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More recently, improvement in a reaction protocol for synthesis of poly(arylene vinylene)s by ADMET polymerization using Ru(1) or the other ruthenium catalysts has been introduced: Weychardt, H.; Plenio, H. Organometallics 2008, 27, 1479-1485.
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Parts of these results were introduced at the 10th Pacific Polymer Conference (PPC10), 6P1S1-017a, Kobe, Japan, Dec 2007.
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Parts of these results were introduced at the 10th Pacific Polymer Conference (PPC10), 6P1S1-017a, Kobe, Japan, Dec 2007.
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34
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Hargadon, M. T.; Davey, E. A.; McIntyre, T. B.; Gnanamgari, D.; Wynne, C. M.; Swift, R. C.; Zirabalist, J. R.; Fredericks, B. L.; Nicastro, A. J.; Goodson, F. E. Maeromolecules 2008, 41, 741-750 Highly regular organization of conjugated polymer chains via block copolymer self-assembly:
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(b) Hargadon, M. T.; Davey, E. A.; McIntyre, T. B.; Gnanamgari, D.; Wynne, C. M.; Swift, R. C.; Zirabalist, J. R.; Fredericks, B. L.; Nicastro, A. J.; Goodson, F. E. Maeromolecules 2008, 41, 741-750 Highly regular organization of conjugated polymer chains via block copolymer self-assembly:
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0037777158
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34547702036
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Synthesis of poly(phenylene vinylenes) with well-defined poly(ε-caprolactone) or polystyrene: Colak, D. G.; Cianga, I.; Yagci, Y.; Cirpan, A.; Karasz, F. E. Macromolecules 2007, 40, 5301-5310.
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Synthesis of poly(phenylene vinylenes) with well-defined poly(ε-caprolactone) or polystyrene: Colak, D. G.; Cianga, I.; Yagci, Y.; Cirpan, A.; Karasz, F. E. Macromolecules 2007, 40, 5301-5310.
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13C NMR spectra of polymers, and UV-vis and fluorescent spectra for PFV and poly(PEG-bl-PFV-bl-PEG) are shown in the Supporting Information.
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13C NMR spectra of polymers, and UV-vis and fluorescent spectra for PFV and poly(PEG-bl-PFV-bl-PEG) are shown in the Supporting Information.
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39
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47249159914
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3 group and PEG shown in Table 2.
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3 group and PEG shown in Table 2.
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40
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0035800302
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Synthesis of end-functionalization of ring-opened polynorbornene via the Wittig type cleavage, for example: (a) Nomura, K.; Takahashi, S.; Imainishi, Y. Macromolecules 2001, 34, 4712-4723.
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Synthesis of end-functionalization of ring-opened polynorbornene via the Wittig type cleavage, for example: (a) Nomura, K.; Takahashi, S.; Imainishi, Y. Macromolecules 2001, 34, 4712-4723.
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The exclusive metathesis with vinyl group without accompanying mediathesis with internal olefins should be required. In this regard, Mo(1) was more suited than Ru(1) because ADMET condensation did not proceed if the reaction was conducted under nitrogen atmosphere, as reported in ref 6
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The exclusive metathesis with vinyl group without accompanying mediathesis with internal olefins should be required. In this regard, Mo(1) was more suited than Ru(1) because ADMET condensation did not proceed if the reaction was conducted under nitrogen atmosphere, as reported in ref 6.
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47249113506
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The Mn value by GPC for the triblock copolymer was somewhat close to that before grafting PEG3000 (Table 2, run 10, last line, but the result was reproducible Mn, 2.99 × 104, M w/Mn, 1.9, by GPC with independent analysis run after preparation of a new calibration curve with polystyrene standards, We also confirmed that PEG was not extracted from the block copolymer after separation of PEG with the block copolymer: both 1H and 13C NMR spectra clearly indicate formation of the block copolymer, and the Mn value estimated by the 1H NMR spectrum is close to the estimated value. We believe that this is due to that the Mn value by GPC was based on polystyrene standards, although we do not have the exact reason
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n value by GPC was based on polystyrene standards, although we do not have the exact reason.
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