Kinetics and reactivities of ruthenium(III)- and osmium(VIII)-catalyzed oxidation of ornidazole with chloramine-T in acid and alkaline media: A mechanistic approach

Journal of Molecular Catalysis A: Chemical

Volumn 310, Issue 1-2, 2009, Pages 24-33

  Puttaswamy, ^a   Sukhdev, Anu ^a   Shubha, J P ^a  

^a BANGALORE UNIVERSITY   (India)

Author keywords

Chloramine T; Ornidazole oxidation; Ru(III) and Os(VIII) catalysis

Indexed keywords

ACID MEDIUM; ACTIVATION PARAMETER; ALKALINE MEDIA; ALKALINE MEDIUM; ANTIPARASITIC DRUGS; CATALYTIC CONSTANTS; CATALYZED OXIDATION; CATALYZED REACTIONS; CHLORAMINE-T; EXPERIMENTAL CONDITIONS; GC-MS ANALYSIS; KINETIC PATTERNS; KINETICS OF OXIDATION; LITERATURE SURVEY; NITROIMIDAZOLE; ORNIDAZOLE OXIDATION; OXIDATION PRODUCTS; PLATINUM GROUP METALS; PLAUSIBLE MECHANISMS; RATE LAWS; RELATIVE RATES; RU(III) AND OS(VIII) CATALYSIS; SOLVENT ISOTOPE EFFECTS; UNCATALYZED REACTIONS; WIDE SPECTRUM;

ACIDS; AMINATION; BIOLOGICAL SYSTEMS; CATALYSIS; CATALYSTS; ISOMERS; ISOTOPES; METAL IONS; OSMIUM; PLATINUM; REACTION KINETICS; REDOX REACTIONS; RUTHENIUM; RUTHENIUM COMPOUNDS; TRACE ANALYSIS;

OXIDATION;

EID: 68049085581     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2009.05.015     Document Type: Article

References (44)

1. Campbell M.M., and Johnson G. Chem. Rev. 78 (1978) 65-79
2. Banerji K.K., Jayaram B., and Mahadevappa D.S. J. Sci. Ind. Res. 46 (1987) 65-76
3. Agarwal M.C., and Upadhyay S.K. J. Sci. Ind. Res. 49 (1990) 13-24
4. Armesto X.L., Canle L., Garia M.V., and Santaballa J.A. Chem. Soc. Rev. 27 (1998) 453-460
5. Kolvari E., Ghorbani-Choghamarani A., Salehi P., Shirini F., and Zolfigol M.A. J. Iran. Chem. Soc. 4 (2007) 126-174
6. Murthy A.R.V., and Rao B.S. Proc. Indian Acad. Sci. 35 (1952) 69-70
7. Rangappa K.S., Manjunathaswamy K., Raghavendra M.P., and Gowda N.M.M. Int. J. Chem. Kinet. 34 1 (2002) 49-55
8. Kombo N., and Upadhyay S.K. Indian J. Chem. 43A (2004) 1210-1215
9. Saldanha R.J.D., Ananda S., Venkatesha B.M., and Gowda N.M.M. J. Mol. Struct. 606 (2002) 147-154
10. Hegde A.C., and Gowda B.T. Oxid. Commun. 23 (2000) 546-564
11. Puttaswamy, Jagadeesh R.V., Nirmala V., and Radhakrishna A. J. Mol. Catal. A: Chem. 229 (2005) 211-220
12. Puttaswamy, Vinod K.N., and Ninge Gowda K.N. Dyes Pigments 78 (2008) 131-138
13. The Extra Pharmacopoeia 29th ed., The Royal Pharmaceutical Society, London, 1989, pp. 674-675.
14. Hizarciolu S.Y., Zeynep A.Y., Ozyazicim M., and Fabad. J. Pharm. Sci. 29 (2004) 133-144
15. Mruthyunjayaswamy B.H.M., Patil S.M.M., and Raju S.A. J. Indian Chem. Soc. 81 (2004) 346-348
16. Ozkan S.A., Senturk Z., and Biyol I. Int. J. Pharm. 157 2 (1997) 137-144
17. Yi Lv., Zhang Z., Deyong H.E., and Yufei H.U. Anal. Sci. 19 4 (2003) 625-627
18. Bhat K.R., Jyothi K., and Gowda B.T. Oxid. Commun. 25 (2002) 117-124 and references therein
19. Jagadeesh R.V., and Puttaswamy. J. Phys. Org. Chem. 21 (2008) 844-858
20. Cotton F.A., Wilkinson G., Murillo C.A., and Bochmann M. Advanced Inorganic Chemistry. 6th ed. (1999), John-Wiley and Sons. Inc., New York
21. Griffith W.P. The Chemistry of Rare Platinum Metals (1967), InterScience, New York
22. Morris J.C., Salazar J.A., and Wineman M.A. J. Am. Chem. Soc. 70 (1948) 2036-2041
23. Bishop E., and Jennings V.J. Talanta 1 (1958) 197-212
24. Hardy F.F., and Johnston J.P. J. Chem. Soc., Perkin Trans. II (1973) 742-746
25. Pryde B.G., and Soper F.G. J. Chem. Soc. (1962) 1582-1588 (1931) 1514-1520
26. Valdes-Santurio J.R., Martinez-Perez J.A., Lopez P.B., and Martinez M.C. STP-Pharma Sci. 5 5 (1995) 391-395
27. Bakshi M., Singh B., Singh A., and Singh S. J. Pharm. Biomed. Anal. 26 (2001) 891-897
28. Soper F.G. J. Chem. Soc. (1942) 1899
29. Narayanan S.S., and Rao V.R.S. Radio Chim. Acta 32 (1983) 211-212
30. Subhashini M., Subramanian M., and Rao V.R.S. Talanta 32 (1985) 1082-1083
31. Cady H.H., and Connick R.E. J. Am. Chem. Soc. 80 (1958) 2646-2652
32. Connick R.E., and Fine D.A. J. Am. Chem. Soc. 82 (1960) 4187-4191
33. Backhours J.R., Doyer F.D., and Shales N. Proc. Roy. Soc. 83 (1950) 146-155
34. T. Davfokratova, Analytical Chemistry of Ruthenium, Academy of Sciences, USSR, 1963 p. 54, 71, 97.
35. Higuchi T., Ikeda K., and Hussain A. J. Chem. Soc. B (1967) 546
36. Mahadevappa D.S., Jadav M.B., and Naidu H.M.K. Int. J. Chem. Kinet. 11 (1979) 261-273
37. Griffith W.P. Q. Rev. Chem. Soc. 19 (1965) 254-273
38. Mayell J.S. Ind. Eng. Chem. Res. 7 2 (1968) 129-136
39. Rangappa K.S., Ramachandra H., Mahadevappa D.S., and Gowda N.M.M. Int. J. Chem. Kinet. 28 (1996) 265-274
40. Puttaswamy, and Vaz N. Trans. Met. Chem. 28 4 (2003) 409-417
41. Collins C.J., and Bowman N.S. Isotope Effect in Chemical Reactions (1970), Van Nostrand, New York p. 267
42. Kohen A., and Limbach H.H. Isotope Effects in Chemistry and Biology (2006), CRC Press, Florida p. 827
43. Moelwyn-Hughes E.A. The Kinetics of Reaction in Solutions (1947), Oxford University Press, London p. 297
44. Puttaswamy R.V., and Jagadeesh. Int. J. Chem. Kinet. 37 (2005) 201-210