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67650358519
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N-(3-(2-Chlorophenyl)-4-methylthiazol-2(3H)-ylidene)-2-methylbenzamide (2b) IR (KBr, 2938 (CH3, 1673 (CO, 1600 (C{double bond, long}C, 1514, 1572 (C{double bond, long}N, 1265 (C{single bond}S, 1152 (C{single bond}N, 1050, 783, 736, 700 cm-1; 1H NMR (400 MHz, CDCl3, δ ppm):7.83 (d, 1H, Ar-H, 7.26 (dt, 1H, J, 1.8, 7.8 Hz, Ar-H, 7.32 (m, 2H, Ar-H, 6.43 (q, 1H, J, 1.2 Hz, CH{double bond, long}C, 2.48 (s, 3H, ArCH3, 2.06 (d, 3H, J, 1.2 Hz, CH3, 13C NMR (100 MHz, CDCl3, δ ppm, 16.7 (ArCH3, 14.29 (CH3, 104.4 (CH{double bond, long}C, 116.7, 116.8, 123.4, 124.7, 125.1 130.3, 131.2, 132.1, 132.6, 134.0, 157.6, 162.3, 169.7 (C{double bond, long}N, 173.4 (C{double bond, long}O, Anal. Calcd. for C18H15ClN2OS: C, 63.06; H, 4.41; N, 8.17; S, 9.35, Found: C, 63.01; H, 4.44; N, 8.24; S, 9.31, GC-MS: m/z, 344 7.1, 342
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+), 253 (19.8), 251 (6.2), 217 (12.0), 215.1 (36.0), 151 (9.0), 149 (9.0), 119 (100), 91 (51.6), 65 (22), 57 (39.0).
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