On the predictive ability of the new thermodynamics of electrolyte solutions

Industrial and Engineering Chemistry Research

Volumn 48, Issue 13, 2009, Pages 6436-6440

  Wilczek Vera, Grazyna ^a   Vera, Juan H ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTIONS; COMPLEX FORMS; ELECTROLYTE SOLUTIONS; EQUILIBRIUM PRESSURE; ESSENTIAL ELEMENTS; EXPERIMENTAL DATA; GENERAL APPLICATIONS; INDIVIDUAL ION; IONIC ACTIVITY; JUNCTION POTENTIAL; LONG RANGE INTERACTIONS; MIXED SALT SYSTEMS; OSMOTIC COEFFICIENT; PREDICTIVE ABILITIES; SET-UPS; STATE OF AFFAIRS; THERMODYNAMIC CONSISTENCY; THERMODYNAMIC TREATMENT;

CALCIUM CHLORIDE; FORECASTING; PHASE EQUILIBRIA; SODIUM CHLORIDE; THERMODYNAMICS;

ELECTROLYTES;

EID: 67651018262     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie9002238     Document Type: Article

References (29)

1. Khoshkbarchi, M. K.; Vera, J. H. Measurement and Correlation of Ion Activity Coefficients in Aqueous Single Electrolyte Solutions. AIChE J. 1996, 42, 249.
2. Zhuo, K., W.; Dong, W. W.; Wang, J. Activity Coefficients of Individual Ions in Aqueous Solutions of Sodium Halides at 298.15 K. Fluid Phase Equilib. 2008, 274, 80.
3. Shatkay, A.; Lerman, A. Individual Activities of Sodium and Chloride Ions in Aqueous Solutions of Sodium Chloride. Anal. Chem. 1969, 41, 514.
4. Lin, C.-l.; Lee, L.-s. A Two-Ionic-Parameter Approach for Ion Activity Coefficients of Aqueous Electrolyte Solutions. Fluid Phase Equilib. 2003, 205, 69.
5. Wilczek-Vera, G.; Rodil, E.; Vera, J. H. On the Activity of Ions and the Junction Potential: Revised Values for Al Data. AIChE J. 2004, 50, 445.
6. Lewis G. N.; Randall, M. Thermodynamics, 1st ed.; McGraw-Hill: New York, 1923; p 382.
7. Wilczek-Vera, G.; Vera, J. H. On the Measurement of Individual Ion Activities. Fluid Phase Equilib. 2005, 236, 96.
8. Skoog D. A.; Holler, F. J.; Crouch, S. R., Principles of Instrumental Analysis, 6th ed.; Thomson Brooks/Cole: Canada, 2007; Appendix 2.
9. Malatesta, F. Reply to Letter to the Editor. AIChE J. 2006, 52, 2307.
10. Pitzer K. S., Ion Interaction Approach. In: Activity Coefficients in Electrolyte Solutions 2nd ed.; Pitzer, K. S., Ed.; CRC Press: Boca Raton, FL, 1991; Chapter 3.
11. Pitzer K. S. Thermodynamics, 3rd ed.; McGraw-Hill: New York, 1995; Chapter 17.
12. Clegg, S. L.; Whitfield, M. Activity Coefficients in Natural Waters. In: Activity Coefficients in Electrolyte Solutions, 2nd ed.; Pitzer, K.S., Ed.; CRC Press: Boca Raton, FL, 1991; Chapter 6.
13. Clegg, S. L.; Whitfield, M. Activity Coefficients in Natural Waters. In: Activity Coefficients in Electrolyte Solutions, 2nd ed.; Pitzer, K.S., Ed.; CRC Press: Boca Raton, FL, 1991; p 407.
14. Wilczek-Vera, G.; Vera, J. H. Peculiarities of the Thermodynamics of Electrolyte Solutions. A Critical Discussion. Can. J. Chem. Eng. 2003, 80, 70, 81; 1251.
15. Lladosa E.; Arce, A.; Wilczek-Vera, G.; Vera, J. H. Effect of the Reference Solution in the Measurement of Ion Activity Coefficients using Cells with Transference. Chem. Eng. Sci., submitted for publication (will be published under a different title).
16. Lee, L.-s.; Chen, T.-m.; Tsai, K.-M.; Lin, C.-l. Individual Ion and Mean Activity Coefficients in NaCl, NaBr, KCl, and KBr Aqueous Solutions. J. Chin. Inst. Chem. Eng. 2002, 33, 267.
17. Schneider, A. C.; Pasel, C.; Luckas, M.; Schmidt, K. G.; Herbell, J. D. Bestimmung von Ionenaktivitats-Koeffizienten in Wassrigen Ltisungen mit Hilfe Ionenselektiver Elektroden (Determination of Coefficients of Ion Activities in Aqueous Solutions Using Ion Electrodes). Chem. Ing. Technol. 2003, 75, 244.
18. Schneider, A. C.; Pasel, C.; Luckas, M.; Schmidt, K. G.; Herbell, J. D. Determination of Hydrogen Single Ion Activity Coefficients in Aqueous HCl Solutions at 25° C. J. Solution Chem. 2004, 33, 257.
19. Rabie, H. R.; Wilczek-Vera, G.; Vera, J. H. Activities of Individual Ions. From Infinite Dilution to Saturated Solutions. J. Solution Chem. 1999, 28, 885.
20. Rodil, E.; Vera, J. H. The Activities of Ions: Analysis of the Theory and Data for Aqueous Solutions of MgBr2, CaBr2,and BaBr2. Fluid Phase Equilib. 2003, 205, 115. 211, 289.
21. Wilczek-Vera, G.; Rodil, E.; Vera, J. H. A Complete Discussion of the Rationale Supporting the Experimental Determination of Individual Ionic Activities. Fluid Phase Equilib. 2006, 244, 33.
22. Wilczek-Vera, G.; Rodil, E.; Vera, J. H. Towards Accurate Values of Individual Ion Activities Additional Data for NaCl, NaBr,and KCl, and New Data for NH4Cl. Fluid Phase Equilib., Festschrift in Honor of John M. Prausnitz 2006, 241, 59.
23. Arce, A.; Wilczek-Vera, G.; Vera, J. H. Activities of Na+ and Cl- Ions from Homoionic Measurements with Null Junction Potentials at Different Concentrations. Chem. Eng. Sci. 2007, 62, 3849.
24. Shiah, I.-M.; Tseng, H. C. Experimental and Theoretical Determination of Vapor Pressures of NaCl-KCl, NaBr-KBr,and NaCl-CaCl2 Aqueous Solutions at 298 to 343 K. Fluid Phase Equilib. 1996, 124, 235.
25. Khoshkbarchi, M. K.; Vera, J. H. Measurement and Correlation of Ion Activity Coefficients in Aqueous Solutions of Mixed Electrolytes with a Common Ion. Fluid Phase Equilib. 1996, 121, 253.
26. 3 at 298.15 K. J. Solution Chem. 1996, 25, 983.
27. Perry R. H.; Green, D. W. Chemical Engineers' Handbook, 6th ed.; McGraw-Hill: New York, 1984.
28. 3 + KNO3, NaCl + KCl, and NaBr + NaCl. J. Chem. Eng. Data, Festschrift for the 90th Birthday of Robin H. Stokes 2009, 54, 345-350.
29. (b) Errata with the same title, published online, J. Chem. Eng. Data, April 1, 2009.