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Within the scope of irreversible thermodynamics, thermodynamically independent properties are quantified by different coefficients in the Onsager matrix of phenomenological coefficients
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Within the scope of irreversible thermodynamics, thermodynamically independent properties are quantified by different coefficients in the Onsager matrix of phenomenological coefficients.
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In this approximation, it is assumed that the flux of a solute relative to the center of mass is proportional to the gradient of electrochemical potential of this solute alone. Generally, for example, due to the solution nonideality, there are some contributions of gradients of electrochemical potentials of other solutes
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In this approximation, it is assumed that the flux of a solute relative to the center of mass is proportional to the gradient of electrochemical potential of this solute alone. Generally, for example, due to the solution nonideality, there are some contributions of gradients of electrochemical potentials of other solutes.
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Because of the relatively low porosity of polyfluoroethylene support, a considerable proportion of pores of TEM could otherwise be seated against impermeable zones of this material
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Because of the relatively low porosity of polyfluoroethylene support, a considerable proportion of pores of TEM could otherwise be seated against impermeable zones of this material.
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Of course, the electroviscosity depends on the pore size, surface charge density and the electrolyte concentration. The indicated correction magnitude corresponds to the properties of membranes used in this study
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Of course, the electroviscosity depends on the pore size, surface charge density and the electrolyte concentration. The indicated correction magnitude corresponds to the properties of membranes used in this study.
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The electrode potential is controlled by the salt concentrations in the feed and the permeate compartments. After pressure switch-off, the permeate concentration ultimately changes due to the salt diffusion through the membrane. However, in our setup, this takes quite a long time (at least 1 h) primarily due to the presence of relatively thick porous support beneath the membrane. Our measurements were essentially shorter up to 100 s
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The electrode potential is controlled by the salt concentrations in the feed and the permeate compartments. After pressure switch-off, the permeate concentration ultimately changes due to the salt diffusion through the membrane. However, in our setup, this takes quite a long time (at least 1 h) primarily due to the presence of relatively thick porous support beneath the membrane. Our measurements were essentially shorter (up to 100 s).
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The fact that the fluctuations decayed more rapidly in the more concentrated solution (lower electrical resistance) can be an indication of their appearance due to the presence of some parasitic inductivities and capacities in our system
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The fact that the fluctuations decayed more rapidly in the more concentrated solution (lower electrical resistance) can be an indication of their appearance due to the presence of some parasitic inductivities and capacities in our system.
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