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Crystal data for 1: C44H34Cl8FeN 8O8, MW 1142.27, monoclinic, space group P2 1/n (no. 14, a=12.4753 (5, b=13.8140 (7, c=13.2608 (5) Å, β=93.4510 (5) °, V=2281.14 (17) Å3, Z=2, Dcalcd=1.663gcm-3, T=200K, of the 22079 reflections which were collected, 5213 were unique (Rint=0.044) used in refinement, Rl=0.0426 (5126 data, I > 2σ (I, wR2=0.105 (all data, GOF=1.08, CCDC-727004. Crystal data for 2: C14H34Cl 8CoN8O8, MW 1145.36, monoclinic, space group P21/n (no. 14, a=12.493 (3, b=13.906 (4, c=13.217 (4) Å, β,=93.273 (3) °, V=2292.4 (11) Å3, Z=2, Dcalcd=1.659 g cm -3, T
-
int=0.024) used in refinement. R1=0.039 (5242 data, I > 2σ (I)), wR2=0.094 (all data), GOF=1.08, CCDC-727005.
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