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Volumn 46, Issue 26, 2007, Pages 4968-4971

Reactivity of "frustrated Lewis pairs": Three-component reactions of phosphines, a borane, and olefins

Author keywords

Addition; Alkenes; Lewis acids; Lewis bases; Phosphanes

Indexed keywords

BORANE; LEWIS ACIDS; LEWIS BASES; PHOSPHANES;

EID: 34447345148     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200701215     Document Type: Article
Times cited : (394)

References (17)
  • 4
    • 0038109148 scopus 로고    scopus 로고
    • A related reaction of B(C6F5)3 with the ylide Ph3PCHPh was shown to form an adduct and thermally rearrange to the parasubstitution product (Ph3PCHPh)C6F 5BF(C6F5)2, see: S. Doering, G. Erker, R. Froehlich, O. Meyer, K. Bergander, Organometallics 1998, 17, 2183
    • 2, see: S. Doering, G. Erker, R. Froehlich, O. Meyer, K. Bergander, Organometallics 1998, 17, 2183.
  • 9
    • 34447337699 scopus 로고    scopus 로고
    • X-ray data: 1: monoclinic, space group P21/c, a, 11.9532(14, b, 15.3319(18, c, 18.729(2) Å, β, 107.436(2)°, V, 3274.7(7) Å3 Data: 5758, parameters, 458, R, 0.0452, Rw, 0.1046. GOF, 1.017. 3: monoclinic, space group P1, a, 11.352(4, b, 11.609(4, c, 15.623(5) Å, α, 111.445(4, β, 99.753(4, γ, 93.350(4)°, V, 1872.4(11) Å3. Data: 6576, parameters, 507, R, 0.0556, Rw, 0.1515, GOF= 1.005. 4: monoclinic, space group Pc, a =14.994(3, b, 12.770(2, c, 16.538(3) Å β, 94.449(3)°, V, 3157.1(9) Å3. Data: 11 111, parameters: 865, R, 0.0838, Rw, 0.1933, GOF, 1.002
    • w = 0.1933, GOF = 1.002.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.