Combination of spectroscopic methods: In situ NMR and UV/Vis measurements to understand the formation of group 4 metallacyclopentanes from the corresponding metallacyclopropenes

Journal of the American Chemical Society

Volumn 131, Issue 12, 2009, Pages 4463-4469

  Beweries, Torsten ^a   Fischer, Christian ^a   Peitz, Stephan ^a   Burlakov, Vladimir V ^a,b   Arndt, Perdita ^a   Baumann, Wolfgang ^a   Spannenberg, Anke ^a   Heller, Detlef ^a   Rosenthal, Uwe ^a  

^a LEIBNIZ INSTITUT FÜR KATALYSE E V AN DER UNIVERSITÄT ROSTOCK   (Germany)

^b A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEX 1; GROUP 4; IN-SITU; NMR SPECTROSCOPY; REACTION BEHAVIOR; ROOM TEMPERATURE; SPECTROSCOPIC METHOD; TITANOCENE; TRIMETHYLSILYL; UV/ VIS SPECTROSCOPY; X-RAY CRYSTAL STRUCTURE ANALYSIS;

ACETYLENE; CRYSTAL STRUCTURE; ETHYLENE; LIGHTING; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SILICON CARBIDE; ZIRCONIUM; ZIRCONIUM COMPOUNDS;

HAFNIUM;

1 ZIRCONACYCLOPROPENE; 1,2 ETHYLENE 1,1' BIS(MU 5 TETRAHYDROINDENYL); 2 HAFNACYCLOPENTENE; 2 ZIRCONACYCLOPENTENE; 3 ZIRCONACYCLOPENTANE; 4 METALLACYCLOPENTANE; ACETYLENE DERIVATIVE; ACRYLIC ACID; ALKENE; ALKYNE; ALKYNE DERIVATIVE; BIS(TRIMETHYLSILYL)ACETYLENE; CYCLOPENTANE; CYCLOPENTANE DERIVATIVE; ETHYLENE; HAFNACYCLOPENTENE; HAFNACYCLOPROPENE; INDENE DERIVATIVE; LITHIUM; METALLACYCLOPROPENE; PENTANE; PROPYLENE; TITANOCENE DICHLORIDE; UNCLASSIFIED DRUG; ZIRCONIUM DERIVATIVE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPARATIVE STUDY; COMPLEX FORMATION; CONTROLLED STUDY; CRYSTAL STRUCTURE; DECOMPOSITION; IN SITU HYBRIDIZATION; MOLECULAR STABILITY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; ROOM TEMPERATURE; SPECTROSCOPY; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

EID: 67749124314     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja809368s     Document Type: Article

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