Hybrid molecular magnets obtained by insertion of decamethyl-metallocenium cations into layered, bimetallic oxalate complexes: [ZIIICp2*IIMIII(ox) 3] (ZIII = Co, Fe; MII = Cr, Fe; MII = Mn, Fe, Co, Cu, Zn; ox = oxalate; Cp* = pentamethylcyclopentadienyl)

Chemistry - A European Journal

Volumn 6, Issue 3, 2000, Pages 552-563

  Coronado, Eugenio ^a   Galán Mascarós, José Ramón ^a   Gómez García, Carlos José ^a   Ensling, Jürgen ^b   Gütlich, Philipp ^b  

^a UNIVERSITY OF VALENCIA   (Spain)

^b JOHANNES GUTENBERG UNIVERSITY   (Germany)

Author keywords

Crystal engineering; Decamethylferrocenium; Layered magnets; Magnetic properties; Oxalate complexes

Indexed keywords

OXALIC ACID;

ANALYTIC METHOD; ARTICLE; CATION TRANSPORT; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLIZATION; DRUG SYNTHESIS; HYBRID; MOSSBAUER SPECTROSCOPY; STRUCTURE ANALYSIS;

EID: 0034603075     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3765(20000204)6:3<552::AID-CHEM552>3.0.CO;2-U     Document Type: Article

References (28)

1. a) Molecular Magnetism: From Molecular Assemblies to the Devices, NATO ASI Series, Vol. E321 (Eds.: E. Coronado, P. Delhaès, D. Gatteschi, J. S. Miller), Kluwer, Dordrecht, 1996;
2. b) J. S. Miller, Adv. Mater. 1990, 2, 98.
3. a) Z.-J. Zhong, N. Matsumoto, H. Okawa, S. Kida, Chem. Lett. 1990, 87;
4. b) M. Ohba, H. Tamaki, N. Matsumoto, H. Okawa, S. Kida, Chem. Lett. 1991, 1157.
5. H. Tamaki, Z.-J. Zhong, N. Matsumoto, S. Kida, M. Koikawa, N. Achiwa, Y. Hashimoto, H. Okawa, J. Am. Chem. Soc. 1992, 114, 6974.
6. a) H. Tamaki, M. Mitsumi, K. Nakamura, N. Matsumoto, S. Kida, H. Okawa, S. Iijima, Chem. Lett. 1992, 1975 ;
7. b) H. Okawa, N. Matsumoto, H. Tamaki, M. Ohba, Mol. Cryst. Liq. Cryst. 1993, 253, 257;
8. c) J. Larionova, B. Mombelli, J. Sanchiz, O. Kahn, Inorg. Chem. 1998, 37, 679.
9. a) C. Mathonière, S.-G. Carling, D. Yusheng, P. Day, J. Chem. Soc. Chem. Commun. 1994, 1551;
10. b) C. Mathonière, J. Nuttall, S.-G. Carling, P. Day, Inorg. Chem. 1996, 35, 1201.
11. a) R. Pellaux, H.-W. Schmalle, R. Huber, P. Fisher, T. Hauss, B. Ouladdiaf, S. Decurtins, Inorg. Chem. 1997, 36, 2301;
12. b) S. Decurtins, H.-W. Schmalle, H.-R. Oswald, A. Linden, J. Ensling, P. Gütlich, A. Hauser, Inorg. Chim. Acta 1994, 216, 65;
13. c) L.-O. Atovmyan, G.-V. Shilov, R.-N. Lyubovskaya, E.-I. Zhilyaeva, N.-S. Ovanesyan, S.-I. Pirumova, I.-G. Gusakovskaya, JETP Lett. 1993, 58, 766.
14. E. Coronado, J.-R. Galán-Mascarós, C. Giménez-Saiz, C.-J. Gómez-García, C. Ruiz-Perez, S. Triki, Adv. Mater. 1996, 8, 737.
15. a) A.-W. Graham, M. Kurmoo, P. Day, J. Chem. Soc. Chem. Commun. 1995, 2061;
16. b) M. Kurmoo, A.-W. Graham, P. Day, S.-J. Coles, M.-B. Hursthouse, J.-L. Caulfield, J. Singleton, F.-L. Pratt, W. Hayes, L. Ducasse, P. Guionneau, J. Am. Chem. Soc. 1995, 117, 12209.
17. E. Coronado, J.-R. Galán-Mascarós, C.-J. Gómez-García, Synth. Metals 1999, 102, 1459.
18. a) Z. Gu, O. Sato, T. Iyoda, K. Hashimoto, A. Fujishima, Mol. Cryst. Liq. Cryst. 1996, 286,147;
19. b) S. Bernard, P. Yu, T. Coradin, E. Rivière, K. Nakatani, R. Clément, Adv. Mater. 1997, 9, 981.
20. M. Clemente-León, E. Coronado, J.-R. Galán-Mascarós, C.-J. Gómez-García, Chem. Commun. 1997, 1727.
21. L. Néel, Ann. Phys. (Paris) 1948, 3, 137.
22. a) S. Iijima, F. Mizutani, Mol. Cryst. Liq. Cryst. 1997, 306, 227;
23. b) S. Iijima, F. Mizutani, M. Mitsunmi, N. Matsumoto, H. Okawa, Inorg. Chim. Acta 1996, 253, 47;
24. c) S. Iijima, T. Katsura, H. Tamaki, M. Mitsumi, N Matsumoto, H. Okawa, Mol. Cryst. Liq. Cryst. 1993, 233, 263.
25. Mössbauer spectra for the decamethylcobaltocenium derivative also confirm the different temperature-dependent magnetization for the two sublattices.
26. J.-C. Baylar, E.-M. Jones in Inorganic Synthesis, Vol. 1 (Ed.: H. S. Booth), McGraw-Hill, New York, 1939, pp. 35.
27. D. Hendrickson, Y. Son, H. Gray, Inorg. Chem. 1971, 10, 1559.
28. A. Altomare, G. Cascarano, C. Giacovazzo, A. J. Guagliardi, Appl. Crystallogr. 1994, 27, 1045.