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Volumn 28, Issue 15, 2009, Pages 4254-4257

Complexation of (5H)-dibenzo[a,d]cyclohepten-5-ylidene to palladium (II) via the diazo route and evidence of C-H... Pd interactions

Author keywords

[No Author keywords available]

Indexed keywords

CARBENE COMPLEXES; CARBOCYCLIC RINGS; CYCLOHEPTENE; HIGH YIELD; PALLADIUM PRECURSORS; SPECTROSCOPIC TECHNIQUE;

EID: 68149167927     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900266z     Document Type: Article
Times cited : (30)

References (77)
  • 50
    • 68149158540 scopus 로고    scopus 로고
    • W. M. Jones' versatile approach of transmetalation of cycloheptatrienyllithium with suitable transition-metal halides and transformation into carbene complexes by subsequent hydride abstraction has been reported for W, Fe, Ru, and Pt but not yet for Pd.
    • W. M. Jones' versatile approach of transmetalation of cycloheptatrienyllithium with suitable transition-metal halides and transformation into carbene complexes by subsequent hydride abstraction has been reported for W, Fe, Ru, and Pt but not yet for Pd.
  • 63
    • 0001089904 scopus 로고
    • For an overview see: a
    • For an overview see: (a) Sutton, D. Chem. Rev. 1993, 93, 995.
    • (1993) Chem. Rev , vol.93 , pp. 995
    • Sutton, D.1
  • 70
    • 68149092172 scopus 로고    scopus 로고
    • Single crystal X-ray structure determination of compound 1-CH 2Cl2: C34H27Cl4PPd, Mr, 714.75, red plate (0.08 x 0.15 x 0.20 mm3, orthorhombic, Pca21 (No. 29, a, 20.2199(4) À,è, 17.5722(4) Å, c, 16.9145(4) Å, V, 6009.9(2) Å3, Z, 8, dcalcd, 1.580 g cm-3, F00O, 2880,/i, 8.934mm -1, Rl, 0.0369[I0 > 2CT(/0, WR2, 0.0949 (all data, GOF, 1.029. For detailed information see the Supporting Information. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-736813. Copies of the data can be obtained free of charge on application to the CCDC, 12 Union Road, Cambridge CB2 IEZ, U.K, fax, 44)1223-336-033; e-mail, deposit@ccdc.cam.ac.uk
    • -1, Rl = 0.0369[I0 > 2CT(/0)],WR2 = 0.0949 (all data), GOF = 1.029. For detailed information see the Supporting Information. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-736813. Copies of the data can be obtained free of charge on application to the CCDC, 12 Union Road, Cambridge CB2 IEZ, U.K. (fax, (+44)1223-336-033; e-mail, deposit@ccdc.cam.ac.uk.
  • 73
    • 68149091872 scopus 로고    scopus 로고
    • In the 31P NMR spectrum a singlet at 27.0 ppm was observed, which is in the range typical for [cw-(carbene)(PPh3)PdCl 2] complexes
    • 2] complexes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.