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67651129637
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n=2.7 (at 45°C, initial monomer concentration= 50 ìmol/mL), Mn=7.35×104, Mwn=2.79 (at 55°C, initial monomer concentration=50 μmol/mL)].
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n= 2.2 (at 50°C, initial monomer concentration=270 μmol/mL), Ru- (A) 40 equiv].The results also indicate that certain optimizations are necessary for obtainment of high molecular weight polymers. The results also clearly suggest that continuous removl of ethylene (and initial monomer concentration, amount of ruthenium catalyst) should be the key for obtainment of high molecular weight polymer, as we previously emphasized,8,10,11 and the effect of solvent may not be very important for obtainment of the high molecular weight polymers (if the resultant polymers are soluble).
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For selected examples for synthesis of PPVs by the precursor method
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see, London
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For selected examples for synthesis of PPVs by the precursor method, see: (a) Burroughes, J. H.; Bradley, D. D. C.; Brown, A. R.; Marks, R. N.; Mackay, K.; Friend, R. H.; Burn, P. L.; Holmes, A. B. Nature (London) 1990, 347, 539-541.
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1HNMRspectra (in CDCl3 at 25 °C)for poly(1)s prepared by ADEMT and by precursor method (purchased from Aldrich) are shown in the Supporting Information
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1HNMRspectra (in CDCl3 at 25 °C)for poly(1)s prepared by ADEMT and by precursor method (purchased from Aldrich) are shown in the Supporting Information.
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Absolute quantum efficiencies were measured by using a Hamamatsu C9920-02 (Hamamatsu Photonics K.K.), and these values were estimated by using a calibrated integration sphere at an exciting wavelength of 400 nm.
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Absolute quantum efficiencies were measured by using a Hamamatsu C9920-02 (Hamamatsu Photonics K.K.), and these values were estimated by using a calibrated integration sphere at an exciting wavelength of 400 nm.
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For example (explained in ref 25)
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For example (explained in ref 25): (a) Clayden, J. Tetrahedron 2004, 60, 4335.
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Clayden1
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