Alternating ring-opening metathesis copolymerization of amino acid derived norbornene monomers carrying nonprotected carboxy and amino groups based on acid-base interaction

Journal of the American Chemical Society

Volumn 131, Issue 30, 2009, Pages 10546-10551

  Sutthasupa, Sutthira ^a   Shiotsuki, Masashi ^a   Masuda, Toshio ^b   Sanda, Fumio ^a  

^a KYOTO UNIVERSITY   (Japan)

^b FUKUI UNIVERSITY OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACID BASE INTERACTION; ALTERNATING COPOLYMERIZATION; AMINO GROUP; FEED RATIOS; MONOMER CONVERSIONS; MONOMER REACTIVITY RATIOS; MONOMER UNITS; NORBORNENE; RING-OPENING METATHESIS COPOLYMERIZATION; RUTHENIUM CATALYSTS; SECOND GENERATION;

AMINATION; AMINES; AMINO ACIDS; COPOLYMERS; MONOMERS; ORGANIC ACIDS; RUTHENIUM; SYNTHESIS (CHEMICAL);

COPOLYMERIZATION;

ACID; AMINO ACID DERIVATIVE; BASE; CARBOXYL GROUP; COPOLYMER; MONOMER; NORBORNENE DERIVATIVE; RUTHENIUM;

ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONTROLLED STUDY; MOLECULAR INTERACTION; REACTION ANALYSIS; RING OPENING METATHESIS POLYMERIZATION; STRUCTURE ANALYSIS;

AMINES; AMINO ACIDS; CARBOXYLIC ACIDS; HYDROGEN-ION CONCENTRATION; KINETICS; NORBORNANES; POLYMERS; SOLUBILITY;

EID: 68049090030     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja903248c     Document Type: Article

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51. The calculationwas carried out by thesemiempirical molecular orbital method using the AM1 Hamiltonian,running on Wavefunction Inc. Spartan '08 for Windows version 1.1.1.
52. 2Hand-NH-signals coalesced when 1 and 2 were mixed. These results indicate that the carboxy andamino groups of monomers 1 and 2 undergoan acid/base interaction.