Synthesis and Characterization of a Family of Systematically Varied Tris(2-pyridyl)methoxymethane Ligands: Copper(I) and Copper(II) Complexes

Inorganic Chemistry

Volumn 37, Issue 26, 1998, Pages 6615-6629

  Jonas, Robert T ^a   Stack, T D P ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001513105     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9713487     Document Type: Article

References (58)

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44. Bis-tris Cu(II) complexes with 3-fold symmetic ligands: (a) Bis(hydrotris(1-pyrazolyl)borate: Mutphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trans. 1979, 1646-1650. (b) Bis(cis,cis-1,3,5-triaminocyclohexane: Ammeter, J. H.; Bürgi, H. B.; Gamp, E.; Meyer-Sandrin, V.; Jensen, W. P. Inorg. Chem. 1979, 18, 733-750. (c) Bis(1,4,7-triazacyclononane-N, N'N"): Chaudhuri, P.; Oder, K.; Wieghardt, K.; Weiss, J.; Reedijk, J.; Hinrichs, W.; Wood, J.; Ozarowski, A.; Stratemaier, H.; Reinen, D. Inorg. Chem. 1986, 25, 2951-2958. (d) Bis(hydrotris(3,5-dimethyl-1-pyrazolyl)borate-N,N'N"): Kitajima, N.; Moro-oka, Y.; Uchida, A.; Sasada, Y.; Ohashi, Y. Acta Crystallogr., Sect. C 1988, 44, 1876-1878. (e) 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Hegetschweiler, K.; Gramlich, V.; Ghisletta, M.; Samaras, H. Inorg. Chem. 1992, 31, 2341-2346. (f) Bis(tris(pyrazol-1-yl)methane-N,N',N"): Astley, T.; Gulbis, J. M.; Hitchman, M. A.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1993, 509-515. (g) Bis(hydrotris(1,2,4-triazolyl)borate-N,N',N"): Janiak, C. Chem. Ber. 1994, 127, 1379-1385. (h) Bis(tris(2-pyridyl)methane): Astley, T.; Headlam, H.; Hitchman, M. A.; Keene, F. R.; Pilbrow, J.; Stratemeier, H.; Tiekink, E. R. T.; Zhong, Y. C. J. Chem. Soc., Dalton Trans. 1995, 3809-3818. (i) Bis(tris(2-pyridyl)phosphine): Astley, T.; Ellis, P. J.; Freeman, H. C.; Hitchman, M. A.; Keene, F. R.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1995, 595-601.
45. Bis-tris Cu(II) complexes with 3-fold symmetic ligands: (a) Bis(hydrotris(1-pyrazolyl)borate: Mutphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trans. 1979, 1646-1650. (b) Bis(cis,cis-1,3,5-triaminocyclohexane: Ammeter, J. H.; Bürgi, H. B.; Gamp, E.; Meyer-Sandrin, V.; Jensen, W. P. Inorg. Chem. 1979, 18, 733-750. (c) Bis(1,4,7-triazacyclononane-N, N'N"): Chaudhuri, P.; Oder, K.; Wieghardt, K.; Weiss, J.; Reedijk, J.; Hinrichs, W.; Wood, J.; Ozarowski, A.; Stratemaier, H.; Reinen, D. Inorg. Chem. 1986, 25, 2951-2958. (d) Bis(hydrotris(3,5-dimethyl-1-pyrazolyl)borate-N,N'N"): Kitajima, N.; Moro-oka, Y.; Uchida, A.; Sasada, Y.; Ohashi, Y. Acta Crystallogr., Sect. C 1988, 44, 1876-1878. (e) 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Hegetschweiler, K.; Gramlich, V.; Ghisletta, M.; Samaras, H. Inorg. Chem. 1992, 31, 2341-2346. (f) Bis(tris(pyrazol-1-yl)methane-N,N',N"): Astley, T.; Gulbis, J. M.; Hitchman, M. A.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1993, 509-515. (g) Bis(hydrotris(1,2,4-triazolyl)borate-N,N',N"): Janiak, C. Chem. Ber. 1994, 127, 1379-1385. (h) Bis(tris(2-pyridyl)methane): Astley, T.; Headlam, H.; Hitchman, M. A.; Keene, F. R.; Pilbrow, J.; Stratemeier, H.; Tiekink, E. R. T.; Zhong, Y. C. J. Chem. Soc., Dalton Trans. 1995, 3809-3818. (i) Bis(tris(2-pyridyl)phosphine): Astley, T.; Ellis, P. J.; Freeman, H. C.; Hitchman, M. A.; Keene, F. R.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1995, 595-601.
46. Bis-tris Cu(II) complexes with 3-fold symmetic ligands: (a) Bis(hydrotris(1-pyrazolyl)borate: Mutphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trans. 1979, 1646-1650. (b) Bis(cis,cis-1,3,5-triaminocyclohexane: Ammeter, J. H.; Bürgi, H. B.; Gamp, E.; Meyer-Sandrin, V.; Jensen, W. P. Inorg. Chem. 1979, 18, 733-750. (c) Bis(1,4,7-triazacyclononane-N, N'N"): Chaudhuri, P.; Oder, K.; Wieghardt, K.; Weiss, J.; Reedijk, J.; Hinrichs, W.; Wood, J.; Ozarowski, A.; Stratemaier, H.; Reinen, D. Inorg. Chem. 1986, 25, 2951-2958. (d) Bis(hydrotris(3,5-dimethyl-1-pyrazolyl)borate-N,N'N"): Kitajima, N.; Moro-oka, Y.; Uchida, A.; Sasada, Y.; Ohashi, Y. Acta Crystallogr., Sect. C 1988, 44, 1876-1878. (e) 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Hegetschweiler, K.; Gramlich, V.; Ghisletta, M.; Samaras, H. Inorg. Chem. 1992, 31, 2341-2346. (f) Bis(tris(pyrazol-1-yl)methane-N,N',N"): Astley, T.; Gulbis, J. M.; Hitchman, M. A.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1993, 509-515. (g) Bis(hydrotris(1,2,4-triazolyl)borate-N,N',N"): Janiak, C. Chem. Ber. 1994, 127, 1379-1385. (h) Bis(tris(2-pyridyl)methane): Astley, T.; Headlam, H.; Hitchman, M. A.; Keene, F. R.; Pilbrow, J.; Stratemeier, H.; Tiekink, E. R. T.; Zhong, Y. C. J. Chem. Soc., Dalton Trans. 1995, 3809-3818. (i) Bis(tris(2-pyridyl)phosphine): Astley, T.; Ellis, P. J.; Freeman, H. C.; Hitchman, M. A.; Keene, F. R.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1995, 595-601.
47. Bis-tris Cu(II) complexes with 3-fold symmetic ligands: (a) Bis(hydrotris(1-pyrazolyl)borate: Mutphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trans. 1979, 1646-1650. (b) Bis(cis,cis-1,3,5-triaminocyclohexane: Ammeter, J. H.; Bürgi, H. B.; Gamp, E.; Meyer-Sandrin, V.; Jensen, W. P. Inorg. Chem. 1979, 18, 733-750. (c) Bis(1,4,7-triazacyclononane-N, N'N"): Chaudhuri, P.; Oder, K.; Wieghardt, K.; Weiss, J.; Reedijk, J.; Hinrichs, W.; Wood, J.; Ozarowski, A.; Stratemaier, H.; Reinen, D. Inorg. Chem. 1986, 25, 2951-2958. (d) Bis(hydrotris(3,5-dimethyl-1-pyrazolyl)borate-N,N'N"): Kitajima, N.; Moro-oka, Y.; Uchida, A.; Sasada, Y.; Ohashi, Y. Acta Crystallogr., Sect. C 1988, 44, 1876-1878. (e) 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Hegetschweiler, K.; Gramlich, V.; Ghisletta, M.; Samaras, H. Inorg. Chem. 1992, 31, 2341-2346. (f) Bis(tris(pyrazol-1-yl)methane-N,N',N"): Astley, T.; Gulbis, J. M.; Hitchman, M. A.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1993, 509-515. (g) Bis(hydrotris(1,2,4-triazolyl)borate-N,N',N"): Janiak, C. Chem. Ber. 1994, 127, 1379-1385. (h) Bis(tris(2-pyridyl)methane): Astley, T.; Headlam, H.; Hitchman, M. A.; Keene, F. R.; Pilbrow, J.; Stratemeier, H.; Tiekink, E. R. T.; Zhong, Y. C. J. Chem. Soc., Dalton Trans. 1995, 3809-3818. (i) Bis(tris(2-pyridyl)phosphine): Astley, T.; Ellis, P. J.; Freeman, H. C.; Hitchman, M. A.; Keene, F. R.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1995, 595-601.
48. Bis-tris Cu(II) complexes with 3-fold symmetic ligands: (a) Bis(hydrotris(1-pyrazolyl)borate: Mutphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trans. 1979, 1646-1650. (b) Bis(cis,cis-1,3,5-triaminocyclohexane: Ammeter, J. H.; Bürgi, H. B.; Gamp, E.; Meyer-Sandrin, V.; Jensen, W. P. Inorg. Chem. 1979, 18, 733-750. (c) Bis(1,4,7-triazacyclononane-N, N'N"): Chaudhuri, P.; Oder, K.; Wieghardt, K.; Weiss, J.; Reedijk, J.; Hinrichs, W.; Wood, J.; Ozarowski, A.; Stratemaier, H.; Reinen, D. Inorg. Chem. 1986, 25, 2951-2958. (d) Bis(hydrotris(3,5-dimethyl-1-pyrazolyl)borate-N,N'N"): Kitajima, N.; Moro-oka, Y.; Uchida, A.; Sasada, Y.; Ohashi, Y. Acta Crystallogr., Sect. C 1988, 44, 1876-1878. (e) 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Hegetschweiler, K.; Gramlich, V.; Ghisletta, M.; Samaras, H. Inorg. Chem. 1992, 31, 2341-2346. (f) Bis(tris(pyrazol-1-yl)methane-N,N',N"): Astley, T.; Gulbis, J. M.; Hitchman, M. A.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1993, 509-515. (g) Bis(hydrotris(1,2,4-triazolyl)borate-N,N',N"): Janiak, C. Chem. Ber. 1994, 127, 1379-1385. (h) Bis(tris(2-pyridyl)methane): Astley, T.; Headlam, H.; Hitchman, M. A.; Keene, F. R.; Pilbrow, J.; Stratemeier, H.; Tiekink, E. R. T.; Zhong, Y. C. J. Chem. Soc., Dalton Trans. 1995, 3809-3818. (i) Bis(tris(2-pyridyl)phosphine): Astley, T.; Ellis, P. J.; Freeman, H. C.; Hitchman, M. A.; Keene, F. R.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1995, 595-601.
49. Bis-tris Cu(II) complexes with 3-fold symmetic ligands: (a) Bis(hydrotris(1-pyrazolyl)borate: Mutphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trans. 1979, 1646-1650. (b) Bis(cis,cis-1,3,5-triaminocyclohexane: Ammeter, J. H.; Bürgi, H. B.; Gamp, E.; Meyer-Sandrin, V.; Jensen, W. P. Inorg. Chem. 1979, 18, 733-750. (c) Bis(1,4,7-triazacyclononane-N, N'N"): Chaudhuri, P.; Oder, K.; Wieghardt, K.; Weiss, J.; Reedijk, J.; Hinrichs, W.; Wood, J.; Ozarowski, A.; Stratemaier, H.; Reinen, D. Inorg. Chem. 1986, 25, 2951-2958. (d) Bis(hydrotris(3,5-dimethyl-1-pyrazolyl)borate-N,N'N"): Kitajima, N.; Moro-oka, Y.; Uchida, A.; Sasada, Y.; Ohashi, Y. Acta Crystallogr., Sect. C 1988, 44, 1876-1878. (e) 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Hegetschweiler, K.; Gramlich, V.; Ghisletta, M.; Samaras, H. Inorg. Chem. 1992, 31, 2341-2346. (f) Bis(tris(pyrazol-1-yl)methane-N,N',N"): Astley, T.; Gulbis, J. M.; Hitchman, M. A.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1993, 509-515. (g) Bis(hydrotris(1,2,4-triazolyl)borate-N,N',N"): Janiak, C. Chem. Ber. 1994, 127, 1379-1385. (h) Bis(tris(2-pyridyl)methane): Astley, T.; Headlam, H.; Hitchman, M. A.; Keene, F. R.; Pilbrow, J.; Stratemeier, H.; Tiekink, E. R. T.; Zhong, Y. C. J. Chem. Soc., Dalton Trans. 1995, 3809-3818. (i) Bis(tris(2-pyridyl)phosphine): Astley, T.; Ellis, P. J.; Freeman, H. C.; Hitchman, M. A.; Keene, F. R.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1995, 595-601.
50. Bis-tris Cu(II) complexes with 3-fold symmetic ligands: (a) Bis(hydrotris(1-pyrazolyl)borate: Mutphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trans. 1979, 1646-1650. (b) Bis(cis,cis-1,3,5-triaminocyclohexane: Ammeter, J. H.; Bürgi, H. B.; Gamp, E.; Meyer-Sandrin, V.; Jensen, W. P. Inorg. Chem. 1979, 18, 733-750. (c) Bis(1,4,7-triazacyclononane-N, N'N"): Chaudhuri, P.; Oder, K.; Wieghardt, K.; Weiss, J.; Reedijk, J.; Hinrichs, W.; Wood, J.; Ozarowski, A.; Stratemaier, H.; Reinen, D. Inorg. Chem. 1986, 25, 2951-2958. (d) Bis(hydrotris(3,5-dimethyl-1-pyrazolyl)borate-N,N'N"): Kitajima, N.; Moro-oka, Y.; Uchida, A.; Sasada, Y.; Ohashi, Y. Acta Crystallogr., Sect. C 1988, 44, 1876-1878. (e) 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Hegetschweiler, K.; Gramlich, V.; Ghisletta, M.; Samaras, H. Inorg. Chem. 1992, 31, 2341-2346. (f) Bis(tris(pyrazol-1-yl)methane-N,N',N"): Astley, T.; Gulbis, J. M.; Hitchman, M. A.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1993, 509-515. (g) Bis(hydrotris(1,2,4-triazolyl)borate-N,N',N"): Janiak, C. Chem. Ber. 1994, 127, 1379-1385. (h) Bis(tris(2-pyridyl)methane): Astley, T.; Headlam, H.; Hitchman, M. A.; Keene, F. R.; Pilbrow, J.; Stratemeier, H.; Tiekink, E. R. T.; Zhong, Y. C. J. Chem. Soc., Dalton Trans. 1995, 3809-3818. (i) Bis(tris(2-pyridyl)phosphine): Astley, T.; Ellis, P. J.; Freeman, H. C.; Hitchman, M. A.; Keene, F. R.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1995, 595-601.
51. Bis-tris Cu(II) complexes with 3-fold symmetic ligands: (a) Bis(hydrotris(1-pyrazolyl)borate: Mutphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trans. 1979, 1646-1650. (b) Bis(cis,cis-1,3,5-triaminocyclohexane: Ammeter, J. H.; Bürgi, H. B.; Gamp, E.; Meyer-Sandrin, V.; Jensen, W. P. Inorg. Chem. 1979, 18, 733-750. (c) Bis(1,4,7-triazacyclononane-N, N'N"): Chaudhuri, P.; Oder, K.; Wieghardt, K.; Weiss, J.; Reedijk, J.; Hinrichs, W.; Wood, J.; Ozarowski, A.; Stratemaier, H.; Reinen, D. Inorg. Chem. 1986, 25, 2951-2958. (d) Bis(hydrotris(3,5-dimethyl-1-pyrazolyl)borate-N,N'N"): Kitajima, N.; Moro-oka, Y.; Uchida, A.; Sasada, Y.; Ohashi, Y. Acta Crystallogr., Sect. C 1988, 44, 1876-1878. (e) 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Hegetschweiler, K.; Gramlich, V.; Ghisletta, M.; Samaras, H. Inorg. Chem. 1992, 31, 2341-2346. (f) Bis(tris(pyrazol-1-yl)methane-N,N',N"): Astley, T.; Gulbis, J. M.; Hitchman, M. A.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1993, 509-515. (g) Bis(hydrotris(1,2,4-triazolyl)borate-N,N',N"): Janiak, C. Chem. Ber. 1994, 127, 1379-1385. (h) Bis(tris(2-pyridyl)methane): Astley, T.; Headlam, H.; Hitchman, M. A.; Keene, F. R.; Pilbrow, J.; Stratemeier, H.; Tiekink, E. R. T.; Zhong, Y. C. J. Chem. Soc., Dalton Trans. 1995, 3809-3818. (i) Bis(tris(2-pyridyl)phosphine): Astley, T.; Ellis, P. J.; Freeman, H. C.; Hitchman, M. A.; Keene, F. R.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1995, 595-601.
52. Bis-tris Cu(II) complexes with 3-fold symmetic ligands: (a) Bis(hydrotris(1-pyrazolyl)borate: Mutphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trans. 1979, 1646-1650. (b) Bis(cis,cis-1,3,5-triaminocyclohexane: Ammeter, J. H.; Bürgi, H. B.; Gamp, E.; Meyer-Sandrin, V.; Jensen, W. P. Inorg. Chem. 1979, 18, 733-750. (c) Bis(1,4,7-triazacyclononane-N, N'N"): Chaudhuri, P.; Oder, K.; Wieghardt, K.; Weiss, J.; Reedijk, J.; Hinrichs, W.; Wood, J.; Ozarowski, A.; Stratemaier, H.; Reinen, D. Inorg. Chem. 1986, 25, 2951-2958. (d) Bis(hydrotris(3,5-dimethyl-1-pyrazolyl)borate-N,N'N"): Kitajima, N.; Moro-oka, Y.; Uchida, A.; Sasada, Y.; Ohashi, Y. Acta Crystallogr., Sect. C 1988, 44, 1876-1878. (e) 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Hegetschweiler, K.; Gramlich, V.; Ghisletta, M.; Samaras, H. Inorg. Chem. 1992, 31, 2341-2346. (f) Bis(tris(pyrazol-1-yl)methane-N,N',N"): Astley, T.; Gulbis, J. M.; Hitchman, M. A.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1993, 509-515. (g) Bis(hydrotris(1,2,4-triazolyl)borate-N,N',N"): Janiak, C. Chem. Ber. 1994, 127, 1379-1385. (h) Bis(tris(2-pyridyl)methane): Astley, T.; Headlam, H.; Hitchman, M. A.; Keene, F. R.; Pilbrow, J.; Stratemeier, H.; Tiekink, E. R. T.; Zhong, Y. C. J. Chem. Soc., Dalton Trans. 1995, 3809-3818. (i) Bis(tris(2-pyridyl)phosphine): Astley, T.; Ellis, P. J.; Freeman, H. C.; Hitchman, M. A.; Keene, F. R.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1995, 595-601.
53. 2+, 0.89 where T = (mean in-plane Cu-L bond distance/mean out-of-plane Cu-L bond distance). Generally, most Cu(II) tetragonally distorted complexes with T values in the range of 0.80-0.85 have static structures, while complexes with T values > 0.85 suggest potential dynamic distortions; see: Murphy, A.; Hathaway, B. J.; King, T. J. J. Chem. Soc., Dalton Trims. 1979, 11, 1646-1650.
54. + complexes is complicated by the formation of the bis-ligated species upon addition of free ligand.
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