Shuttling germanium atoms into branched polysilanes

Journal of the American Chemical Society

Volumn 131, Issue 14, 2009, Pages 5022-5023

  Wagner, Harald ^a,b,c   Baumgartner, Judith ^a,b,c   Müller, Thomas ^a,b   Marschner, Christoph ^a,b,c  

^a GRAZ UNIVERSITY OF TECHNOLOGY   (Austria)

^b UNIVERSITY OF OLDENBURG   (Germany)

^c GRAZ UNIVERSITY OF TECHNOLOGY   (Austria)

Author keywords

[No Author keywords available]

Indexed keywords

CORE PART; LEWIS ACID; OLIGOSILANES; QUANTUM MECHANICAL; REACTION CASCADES; REARRANGEMENT REACTIONS; REPEATED SEQUENCES;

ATOMS; GERMANIUM; POLYSILANES; SEMICONDUCTING GERMANIUM COMPOUNDS; SILANES;

MOLECULES;

DIMETICONE; GERMANIUM; LEWIS ACID;

ARTICLE; ATOM; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; HYDROGEN BOND; QUANTUM MECHANICS; THERMODYNAMICS;

EID: 67849130867     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja809270m     Document Type: Article

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17. All computations were done using the Gaussian 03 package: Frisch, M. J.; et al. Gaussian 03, revision D.01; Gaussian, Inc.: Pittsburgh, PA, 2003. For details, see the Supporting Information.
18. The results of calculations (ref 14 on p S-30 in the Supporting Information) suggest that 1,3-methyl-bridged compounds do not play a significant role in this rearrangement.