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Volumn 128, Issue 10, 2006, Pages 3124-3125

Direct observation of β-aryl eliminations from Rh(I) alkoxides

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; KETONE DERIVATIVE; OXIDE; RHODIUM;

EID: 33644938378     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja058550q     Document Type: Article
Times cited : (121)

References (33)
  • 1
    • 27644557202 scopus 로고    scopus 로고
    • For recent reviews on transition-metal-catalyzed transformations that involve β-hydrocarbyl eliminations, see: (a) Satoh, T.; Miura, M. Top. Organomet. Chem. 2005, 14, 1.
    • (2005) Top. Organomet. Chem. , vol.14 , pp. 1
    • Satoh, T.1    Miura, M.2
  • 7
    • 1342302388 scopus 로고    scopus 로고
    • and references therein
    • Metal-catalyzed ring openings via β-elimination of tert-cyclobutanols: (a) Nishimura, T.; Uemura, S. Synlett 2004, 201 and references therein.
    • (2004) Synlett , pp. 201
    • Nishimura, T.1    Uemura, S.2
  • 19
    • 23944510195 scopus 로고    scopus 로고
    • β-Aryl eliminations from isolated Rh(I) iminyl complexes: Zhao, P.; Hartwig, J. F. J. Am. Chem. Soc. 2005, 127, 11618.
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 11618
    • Zhao, P.1    Hartwig, J.F.2
  • 22
    • 33644959871 scopus 로고    scopus 로고
    • note
    • 2Ph, at 20-80 °C led to no reaction.
  • 23
    • 33644944713 scopus 로고    scopus 로고
    • note
    • 2Ph] product.
  • 24
    • 33644940375 scopus 로고    scopus 로고
    • note
    • Both β-phenyl elimination and ring opening C-C cleavage have been reported in relevant Pd-catalyzed processes; see refs 5a-c.
  • 25
    • 33644961270 scopus 로고    scopus 로고
    • note
    • See Supporting Information for details. Complex 4 underwent slow aromatic C-H exchange with benzene as well as the aromatic ketone products. See ref 8 for an analogous observation.
  • 31
    • 0000918807 scopus 로고
    • Hartley, F. R., Patai, S., Eds.; John Wiley: New York
    • (a) Cross, R. J. In The Chemistry of the Metal-Carbon Bond; Hartley, F. R., Patai, S., Eds.; John Wiley: New York, 1985; Vol. 2, p 559.
    • (1985) The Chemistry of the Metal-Carbon Bond , vol.2 , pp. 559
    • Cross, R.J.1
  • 33
    • 0030015257 scopus 로고    scopus 로고
    • (c) For β-hydrogen elimination from alkoxo and amido complexes by a migratory deinsertion mechanism, see ref 6d and Hartwig. J. F. J. Am. Chem. Soc. 1996, 118, 7010.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 7010
    • Hartwig, J.F.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.