Measurement and Correlation of Ion Activity in Aqueous Single Electrolyte Solutions

AIChE Journal

Volumn 42, Issue 1, 1996, Pages 249-258

  Khoshkbarchi, Mohammad K ^a   Vera, Juan H ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CORRELATION METHODS; ELECTROLYTES; ION SELECTIVE ELECTRODES; MATHEMATICAL MODELS; POTASSIUM COMPOUNDS; SODIUM CHLORIDE; SOLUTIONS;

ANION; CATION; ION ACTIVITY; ION SELECTIVE INTERACTIONS; ION-ION INTERACTIONS; PITZER MODEL; POTASSIUM CHLORIDE; SODIUM BROMIDE; TRANSFERENCE NUMBERS;

IONS;

EID: 0029733942     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690420121     Document Type: Article

References (23)

1. Ashrafizadeh, S. N., M. E. Weber, and J. H. Vera, "Cation Exchange with Reverse Micelles," Ind. Eng. Chem. Res., 32, 125 (1993).
2. Bates, R. G., Determination of pH Theory and Practice, 2nd ed., John Wiley, New York (1965).
3. Bates, R. G., B. R. Staples, and R. A. Robinson, "Ionic Hydration and Single Ion Activity in Unassociated Chlorides at High Ionic Strengths," Anal. Chem., 42, 867 (1970).
4. Bromley, L. A., "Thermodynamic Properties of Strong Electrolytes in Aqueous Solutions," AIChE J., 19; 313 (1973).
5. Chen, C. C., H. I. Britt, J. F. Boston, and L. B. Evans, "Local Composition Model for Excess Gibbs Energy of Electrolyte System," AIChE J., 31, 588 (1982).
6. Cruz, J. L., and H. Renon, "A New Thermodynamic Representation of Binary Electrolyte Solutions Nonideality in the Whole Range of Concentrations," AIChE J., 24, 817 (1978).
7. Eisenman, G., Glass Electrodes for Hydrogen and Other Cations, Marcel Dekker, New York (1967).
8. Gibbs, J. W., Collected Works, Vol. 1, Longmans Green, New York (1928).
9. Guggenheim, E. A., "The Conception of Electrical Potential Difference Between Two Phases and the Individual Activities of Ions," J. Phys. Chem., 31, 842 (1929).
10. Haghtalab, A., and J. H. Vera, "A Nonrandom Model for the Excess Gibbs Energy of Electrolyte Solutions," AIChE J., 34, 803 (1988).
11. Haghtalab, A., and J. H. Vera, "Nonrandom Factor Model for Electrolyte Solutions," AIChE J., 37, 147 (1991).
12. Harned, H. S., and B. B. Owen, The Physical Chemistry of Electrolyte Solutions, 3rd ed., Reinhold, New York (1958).
13. Komar, N. P., and A. Z. Kaftanov, "Estimation of the Activity Coefficient of Chloride Ions in Potassium Chloride Solution," Russ. J. Phys. Chem, 48, 246 (1974).
14. Lewis, G. N., and M. Randall, Thermodynamics, 2nd ed. rev. by K. S. Pitzer and L. Brewer, McGraw-Hill, New York (1961).
15. Maclnnes, D. A., D. Belcher, and T. Shedlovsky, "The Meaning and Standardization of the pH Scale," J. Amer. Chem. Soc., 60, 1094 (1938).
16. MacInnes, D. A., The Principals of Electrochemistry, Dover, New York (1961).
17. Milazzo, G., N. Bonciocat, and M. Borda, "True Temperature Coefficients of the Electric Tension of Individual Electrodes: XI. Theoretical Analysis of the Procedure to Obtain Individual Activity Coefficients," Electrochim. Acta, 21, 349 (1975).
18. Mokhov, V. M., I. P. Bagdasarova, A. G. Kekeliya, and L. V. Lavrelashvilig, "Individual Activity Coefficients in Sodium Chloride Solutions at Different Temperatures," Russ. J. Phys. Chem., 51, 1406 (1977).
19. Pitzer, K., "Electrolytes From Dilute Solutions to Fused Salts," J. Amer. Chem. Soc., 102, 2902 (1980).
20. Robinson, R. A., and R. H. Stokes, Electrolyte Solutions, 2nd ed., Butterworths, Boston (1959).
21. Shatkay, A., and A. Lerman, "Individual Activities of Sodium and Chloride in Aqueous Solutions of Sodium Chloride," Anal. Chem., 41, 514 (1969).
22. Skoog, D. A., and J. J. Leary, Principles of Instrumental Analysis, Saunders, New York (1992).
23. Taylor, P. B., "Electromotive Force of the Cell With Transference and Theory of Interdiffusion of Electrolytes," J. Phys. Chem., 31, 1478 (1927).