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Single crystal X-ray structure determination of compound 1-CH 2Cl2: C34H27Cl4PPd, Mr, 714.75, red plate (0.08 x 0.15 x 0.20 mm3, orthorhombic, Pca21 (No. 29, a, 20.2199(4) À,è, 17.5722(4) Å, c, 16.9145(4) Å, V, 6009.9(2) Å3, Z, 8, dcalcd, 1.580 g cm-3, F00O, 2880,/i, 8.934mm -1, Rl, 0.0369[I0 > 2CT(/0, WR2, 0.0949 (all data, GOF, 1.029. For detailed information see the Supporting Information. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-736813. Copies of the data can be obtained free of charge on application to the CCDC, 12 Union Road, Cambridge CB2 IEZ, U.K, fax, 44)1223-336-033; e-mail, deposit@ccdc.cam.ac.uk
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-1, Rl = 0.0369[I0 > 2CT(/0)],WR2 = 0.0949 (all data), GOF = 1.029. For detailed information see the Supporting Information. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-736813. Copies of the data can be obtained free of charge on application to the CCDC, 12 Union Road, Cambridge CB2 IEZ, U.K. (fax, (+44)1223-336-033; e-mail, deposit@ccdc.cam.ac.uk.
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In the 31P NMR spectrum a singlet at 27.0 ppm was observed, which is in the range typical for [cw-(carbene)(PPh3)PdCl 2] complexes
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2] complexes.
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