : Struct. Funct. Gen. 1988, 4, 274;
9. (b) S. K. Nair and D. W. Christianson, J. Am. Chem. Soc. 1991, 113, 9455.
10. (a) R. Alsfasser, S. Trofimenko, A. Looney, G. Parkin and H. Vahrenkamp, Inorg. Chem. 1991, 30, 4098;
11. (b) A. Looney, G. Parkin, R. Alsfasser, M. Ruf and H. Vahrenkamp, Angew. Chem., Int. Ed. Engl. 1992, 31, 92.
12. A. Looney, R. Han, K. McNeill and G. Parkin, J. Am. Chem. Soc. 1993, 115, 4690.
13. (a) M. Ruf, K. Weis and H. Vahrenkamp, J. Chem. Soc., Chem. Commun. 1994, 135;
14. (b) R. Alsfasser, M. Ruf, S. Trofimenko and H. Vahrenkamp, Chem. Ber. 1993, 126, 703.
15. (a) N. Kitajima, S. Hikichi M. Tananka and Y. Moro-oka, J. Am. Chem. Soc. 1993, 115, 5496;
16. (b) S. Hikichi, M. Tanaka, Y. Moro-oka and N. Kitajima, J. Chem. Soc., Chem. Commun. 1992, 814.
17. M. A. Holmes and B. W. Matthews, J. Mol. Biol. 1982, 160, 623.
18. M. F. Schmid and J. R. Herriott, J. Mol. Biol. 1976, 103, 175.
19. B. W. Matthews, Acc. Chem. Res. 1988, 21, 333.
20. W. R. Kester and B. W. Matthews, J. Biol. Chem. 1977, 252, 7704.
21. D. W. Christianson, Adv. Protein Chem. 1991, 42, 281.
22. D.W. Christianson and W. N. Lipscomb, Acc. Chem. Res. 1989, 22, 62.
23. H. Feinberg, H. M. Greenblatt, V. Behar, C. Gilon, S. Cohen, A. Bino and G. Shoham, Acta Crystallogr. 1995, D51, 428.
24. S. S. Tandon, S. Chander, L. K. Thompson, J. N. Bridson and V. McKee, Inorg. Chim. Acta 1994, 219, 55.
25. (a) A. Abufarag and H. Vahrenkamp, Inorg. Chem. 1995, 34, 3279;
26. (b) A. Abufarag and H. Vahrenkamp, Inorg. Chem. 1995, 34, 2207.
27. J. T. Groves and J. R. Olson, Inorg. Chem. 1985, 24, 2717.
28. A. Schepartz and R. Breslow, J. Am. Chem. Soc. 1987, 109, 1814.
29. C. Dowling, V. J. Murphy and G. Parkin, Inorg. Chem., in press.
30. For an example of a NNO ligand that does bind in a facial manner to a four-coordinate zinc centre, but does not incorporate pyrazolyl moieties, see : E. J. Corey, P.-W. Yuen, F. J. Hannon and D. A. Wierda, J. Org. Chem. 1990, 55, 784.
31. But) system. See : A. Looney, R. Han, I. B. Gorrell, M. Cornebise, K. Yoon, G. Parkin and A. L. Rheingold, Organometallics 1995, 14, 274.
32. But)ZnMe (Ref. 23). C. Dowling and G. Parkin, unpublished results.
33. K. Yoon and G. Parkin, J. Am. Chem. Soc. 1991, 113, 8414.