High lipophilicity of perfluoroalkyl carboxylate and sulfonate: Implications for their membrane permeability

Journal of the American Chemical Society

Volumn 131, Issue 6, 2009, Pages 2290-2296

  Jing, Ping ^a   Rodgers, Patrick J ^a   Amemiya, Shigeru ^a  

^a UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; BIOCHEMISTRY; CAPILLARITY; CELL MEMBRANES; CYCLIC VOLTAMMETRY; DRUG PRODUCTS; ETHYLENE; HYDRATES; HYDROPHILICITY; ORGANIC POLLUTANTS;

ALKYL CHAIN; BILAYER LIPID MEMBRANE; BIOMEDICAL APPLICATIONS; CARBOXYLATE GROUPS; DIFFUSION MODEL; ELECTRON-WITHDRAWING EFFECTS; HOMOLOGOUS SERIES; INDUCTIVE EFFECTS; LIPOPHILIC MEMBRANE; LIPOPHILICITY; MEMBRANE PERMEABILITY; N-OCTANOL; ORDERS OF MAGNITUDE; PARTITION COEFFICIENT; PERFLUROALKYL;

CARBOXYLATION;

ALKYL GROUP; ANION; CARBOXYLIC ACID DERIVATIVE; NONANOIC ACID; OCTANOL; PERFLUORO COMPOUND; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; SULFONIC ACID DERIVATIVE; WATER; ALKANESULFONIC ACID; CARBOXYLIC ACID; ELECTROLYTE; FLUOROCARBON; LIPID BILAYER; SURFACTANT;

ARTICLE; BILAYER MEMBRANE; CONTROLLED STUDY; CYCLIC POTENTIOMETRY; DIFFUSION; HYDROPHILICITY; ION TRANSPORT; LIPID MEMBRANE; LIPOPHILICITY; MEMBRANE PERMEABILITY; PARTITION COEFFICIENT; SOLUBILITY; CHEMICAL MODEL; CHEMICAL PHENOMENA; CHEMISTRY; LIPID BILAYER; PERMEABILITY; THERMODYNAMICS;

1-OCTANOL; ALKANESULFONATES; CARBOXYLIC ACIDS; ELECTROLYTES; FLUOROCARBONS; HYDROPHOBIC AND HYDROPHILIC INTERACTIONS; LIPID BILAYERS; MODELS, CHEMICAL; PERMEABILITY; SURFACE-ACTIVE AGENTS; THERMODYNAMICS; WATER;

EID: 67749106312     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja807961s     Document Type: Article

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