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Volumn 131, Issue 12, 2009, Pages 4210-4211

Magnesium-magnesium bond stabilized by a doubly reduced α-diimine: Synthesis and structure of [K(THF)3]2[LMg-MgL] (L ) [(2,6-iPr2C6H3)NC(Me)] 22-

Author keywords

[No Author keywords available]

Indexed keywords

DIIMINE; DIIMINE LIGAND; SINGLE CRYSTAL X-RAY DIFFRACTION;

EID: 67849102051     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja900568c     Document Type: Article
Times cited : (115)

References (20)
  • 5
    • 53249115651 scopus 로고    scopus 로고
    • and references therein. For Zn-Zn bonding, also see: b
    • For Zn-Zn bonding, also see: (b) Carmona, E.; Galindo, A. Angew. Chem., Int. Ed. 2008, 47, 6526-6536, and references therein.
    • (2008) Angew. Chem., Int. Ed , vol.47 , pp. 6526-6536
    • Carmona, E.1    Galindo, A.2
  • 14
    • 67849135324 scopus 로고    scopus 로고
    • Synthesis of 3: Potassium (0.15 g, 3.91 mmol) was added to a mixture of L (0.50 g, 1.24 mmol) and MgCl2 (0.14 g, 1.26 mmol) in THF, and the suspension was stirred for 3 days. The reaction mixture was filtered, and the filtrate was concentrated to ∼30 mL and stored at ca, 20 °C for several days to yield 3 as pink crystals (0.45 g, 48, 1H NMR (400 MHz, C6D6, δ 1.10 (m, 24H, CH(CH3)2, 1.21 (m, 24H, CH(CH3)2, 1.40 (THF, 1.84 (s, 12H, CCH3, 3.56 (THF, 3.90 (m, 8H, CH(CH 3)2, 6.63 (m, 4H, p-ArH, 6.91 m, 8 H, m-ArH
    • 2), 6.63 (m, 4H, p-ArH), 6.91 (m, 8 H, m-ArH).
  • 15
    • 67849120738 scopus 로고    scopus 로고
    • int = 0.0365), 5708 observed [I > 2δ(I)]; R1 = 0.0633, wR2 = 0.1723.
    • int = 0.0365), 5708 observed [I > 2δ(I)]; R1 = 0.0633, wR2 = 0.1723.
  • 18
    • 67849126115 scopus 로고    scopus 로고
    • The structure optimization and NBO bonding analysis of the model compound were carried out at the B3LYP level with a DZP, basis set using the Gaussian 03 program full citation in the Supporting Information
    • The structure optimization and NBO bonding analysis of the model compound were carried out at the B3LYP level with a DZP++ basis set using the Gaussian 03 program (full citation in the Supporting Information).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.