Ru(III)-catalysed oxidation of some N-heterocycles by chloramine-T in hydrochloric acid medium: A kinetic and mechanistic study

Journal of Molecular Catalysis A: Chemical

Volumn 229, Issue 1-2, 2005, Pages 211-220

  Puttaswamy, ^a   Jagadeesh, R V ^a   Vaz, Nirmala ^a   Radhakrishna, A ^b  

^a BANGALORE UNIVERSITY   (India)

^b SHRIRAM INSTITUTE FOR INDUSTRIAL RESEARCH   (India)

Author keywords

Chloramine T; N heterocycles; Oxidation kinetics; Ru(III) catalysis

Indexed keywords

AMINES; CATALYSIS; DIELECTRIC PROPERTIES; ENTHALPY; ENTROPY; HYDROCHLORIC ACID; IONIC STRENGTH; IONS; OXIDATION; REACTION KINETICS;

HALIDE IONS; ISOKINETIC TEMPERATURE; N-HETEROCYCLES; OXIDATION REACTION;

RUTHENIUM COMPOUNDS;

2 AMINOBENZIMIDAZOLE; 2 HYDROXYBENZIMIDAZOLE; BENZIMIDAZOLE; BENZIMIDAZOLE DERIVATIVE; CHLORINE; HALIDE; HETEROCYCLIC COMPOUND; HYDROCHLORIC ACID; IMIDAZOLE; PHENZIDOLE; REACTIVE OXYGEN METABOLITE; RUTHENIUM; RUTHENIUM CHLORIDE; RUTHENIUM DERIVATIVE; TOLUENESULFONAMIDE DERIVATIVE; TOSYLCHLORAMIDE SODIUM; UNCLASSIFIED DRUG; WATER;

ANALYTIC METHOD; ARTICLE; CALCULATION; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL REACTION KINETICS; CORRELATION ANALYSIS; ELECTRICITY; ENTHALPY; ENTROPY; EVALUATION; EXPERIMENT; IONIC STRENGTH; MEASUREMENT; MECHANICS; OXIDATION; PARAMETER; REACTION ANALYSIS; TEMPERATURE;

EID: 13444274590     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2004.10.057     Document Type: Article

References (44)

1. R.J. Sundberg, and R.B. Martin Chem. Rev. 74 1974 471
2. P. Preston Chem. Rev. 74 1974 279
3. G.A. Novikova, A.K. Molodkin, and S.S. Kukelenko Russ. J. Inorg. Chem. 33 1988 1794
4. J.B. Wright The chemistry of the benzimidazoles Chem. Rev. 48 1951 520 524 and references therein
5. N. Shashikala, E.G. Leelamani, and G.K.N. Reddy Ind. J. Chem. 21A 1982 743
6. V. Gayathri, E.G. Leelamani, N.M.N. Gowda, and G.K.N. Reddy Transit. Met. Chem. 25 2000 450 and references therein
7. S. Rekha, and K.R. Nagasundar Asian J. Chem. 15 2 2003 987
8. N.C. Subramanyam, and S.M. Mayanna Corros. Sci. 25 3 1985 163
9. F.X. Perrin, and J.P. Pagatti Corros. Sci. 40 1998 1647
10. J.B. Wright The chemistry of the benzimidazoles Chem. Rev. 48 1951 517 519 and references therein
11. M.M. Campbell, and G. Johnson Chem. Rev. 78 1978 65
12. D.H. Bremner Synth. Reag. 6 1984 9
13. K.K. Banerji, B. Jayaram, and D.S. Mahadevappa J. Sci. Ind. Res. 46 1987 65
14. K.S. Rangappa, M.P. Raghavendra, and D.S. Mahadevappa J. Carbohydr. Chem. 26 3 1997 359
15. Puttaswamy, T.M. Anuradha, R. Ramachandrappa, and N.M.M. Gowda Int. J. Chem. Kinet. 32 4 2000 221
16. R.J.D. Saldanha, S. Ananda, B.M. Venkatesha, and N.M.M. Gowda J. Mol. Structr. 606 2002 147
17. G. Akerloff J. Am. Chem. Soc. 54 1932 4125
18. F.F. Hardy, and J.P. Johnson J. Chem. Soc. Perkin Trans. 2 1973 742
19. B.G. Pryde, and F.G. Soper J. Chem. Soc. 1926 1582
20. E. Bishop, and V.J. Jennings Talanta 1 1958 197
21. H.H. Cady, and R.E. Connick J. Am. Chem. Soc. 80 1958 2646
22. R.E. Connick, and D.A. Fine J. Am. Chem. Soc. 82 1960 4187
23. J.R. Backhours, F.D. Doyer, and N. Shales Proc. Royal Soc. 83 1950 146
24. T. Davfokratova, Analytical Chemistry of Ruthenium, Academy of Sciences, USSR, 1963, p. 54, 71 and 97.
25. W.P. Griffith The Chemistry of Rare Platinum Metals 1967 Interscience New York p. 141
26. B. Singh, N.B. Singh, and B.B. Sexena J. Ind. Chem. Soc. 61 1984 319
27. B. Singh, P.K. Singh, and D. Singh J. Mol. Catal. 78 1988 207
28. S. Ananda, B.M. Venkatesha, D.S. Mahadevappa, and N.M.M. Gowda Int. J. Chem. Kinet. 25 1993 755
29. Puttaswamy, and R. Ramachandrappa Transit. Met. Chem. 24 1996 326
30. S. Ananda, M.B. Jagadeesha, Puttaswamy, and N.M.M. Gowda Synth. React. Met-Org. Chem. 27 1997 1093
31. C.J. Collins, and N.S. Bowman Isotope Effects in Chemical Reactions 1970 Van Nostrand Reinhold New York p. 267
32. K.B. Wiberg Chem Rev. 55 1955 713
33. K.B. Wiberg Physical Organic Chemistry 1964 Wiley New York
34. K.J. Laidler, and H. Eyrings Am. N.Y. Acad. Sci. 39 1940 303
35. K.J. Laidler Reaction Kinetics 1963 Pergamon New York
36. E.S. Emis Solvent Effects on Reaction Rates and Mechanisms 1966 Academic Press New York
37. O. Exner Coll. Czech Chem. Commun. 29 1964 1094
38. Puttaswamy, and D.S. Mahadevappa J. Phys. Org. Chem. 2 1989 660
39. K.K. Senguptha, N. Bhattacharjee, and B. Pal Transit. Met. Chem. 24 1999 268
40. Puttaswamy, and N. Vaz Bull. Chem. Soc. Jpn. 76 2003 73
41. E.A. Moelwyn-Hughes Kinetics of Reaction in Solutions 1947 Oxford University Press London pp. 297-299
42. J.C. Morris, J.A. Salazar, and M.A. Wineman J. Am. Chem. Soc. 70 1948 2036
43. F. Feigl Spot Tests in Organic Analysis 7th ed. 1966 Elsevier Amsterdam pp. 510-512
44. F. Feigl Spot Tests in Organic Analysis 7th ed. 1966 Elsevier Amsterdam pp. 498-500