Activities of individual ions from infinite dilution to saturated solutions

Journal of Solution Chemistry

Volumn 28, Issue 7, 1999, Pages 885-913

  Rabie, Hamid R ^a   Wilczek Vera, Grazyna ^b   Vera, Juan H ^b  

^a GE Water & Process Technologies   (Canada)

^b MCGILL UNIVERSITY   (Canada)

Author keywords

Activities; Activity coefficients; Electrolytes; Hydration; Ions; Salts

Indexed keywords

EID: 0033242458     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1021736315580     Document Type: Article

References (55)

1. 1. K. S. Pitzer, J. Amer. Chem. Soc. 102, 2902 (1980).
2. 2. G. Eisenman, Glass Electrodes for Hydrogen and Other Cations (Marcel Dekker, New York, 1967).
3. 3. J. J. C. Jansz, Hydrometallurgy 11, 13 (1983).
4. 4. H. R. Rabie and J. H. Vera, J. Phys. Chem. B. 101, 10295 (1997).
5. 5. H. R. Rabie and J. H. Vera, Ind. Eng. Chem. Res. 35, 3665 (1996).
6. 6. A. M. Soto-Campos, M. K. Khoshkbarchi, and J. H. Vera, J. Chem. Thermodyn. 29, 609 (1997).
7. 7. A. A. Pradhan and J. H. Vera, Fluid Phase Equilibria 152, 121 (1998).
8. 8. A. Soto, A. Arce, M. K. Khoshkbarchi, and J. H. Vera, Biophys. Chem. 73, 77 (1998).
9. 9. M. K. Khoshkbarchi and J. H. Vera, Ind. Eng. Chem. Res. 36, 2245 (1997).
10. 10. G. N. Lewis and M. Randall, Thermodynamics, 1st edn. (McGraw-Hill, New York, 1923).
11. 11.J. O'M. Bockris and A. K. N. Ready, Modern Electrochemistry, 3rd edn. (Plenum, New York, 1977).
12. 12. K. S. Pitzer, Thermodynamics, 3rd edn. (McGraw-Hill, New York, 1995).
13. 13. R. R. Bates, B. R. Staples, and R. A. Robinson, Anal. Chem. 42, 867 (1970). Equation (10) of this reference has an error of sign. The term inside the square brackets should read [1 + 0.018 (2 - h)m].
14. 14. N. P. Komar and A. Z. Kaftanov, Russ. J. Phys. Chem. 48, 246 (1974).
15. 15. A. Shatkay and A. Lerman, Anal. Chem. 41, 514 (1969).
16. 16. G. Milazzo, Z. Phys. Chem. 54, 27 (1967).
17. 17. G. Milazzo, Z. Phys. Chem. 62, 47 (1968).
18. 18. G. Milazzo and V. K. Sharma, Z. Phys. Chem. 73, 223 (1970).
19. 19. G. Milazzo, and G. Schenk, Z. Phys. Chem. 76, 127 (1971).
20. 20. G. Milazzo, N. Bonciocat, and M. Borda, Electrochim. Acta 21, 349 (1976).
21. 21. V. M. Mokhov, I. P. Bagdasarova, A. G. Kekeliya, and L. V. Lavrelashvilig, Russ. J. Phys. Chem. 51, 1406 (1977).
22. +|. In Eq. (9), the sum for anions for solution 1, in the denominator of the pre-exponential factor, should be preceded by a + and not by a - sign.
23. 23. M. K. Khoshkbarchi, and J. H. Vera, Fluid Phase Equilibria 121, 253 (1996). Equation (3) of this publication, has the same typographical errors as Eq. (9) of Ref. 22.
24. 24. M. M. Marcos-Arroyo, M. K., Khoshkbarchi, and J. H. Vera, J. Solution Chem. 25, 983 (1996). The symbols for nitrate and potassium ions are exchanged in the caption of Fig. 4 of this publication.
25. 25. Waters Symposium: Ion Selective Electrodes. J. Chem. Ed. 74, 159 (1997).
26. 26. J. Rudzicka, J. Chem. Ed. 74, 167 (1997).
27. 27. A. Haghtalab and J. H. Vera, J. Chem. Eng. Data 36, 332 (1991).
28. 28. A. Haghtalab and J. H. Vera, J. Solution Chem. 20, 479 (1991).
29. 29. M. K. Khoshkbarchi and J. H. Vera, AIChE J. 42, 2354 (1996).
30. 30. M. K. Khoshkbarchi and J. H. Vera, J. Solution Chem. 25, 865 (1996).
31. 31. M. K. Khoshkbarchi and J. H. Vera, Ind. Eng. Chem. Res. 35, 2735 (1996).
32. 32. A. M. Soto-Campos, M. K. Khoshkbarchi, and J. H. Vera, Biophys. Chem. 67, 95 (1997).
33. 33. M. K. Khoshkbarchi, A. M. Soto-Campos, and J. H. Vera, J. Solution Chem. 26, 941 (1997).
34. 34. A. M. Soto-Campos, M. K. Khoshkbarchi, and J. H. Vera, Fluid Phase Equilibria 142, 193 (1998).
35. 35. G. Kakabadse, Ion-Selective Electrode Rev. 3, 127 (1981).
36. 36. A. Haghtalab, Ph. D. Thesis, McGill University, 1990.
37. 37. P. B. Taylor, J. Phys. Chem. 31, 1478 (1927).
38. 38. J. W. Gibbs, Collected Works, Vol. 1 (Longmans Green, New York, 1928).
39. 39. D. A. MacInnes, D. Belcher, and T. Shedlovsky, J. Amer. Chem. Soc. 60, 1094 (1938).
40. 40. H. S. Harned and B. B. Owen, The Physical Chemistry of Electrolyte Solutions, 3rd edn. (Reinhold, New York, 1958).
41. 41. R. R. Bates, Determination of pH; Theory and Practice, 2nd ed. (Wiley, New York, 1965).
42. 42. R. A. Robinson and R. H. Stokes, Electrolyte Solutions, 2nd edn. (Butterworths, Boston, 1959).
43. 43. M. K. Khoshkbarchi, Data Files kept by J. H. Vera at McGill University following Faculty Regulations (1998).
44. 44. D. J. G. Ives and G. J. Janz, Reference Electrodes (Academic Press, New York, 1961).
45. 45. D. A. Skoog and J. J. Leary, Principles of Instrumental Analysis (Saunders, New York, 1992).
46. 46. W. J. Hamer and Y. Ch. Wu, J. Phys. Chem. Ref. Data 1, 1047 (1972).
47. 47. I. D. Zaytsev and G. G. Aseyev, Properties of Aqueous Solutions of Electrolytes (CRC Press, Boca Raton, FL, 1992).
48. 48. S.-H. Chong and F. Hirata, J. Phys. Chem. B 101, 3209 (1997).
49. 49. G. N. Lewis and M. Randall, Thermodynamics, 2nd edn. revised by K. S. Pitzer and L. Brewer (McGraw-Hill, New York, 1961).
50. 50. R. H. Stokes and R. A. Robinson, J. Amer. Chem. Soc. 70, 1870 (1948).
51. 51. M. A. Burghes, Metal Ions in Solutions (Ellis Horwood, Wiley, New York, 1978).
52. 52. O. Ya. Samoilov, Structure of Aqueous Electrolyte Solutions and the Hydration of Ions translated by D. J. G. Ives (Consultants Bureau, New York, 1965).
53. 53. J. E. Desnoyers and C. Jolicoeur, in Modern Aspects of Electrochemistry, No. 5, J. O'M. Bockris and B. E. Conway, eds. (Plenum Press, New York, 1969).
54. 54. D. A. Skoog, F. J. Holler, and T. A. Nieman, Principles of Instrumental Analysis, 5th edn. (Saunders, New York, 1998), p. A-26.
55. 55. J. N. Butler, with a chapter by D. R. Cogley, Ionic Equilibrium: Solubility and pH Calculations, 1st edn. (Wiley, New York, 1998), p. 462.