Ruthenium(III)- and osmium(VIII)-catalyzed oxidation of 2-thiouracil by bromamine-B in acid and alkaline media: A kinetic and mechanistic study

Transition Metal Chemistry

Volumn 28, Issue 4, 2003, Pages 409-417

  Swamy, Putta ^a   Vaz, Nirmala ^a  

^a BANGALORE UNIVERSITY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CATALYSIS; CATALYST ACTIVITY; CHEMICAL ACTIVATION; HYDROCHLORIC ACID; OSMIUM; OXIDATION; PHASE EQUILIBRIA; RATE CONSTANTS; RUTHENIUM; SODIUM COMPOUNDS; STOICHIOMETRY;

BROMAMINE; CATALYZED OXIDATION; EQUILIBRIUM CONSTANTS; SOLVENT ISOTOPE EFFECTS; THIOURACIL;

NITROGEN COMPOUNDS;

EID: 0037526294     PISSN: 03404285     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1023624911189     Document Type: Article

References (48)

1. M.M. Campbell and G. Johnson, Chem. Rev., 78, 65 (1978)
2. K.K. Banerji., B. Jayaram and D.S. Mahadevappa, J. Sci. Ind. Res., 46, 65 (1987)
3. H. Ramachandra, K.S. Rangappa and D.S. Mahadevappa, J. Phys. Org. Chem., 9, 439 (1996)
4. P. Swamy and T.M. Anuradha, Proc. Indian Acad. Sci. (Chem. Sci.), 111, 601 (1999).
5. F.F. Hardy and J.P. Johnson, J. Chem. Soc., Perkin Trans. 2, 742 (1973)
6. F. Ruff and A. Kucsman, J. Chem. Soc., Perkin Trans., 2, 1075 (1982)
7. P. Swamy and D.S. Mahadevappa, J. Phys. Org. Chem., 2, 660 (1989)
8. P. Swamy and R. Ramachandrappa, Transition Met. Chem., 24, 52 (1999)
9. P. Swamy, N. Vaz and N.M. Made Gowda, Int. J. Chem. Kinet., 33, 480 (2001).
10. D.S. Tarbell and N. Kharasch (Ed.) Organic Sulphur Compounds, Pergamon Press, New York, 1961. p. 97
11. D.A. Dixon, T.P. Dasgupta and N.P. Sadler, Inorg. React. Mech., 1, 41 (1988).
12. D.S. Mahadevappa, Curr. Sci. (India), 34, 530 (1973)
13. N.M. Made Gowda, A.S. Ananda Murthy and D. S. Mahadevappa, Curr. Sci. (India), 44, 5 (1975)
14. D.K. Padma, R.A. Shaw, A.R.V. Murthy and M. Woods, Int. J. Sulphur Chem., 1, 243 (1971).
15. Astwood, J. Pharmacol Exptl. Therap. 78, 79 (1943)
16. Astwood, Endocrinology, 37, 456 (1945)
17. Astwood and Mackenzies, Endocrinology, 37, 185 (1943).
18. T.K. Kagiya, R. Kimura, C. Komuro, K. Sukano and S. Nishimoto, Chem. Lett. 1471 (1983)
19. L.R. Subbaraman, J. Subbaraman and E.J. Behrman, J. Org. Chem., 38, 1499 (1973).
20. H.M.K. Naidu, S.N. Katgeri and D.S. Mahadevappa, Z. Phys. Chemie., Leipzig, 264, 469 (1983)
21. D.L. Kamble and S.T. Nandibewoor, J. Phys. Org. Chem., 11, 171 (1998)
22. P. Swamy and N. Vaz, Stud. Surf. Sci. Cat., 133, 535 (2001).
23. M.S. Ahmed and D.S. Mahadevappa, Talanta, 27, 669 (1980).
24. D.S. Mahadevappa and N.M. Made Gowda, Talanta, 22, 771 (1975).
25. A.H. Gordon, Biochem. J., 45, 99 (1949).
26. D.L. Small, J.H. Bailey and G.J. Cavallito, J. Am. Chem. Soc., 69, 1711 (1947)
27. D.T. McAllan, T.V. Cullum, R.A. Dean and F.A. Fidler, J. Am. Chem. Soc., 73, 3629 (1951)
28. D.S. Mahadevappa, and N.M. Made Gowda, Talanta, 22, 771 (1975)
29. Z. Abedinzadeh, M.G. Albert and C. Ferradini, Can. J. Chem., 67, 1247 (1989).
30. H.H. Cady and R.E. Connick, J. Am. Chem. Soc., 80, 2646 (1958).
31. R.E. Connick and D.A. Fine, J. Am. Chem. Soc., 82, 4187 (1960).
32. J.R. Backhours, F.D. Doyer and N. Shales, Proc. Roy. Soc., 83, 146 (1950).
33. T. Davfokratova, Analytical Chemistry of Ruthenium, Academy of Sciences, USSR, 1963, p. 54, 71 and 97.
34. W.P. Griffith, The Chemistry of Rare Platinum Metals, Interscience, New York, 1967, p. 141.
35. B. Singh, N.B. Singh and B.B. Saxena, J. Indian Chem. Soc., 61, 319 (1984).
36. B. Singh, P.K. Singh and D. Singh, J. Mol. Cat., 78, 207 (1988).
37. S. Ananda, B.M. Venkatesha, D.S. Mahadevappa and N.M. Made Gowda, Int. J. Chem Kinet., 25, 755 (1993).
38. P. Swamy, N. Vaz and H. Ramalingaiah, Synth. React. Inorg. Met.-Org Chem., 30, 1667 (2000).
39. D.R. Pryde and F. G. Soper, J. Chem. Soc., 1510 (1931).
40. J.C. Morris, J.A. Salazar and M.A. Wineman, J. Am. Chem. Soc., 70, 2036 (1948).
41. E. Bishop and V.J. Jennings, Talanta, 1, 197 (1958).
42. F.F. Hardy and J.P. Johnston, J. Chem. Soc. Perkin Trans., 2, 742 (1973).
43. S.S. Narayanan and V.R.S. Rao, Radiochem. Acta, 32, 211 (1983).
44. M. Subhashini, M. Subramanian and V.R.S. Rao, Talanta, 32 1082 (1985).
45. C.J. Collins and N.S. Bowman, Isotope Effects in Chemical Reactions, Van Nostrand Reinhold, New York, 1970, p. 267.
46. K.M. Mackay and R.A. Mackay, Introduction to Modern Inorganic Chemistry, 4th Edit., Prentice Hall, Englewood Cliffs, NJ, 1989, p. 259.
47. F.A. Cotton, G. Wilkinson and P.L. Gaus, Basic Inorganic Chemistry, 3rd Edit., Wiley and Sons, Inc., New York, 1995, p. 600.
48. R.D. Saverbrum and E.B. Sandell, J. Am. Chem. Soc., 75, 4170 (1953).