Control of charge transfer phase transition and ferromagnetism by photoisomerization of spiropyran for an organic-inorganic hybrid system, (SP)[FeIIFeIlI(dto)3] (SP = spiropyran, dto = C2O2S2)

Journal of the American Chemical Society

Volumn 131, Issue 1, 2009, Pages 212-220

  Kida, Noriyuki ^a   Hikita, Masanori ^a   Kashima, Izuru ^a   Okubo, Masashi ^b   Itoi, Miho ^c   Enomoto, Masaya ^a   Kato, Kenichi ^d   Takata, Masaki ^d   Kojima, Norimichi ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b CHUO UNIVERSITY   (Japan)

^c AOYAMA GAKUIN UNIVERSITY   (Japan)

^d RIKEN SPring 8 Center ^*  (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION BAND; CHARGE TRANSFER PHASE TRANSITION; CLOSED FORM; FERROMAGNETIC TRANSITION TEMPERATURES; FERROMAGNETIC TRANSITIONS; HEXAGONAL RINGS; HONEYCOMB NETWORKS; MIXED VALENCE COMPLEXES; MIXED VALENCE SYSTEMS; ORGANIC-INORGANIC HYBRID SYSTEMS; PHOTO-IRRADIATION; PHOTO-IRRADIATION TIME; PHOTOINDUCED EFFECTS; SPIN ENTROPY; SPIROPYRAN; UV IRRADIATION;

CHARGE TRANSFER; ELECTRIC GROUNDING; FERROMAGNETIC MATERIALS; FERROMAGNETISM; HYBRID COMPUTERS; HYBRID SYSTEMS; ION EXCHANGE; IRON COMPOUNDS; IRRADIATION; ISOMERIZATION; MAGNETIC PROPERTIES; MASS TRANSFER;

PHASE TRANSITIONS;

IRON; PYRAN DERIVATIVE;

ABSORPTION; ARTICLE; CHEMICAL STRUCTURE; ENTROPY; FORCE; HYBRIDIZATION; ISOMERIZATION; MAGNETISM; PHASE TRANSITION; PHOTOSENSITIVITY; SOLID STATE; SYNTHESIS; TIME; TRANSITION TEMPERATURE; ULTRAVIOLET IRRADIATION;

EID: 67749086558     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja806879a     Document Type: Article

References (63)

1. Tajima, N.; Fujisawa, J.; Naka, N.; Ishihara, T.; Kato, R.; Nishio, Y.; Kajita, K. J. Phys. Soc. Jpn. 2005, 74, 511.
2. (a) Decurtins, S.; Gutlich, P.; Kohler, C. P.; Spiering, H.; Hauser, A. Chem. Phys. Lett. 1984, 105, 1.
3. (b) Decurtins, S.; Giitlich, P.; Hasselbach, K. M.; Hauser, A.; Spiering, H. Inorg. Chem. 1985, 24, 2174.
4. Gutlich, P.; Goodwin, H. A. Spin Crossover in Transition Metal Compounds I-III, Springer: New York, 2004. and related refs therein.
5. (a) Sato, O.; Iyoda, T.; Fujishima, A.; Hashimito, K. Science 1996, 272, 704.
6. (b) Einaga, Y.; Sato, O.; Iyoda, T.; Kobashi, Y.; Ambe, F.; Hashimoto, K.; Fujishima, A. Chem. Lett. 1997, 289.
7. (c) Bleuzen, A.; Lomenech, C.; Escax, V.; Villain, F.; Varret, F.; Moulin, C.; Verdaguer, M. J. Am. Chem. Soc. 2000, 122, 6648.
8. (d) Varret, F.; Bleuzen, A.; Boukheddaden, K.; Bousseksou, A.; Codjovi, E.; En- achescu, C.; Goujon, A.; Linares, J.; Menendez, N.; Verdaguer, M. Pure Appl. Chem. 2002, 74, 2159.
9. (e) Li, G.; Akitsu, T.; Sato, O.; Einaga, Y. J. Am. Chem. Soc. 2003, 125 (41), 12396.
10. (f) Dei, A. Angew. Chem., Int. Ed. 2005, 44, 1160.
11. (a) Carbonera, C.; Dei, A.; Letard, J. F.; Sangregorio, C.; Sorace, L. Angew. Chem., Int. Ed. 2004, 43, 3135.
12. (b) Dei, A.; Gatteschi, D.; Sangregorio, C.; Sorace, L. Acc. Chem. Res. 2004, 37 (11), 827.
13. (c) Sato, O.; Cui, A.; Matsuda, R.; Tao, J.; Hayami, S. Acc. Chem. Res. 2007, 40 (5), 361.
14. (d) Sato, O.; Tao, J.; Zhang, Y. J. Angew. Chem., Int. Ed. 2007, 46, 2152.
15. (a) Liu, X. J.; Moritomo, Y.; Nakamura, A.; Kojima, N. J. Phys. Soc. Jpn. 1999, 68, 3134.
16. (b) Son, J.-Y.; Mizokawa, T.; Quilty, J. W.; Takubo, K.; Ikeda, K.; Kojima, N. Phys. Rev. B: Condens. Mater. Chem. 2005, 72, 235105.
17. Matsuzaki, H.; Matsuoka, T.; Kishida, H.; Takizawa, K.; Miyasaka, H.; Sugiura, K.; Yamashita, M.; Okamoto, H. Phys. Rev. Lett. 2003, 90, 046401.
18. (a) Uchida, N.; Koshihara, S.; Ishikawa, T.; Ota, A.; Fukaya, S.; Matthieu, C.; Yamochi, H.; Saito, G. J. Phys. IV France 2004, 114, 143.
19. (b) Chollet, M.; Guerin, L.; Uchida, N.; Fukaya, S.; Shimoda, H.; Ishikawa, T.; Matsuda, K.; Hasegawa, T.; Ohta, A.; Yamochi, H.; Saito, G.; Tazaki, R.; Adachi, S.; Koshihara, S. Science 2005, 307, 86.
20. (a) Laget, V.; Hornick, C.; Rabu, P.; Drillon, M.; Ziessel, R. Coord. Chem. Rev. 1998, 178, 1533.
21. (b) Rabu, P.; Huang, Z. L.; Hornick, C.; Drillon, M. Synth. Met. 2001, 122, 509.
22. (a) Okubo, M.; Enomoto, M.; Kojima, N. Solid State Commun. 2005, 134, 777.
23. (b) Shimizu, H.; Okubo, M.; Nakamoto, A.; Enomoto, M.; Kojima, N. Inorg. Chem. 2006, 45, 10240.
24. Fujita, W.; Awaga, K. J. Am. Chem. Soc. 1997, 119, 4563.
25. (a) Tamaki, H.; Zhong, Z. J.; Matsumoto, N.; Kida, S.; Koikawa, M.; Achiwa, N.; Hashimoto, Y.; Okawa, H. J. Am. Chem. Soc. 1992, 114, 6974.
26. (b) Tamaki, H.; Mitsumi, M.; Nakamura, K.; Matsumoto, N.; Kida, S.; Okawa, H.; Iijima, S. Chem. Lett. 1992, 1975.
27. (a) Decurtins, S.; Schmalle, H. W.; Oswald, H. R.; Linden, A.; Ensling, J.; Gutlich, P.; Hauser, A. Inorg. Chim. Acta 1994, 216, 65.
28. (b) Clement, R.; Decurtins, S.; Gruselle, M.; Train, C. Monatsh. Chem. 2003, 134, 117.
29. Mathoniere, C.; Nuttall, C. J.; Carling, S. G.; Day, P. Inorg Chem. 1996, 35, 1201.
30. Coronado, E.; Galán-Mascarós, J. R.; Gómez- García, C. J.; Ensling, J.; Gütlich, P. Chem. Eur. J. 2000, 6, 552.
31. Coronado, E.; Galán-Mascarós, J. R.; Gómez- García, C. J.; Laukhin, V. Nature 2000, 408, 447.
32. Okawa, H.; Mitsumi, M.; Ohba, M.; Kodera, M.; Matsumoto, N. Bull. Chem. Soc. Jpn. 1994, 67, 2139.
33. Kojima, N.; Aoki, W.; Itoi, M.; Seto, M.; Kobayashi, Y.; Maeda, Yu Solid State Commun. 2001, 120, 165.
34. Nakamoto, T.; Miyazaki, Y.; Itoi, M.; Ono, Y.; Kojima, N.; Sorai, M. Angew. Chem., Int. Ed. 2001, 40, 4716.
35. Kojima, N.; Aoki, W.; Seto, M.; Kobayashi, Y.; Maeda, Yu Synth. Met. 2001, 121, 1796.
36. Kojima, N.; Itoi, M.; Ono, Y.; Okubo, M.; Enomoto, M. Mater. Sci. 2003, 21, 181.
37. Bradley, J. M.; Carling, S. G.; Visser, D.; Day, P.; Hautot, D.; Long, G. J. Inorg. Chem. 2003, 42, 986.
38. Ono, Y.; Okubo, M.; Kojima, N. Solid State Commun. 2003, 126, 291.
39. Itoi, M.; Taira, A.; Enomoto, M.; Matsushita, N.; Kojima, N.; Kobayashi, Y.; Asai, K.; Koyama, K.; Nakamoto, T.; Uwatoko, Y.; Yamamura, J. Solid State Commun. 2004, 130, 415.
40. (a) Itoi, M.; Doctoral Thesis, The University of Tokyo, Japan, 2004.
41. (b) Itoi, M.;Ono, Y.;Kojima, N.;Kato, K.;Osaka, K.;Takata, M.; Eur. J. Inorg. Chem. 2006, 2006, 1198.
42. Kojima, N.; Ono, Y.; Kobayashi, K.; Seto, M. Hyperfine Interact. 2004, 156-157, 175.
43. de Jongh, L. J.; Van Amstel, W. D.; Miedema, A. R. Physica 1972, 58, 277.
44. Landee, C. P.; Halvorson, K. E.; Willett, R. D. J. Appl. Phys. 1987, 61, 3295.
45. de Jongh, L. J., Ed. Magnetic Properties of Layered Transition Metal Compounds; Kluwer Academic Publishers: Dordrecht, 1990.
46. Einaga, Y.; Sato, O.; Iyoda, T.; Fujishima, A.; Hashimoto, K. J. Am. Chem. Soc. 1999, 121, 3745.
47. (a) Einaga, Y; Taguchi, M.; Li, G.; Akitsu, T.; Gu, Z.-Z.; Sugai, T.; Sato, O. Chem. Mater. 2003, 15, 8.
48. (b) Taguchi, M.; Li, G.; Gu, Z.; Sato, O.; Einaga, Y. Chem. Mater. 2003, 15, 4756.
49. Mikami, R.; Taguchi, M.; Yamada, K.; Suzuki, K.; Sato, O.; Einaga, Y. Angew. Chem., Int. Ed. 2004, 43, 6135.
50. Yamamoto, T.; Umemura, Y.; Sato, O.; Einaga, Y. Chem. Mater. 2004, 16, 1195.
51. Yamamoto, T.; Umemura, Y.; Sato, O.; Einaga, Y. J. Am. Chem. Soc. 2005, 127, 16065.
52. Suda, M.; Miyazaki, Y.; Hagiwara, Y.; Sato, O.; Shiratori, S.; Einaga, Y. Chem. Lett. 2005, 34, 1028.
53. Bénard, S.; Yu, P. Adv. Mater. 2000, 12, 48.
54. Bénard, S.; Riviere, E.; Yu, P.; Nakatani, K.; Delouis, J. F. Chem. Mater. 2001, 13, 159.
55. Kashima, I.; Okubo, M.; Ono, Y.; Itoi, M.; Kida, N.; Hikita, M.; Kojima, N. Synth. Met. 2005, 153, 473.
56. Kim, S. H.; Suh, H. J.; Cui, J. Z.; Gal, Y. S.; Jin, S. H.; Koh, K. Dyes Pigments 2002, 53, 251.
57. Nishibori, E.; Takata, M.; Kato, K.; Sakata, M.; Kubota, Y.; Aoyagi, S.; Kuroiwa, Y.; Yamamoto, M.; Ikeda, N. Nucl. Instrum. Methods Phys. Res. A 2001, 1045-1048, 467.
58. Coucouvanis, D.; Piltingsrud, D. J. Am. Chem. Soc. 1973, 95, 5556.
59. 2) for 5 h. After the UV irradiation was stopped, the sample was warmed to room temperature. Then the sample was taken out from the cryostat and the magnetization measurement was performed. Judging from the UV-vis absorption measurement, the photoisomerization-induced HTP is stable enough while the magnetization measurement.
60. (a) Sorai, M.; Seki, S. J. Phys. Chem. Solids 1974, 35, 555.
61. (b) Gallois, B.; Real, J.; Hauw, C.; Zarembowitch, J. Inorg. Chem. 1990, 29, 1152.
62. Kobayashi, Y.; Itoi, M.; Kojima, N.; Asai, K. J. Phys. Soc. Jpn. 2002, 71, 3016.
63. Kobayashi, Y.; Itoi, M.; Kojima, N.; Asai, K. J. Mag. Mag. Mater. 2004, 272-276, 1091.