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Volumn 82, Issue 7, 2009, Pages 778-792

Metal-mediated retro-allylation of homoallyl alcohols for highly selective organic synthesis

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLATION; ALLYLMETALS; AROMATIC ALDEHYDE; ARYL HALIDES; CARBONYL COMPOUNDS; CROSS COUPLING REACTIONS; ERYTHRO; HOMOALLYL ALCOHOL; IN-SITU; KINETIC CONTROL; ORGANIC SYNTHESIS; PALLADIUM CATALYSIS; PENTAMETHYLCYCLOPENTADIENYL; RETRO-ALLYLATION; REVERSIBLE ADDITION; STEREO-SELECTIVE; TRANSITION STATE; TRANSMETALATION;

EID: 67849088718     PISSN: 00092673     EISSN: 13480634     Source Type: Journal    
DOI: 10.1246/bcsj.82.778     Document Type: Article
Times cited : (75)

References (85)
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    • For convenience, throughout the manuscript, crotylation, methallylation, and prenylation are defined as introductions of 1-methyl-2-propenyl, 2-methyl-2-propenyl, and 1,1-dimethyl-2-propenyl groups, respectively, into a carbonyl group. On the other hand, crotyl, methallyl, and prenyl groups denote herein 2-butenyl, 2-methyl-2-propenyl, and 3-methyl-2-butenyl groups, respectively
    • For convenience, throughout the manuscript, crotylation, methallylation, and prenylation are defined as introductions of 1-methyl-2-propenyl, 2-methyl-2-propenyl, and 1,1-dimethyl-2-propenyl groups, respectively, into a carbonyl group. On the other hand, crotyl, methallyl, and prenyl groups denote herein 2-butenyl, 2-methyl-2-propenyl, and 3-methyl-2-butenyl groups, respectively.
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    • Rh-catalyzed deallylation was recently reported
    • Rh-catalyzed deallylation was recently reported. P. Zhao, C. D. Incarvito, J. F. Hartwig, J. Am. Chem. Soc. 2006, 128, 3124.
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    • Zhao, P.1    Incarvito, C.D.2    Hartwig, J.F.3


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