Microkinetic analysis of the epoxidation of styrene catalyzed by (porphyrin)Mn encapsulated in molecular squares

Journal of Catalysis

Volumn 266, Issue 1, 2009, Pages 145-155

  Oxford, Gloria A E ^a   Curet Arana, María C ^a,b   Majumder, Debarshi ^a   Gurney, Richard W ^c,d   Merlau, Melissa L ^c   Nguyen, SonBinh T ^c   Snurr, Randall Q ^a   Broadbelt, Linda J ^a  

^a Northwestern University   (United States)

^b UNIVERSITY OF PUERTO RICO   (Puerto Rico)

^c NORTHWESTERN UNIVERSITY   (United States)

^d SIMMONS COLLEGE   (United States)

Author keywords

(Porphyrin)Mn; Biomimetic catalysis; Epoxidation; Microkinetic modeling; Molecular squares; Oxidation; Styrene

Indexed keywords

(PORPHYRIN)MN; BIOMIMETIC CATALYSIS; CONCENTRATION OF; DEACTIVATED CATALYSTS; DIMER FORMATION; ELEMENTARY STEPS; EXPERIMENTAL DATA; EXPERIMENTAL STUDIES; IODOSYLBENZENE; IRREVERSIBLE DEGRADATION; MICHAELIS-MENTEN; MICROKINETIC ANALYSIS; MICROKINETIC MODELING; MICROKINETIC MODELS; MOLECULAR SQUARES; RATE ANALYSIS; RATE EXPRESSION; REACTION TIME; STYRENE EPOXIDATIONS; SUPRAMOLECULAR CAVITY;

BIOMIMETICS; CATALYSIS; CATALYST DEACTIVATION; CATALYST POISONING; MANGANESE COMPOUNDS; OXIDATION; PORPHYRINS; STYRENE;

MANGANESE;

EID: 67651155745     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2009.06.003     Document Type: Article

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