Latent catalytic systems for ring-opening metathesis-based thermosets

Journal of Thermal Analysis and Calorimetry

Volumn 96, Issue 3, 2009, Pages 705-713

  Mauldin, T C ^a   Kessler, M R ^b  

^a IOWA STATE UNIVERSITY   (United States)

^b Iowa State University of Science and Technology   (United States)

Author keywords

Curing kinetics; Grubbs catalysts; Ozawa Flynn Wall isoconversional model free approach; Ring opening metathesis polymerization

Indexed keywords

AMBIENT TEMPERATURES; CATALYTIC SYSTEM; CURING KINETICS; GLASS TRANSITION TEMPERATURE; GRUBBS CATALYSTS; HIGH TEMPERATURE; MODEL SYSTEM; OZAWA-FLYNN-WALL ISOCONVERSIONAL MODEL-FREE APPROACH; POLYDICYCLOPENTADIENE; RING OPENING METATHESIS; RING-OPENING METATHESIS POLYMERIZATION;

CATALYSIS; CATALYST ACTIVITY; CURING; DIFFERENTIAL SCANNING CALORIMETRY; GLASS TRANSITION; LIGHT MEASUREMENT; POLYMERS; SYNTHESIS (CHEMICAL); THERMOSETS;

RING OPENING POLYMERIZATION;

EID: 68349096297     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-009-0039-y     Document Type: Article

References (24)

1. Ivin KJ, Mol JC. Olefin metathesis, metathesis polymerization. San Diego, CA: Academic Press; 1997.
2. CW Bielawski RH Grubbs 2007 Living ring-opening metathesis polymerization Prog Polym Sci 32 1 29
3. RH Grubbs W Tumas 1989 Polymer synthesis and organotransition metal chemistry Science 243 907 15
4. AM Rouhi 2002 Olefin metathesis: big-deal reaction Chem Eng News 80 29 33
5. AM Rouhi 2002 Olefin metathesis: the early days Chem Eng News 80 34 8
6. ST Nguyen LK Johnson RH Grubbs 1992 Ring-opening metathesis polymerization (ROMP) of norbornene by a group VIII carbene complex in protic media J Am Chem Soc 114 3974 5
7. ST Nguyen RH Grubbs 1993 Syntheses and activities of new single-component, ruthenium-based olefin metathesis catalysis J Am Chem Soc 115 9858 9
8. EL Dias ST Nguyen RH Grubbs 1997 Well-defined ruthenium olefin metathesis catalysts: mechanism and activity J Am Chem Soc 119 3887 97
9. RH Grubbs 2006 Olefin-metathesis catalysts for the preparation of molecules and materials Angew Chem Int Ed 45 3760 5
10. M Scholl S Ding WL Choon RH Grubbs 1999 Synthesis and activity of a new generation of ruthenium-based olefin metathesis catalysts coordinated with 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ligands Org Lett 1 953 6
11. AS Jones JD Rule JS Moore SR White NR Sottos 2006 Catalyst morphology and dissolution kinetics for self-healing polymers Chem Mater 18 1312 7
12. MS Sanford JA Love RH Grubbs 2001 A versatile precursor for the synthesis of new ruthenium olefin metathesis catalysts Organometallics 20 5314 8
13. SL Bolton JE Williams MB Sponsler 2007 Stablilization of (Trialkylphosphine)ruthenium alkylidene metathesis catalysts using phosphine exchange Organometallics 26 2485 7
14. T Ozawa 1965 A new method for analyzing thermogravimetric data Bull Chem Soc Jpn 38 1881 6
15. JH Flynn LA Wall 1966 A quick, direct method for the determination of activation energy from thermogravimetric data Polym Lett 4 323 8
16. MS Sanford JA Love RH Grubbs 2001 Mechanism and activity of ruthenium olefin metathesis catalysis J Am Chem Soc 123 6543 54
17. SH Hong MW Day RH Grubbs 2004 Decomposition of a key intermediate in ruthenium-catalyzed olefin metathesis reactions J Am Chem Soc 126 7414 5
18. SH Hong AG Wenzel TT Salguero MW Day RH Grubbs 2007 Decomposition of ruthenium olefin metathesis catalysts J Am Chem Soc 129 7961 8
19. Metton® and Telene® brochures. Brochures downloaded from http://www.metton.com and http://www.telene.com.
20. MS Sanford M Ulman RH Grubbs 2001 New insights into the mechanism of ruthenium-catalyzed olefin metathesis reactions J Am Chem Soc 123 749 50
21. CW Bielawski RH Grubbs 2000 Highly efficient ring-opening metathesis polymerization (ROMP) using new ruthenium catalysts containing N-heterocyclic carbene ligands Angew Chem Int Ed 39 2903 6
22. MR Kessler SR White 2002 Cure kinetics of the ring-opening metathesis polymerization of dicyclopentadiene J Polym Sci Part A 40 2373 83
23. T-L Choi RH Grubbs 2003 Controlled living ring-opening-metathesis polymerization by a fast-initiating ruthenium catalyst Angew Chem Int Ed 42 1743 6
24. Crabtree RH, editor. The organometallic chemistry of the transition metals. 4th ed. New York: John Wiley and Sons; 2005. p. 104-11.