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Ru-catalyzed β-allyl elimination: Kondo, T.; Kodoi, K.; Nishinaga, E.; Okada, T.; Morisaki, Y.; Watanabe, Y.; Mitsudo, T.-a. J. Am. Chem. Soc. 1998, 120, 5587.
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1342302388
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Metal-catalyzed ring openings via β-elimination of tert-cyclobutanols: (a) Nishimura, T.; Uemura, S. Synlett 2004, 201 and references therein.
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β-Aryl eliminations from isolated Rh(I) iminyl complexes: Zhao, P.; Hartwig, J. F. J. Am. Chem. Soc. 2005, 127, 11618.
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33644959871
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note
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2Ph, at 20-80 °C led to no reaction.
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-
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23
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33644944713
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note
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2Ph] product.
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24
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33644940375
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note
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Both β-phenyl elimination and ring opening C-C cleavage have been reported in relevant Pd-catalyzed processes; see refs 5a-c.
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-
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25
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33644961270
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note
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See Supporting Information for details. Complex 4 underwent slow aromatic C-H exchange with benzene as well as the aromatic ketone products. See ref 8 for an analogous observation.
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26
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See for example: Kegley, S. E.; Schaverien, C. J.; Freudenberger, J. H.; Bergman, R. G. J. Am. Chem. Soc. 1987, 109, 6563.
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Kegley, S.E.1
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Nishihara, Y.; Yoda, C.; Osakada, K. Organometallics 2001, 20, 2124.
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Nishihara, Y.1
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28
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0035477045
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A Pd-C distance of 2.34 Å was measured for a cationic Pd(II) complex stabilized by an interaction with the ipso carbon of a phenyl group: Cámpora, J.; Gutiérrez-Puebla, E.; López, J. A.; Monge, A.; Palma, P.; del Río, D.; Carmona, E. Angew. Chem., Int. Ed. 2001, 40, 3641.
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Monge, A.4
Palma, P.5
Del Río, D.6
Carmona, E.7
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3142663134
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For a recent review, see: Scherer, W.; McGrady, G. S. Angew. Chem., Int. Ed. 2004, 43, 1782.
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Scherer, W.1
McGrady, G.S.2
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Urtel, H.; Meier, C.; Eisenträger, F.; Rominger, F.; Joschek, J. P.; Hofmann, P. Angew. Chem., Int. Ed. 2001, 40, 781.
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0000918807
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Hartley, F. R., Patai, S., Eds.; John Wiley: New York
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(a) Cross, R. J. In The Chemistry of the Metal-Carbon Bond; Hartley, F. R., Patai, S., Eds.; John Wiley: New York, 1985; Vol. 2, p 559.
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8344267913
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(b) For a more recent study, see: Vela, J.; Vaddadi, S.; Cundari, T. R.; Smith, J. M.; Gregory, E. A.; Lachicotte, R. J.; Flaschenriem, C. J.; Holland, P. L. Organometallics 2004, 23, 5226.
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Lachicotte, R.J.6
Flaschenriem, C.J.7
Holland, P.L.8
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33
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(c) For β-hydrogen elimination from alkoxo and amido complexes by a migratory deinsertion mechanism, see ref 6d and Hartwig. J. F. J. Am. Chem. Soc. 1996, 118, 7010.
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Hartwig, J.F.1
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