Mono(aryloxido)titanium(IV) Complexes and their application in the selective dimerization of ethylene

European Journal of Inorganic Chemistry

Volumn , Issue 20, 2009, Pages 2942-2950

  Cazaux, Jean Benoit ^a   Braunstein, Pierre ^b   Magna, Lionel ^a   Saussine, Lucien ^a   Olivier Bourbigou, Hélène ^a  

^a IFP ENERGIES NOUVELLES   (France)

^b UNIVERSITÉ LOUIS PASTEUR   (France)

Author keywords

Dimerization; Hemilability; O ligands; Structure activity relationships; Titanium

Indexed keywords

CATALYST ACTIVITY; ETHYLENE; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL); TITANIUM COMPOUNDS; X RAY DIFFRACTION;

BRIDGING LIGANDS; DIMERIZATIONS; DINUCLEAR COMPLEX; GENERAL FORMULAS; HEMILABILITY; MONONUCLEAR COMPLEXES; O LIGANDS; STRUCTURE-ACTIVITY RELATIONSHIPS; TITANIA; X- RAY DIFFRACTIONS;

DIMERIZATION;

EID: 67650422409     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200900322     Document Type: Article

References (66)

1. D. Vogt, "Oligomerization of Ethylene to Higher Linear Alpha Olefins" in Applied Homogeneous catalysis with Organometallic Compounds (Eds.: B. Cornils, W A. Hermann), 1st ed., WileyVCH, Weinheim, Germany, 2002, p. 245.
2. J. T Dixon, M. J. Green, F. M. Hess, D. H. Morgan, J. Organomet. Chem. 2004, 689, 3641.
3. W K. Reagen, B. K. Conroy, Patent US 5,198,563, 1993.
4. F. J. Wu, Patent EP0537609B1, 1996.
5. R. Köhn, M. Haufe, G. Kociok-Koehn, S. Grimm, P. Wasserscheid, W Keim, Angew. Chem. Int, Ed, 2000, 39, 4337.
6. T Yoshida, T Yamamoto, H. Okada, H. Murakita, Patent US 20020035029Al, 2002.
7. F. J. Wu, Patent US 5,811,618, Aug 25, 1995.
8. A. Carter, S. A. Cohen, N. A. Cooley, A. Murphy, J. Scutt, D. F. Wass, Chem. Commun. 2002, 858.
9. D. S. McGuinness, P. Wasserscheid, W Keim, C. Hu, U. Englert, J. T. Dixon, J. J. C. Grove, Chem, Commun. 2003, 334.
10. D. S. McGuinness, P. Wasserscheid, W Keim, D. H. Morgan, J T. Dixon, A. Bollmann, H. Maumela, F. M. Hess, U. Englert, J. Am, Chem, Soc 2003, 125, 5272.
11. K. Blann, A. Bollmann, J T. Dixon, F. M. Hess, E. Killian, H. Maumela, D. H. Morgan, A. Neveling, S. Otto, M. J. Overett, Chem. Commun. 2005, 620.
12. W J. Van Rensburg, J. J. C. Grove, J. P. Steynberg, K. B. Stark, J. J. Huyser, P. J. Steynberg, Organometallics 2004, 23, 1207.
13. T. Agapie, M. W. Day, L. W. Henling, J. A. Labinger, J. E. Bercaw, Organometallics 2006, 25, 2733.
14. K. Blann, À. Bollmann, J. T. Dixon, A. Neveling, D. H. Morgan, H. Maumela, E. Killian, F. Hess, S. Otto, L. Pepler, H. A. Mahomed, M. J. Overett, Patent WO 2004/056479 Al, 2004.
15. A. Bollmann, K. Blann, J. T. Dixon, F. M. Hess, E. Killian, H. Maumela, D. S. McGuinness, D. H. Morgan, A. Neveling, S. Otto, M. Overett, A. M. Z. Slawin, P. Wasserscheid, S. Kuhlmann, J. Am, Chem, Soc. 2004, 126, 14712.
16. M. J Overett, K. Blann, A. Bollmann, J. T Dixon, D. Haasbroek, E. Killian, H. Maumela, D. S. McGuinness, D. H. Morgan, J. Am. Chem. Soc. 2005, 127, 10723.
17. M. J. Overett, K. Blann, A. Bollmann, J. T. Dixon, F. Hess, E. Killian, H. Maumela, D. H. Morgan, A. Neveling, S. Otto, Chem. Commun. 2005, 622.
18. A. Jabri, P. Crewdson, S. Gambarotta, I. Korobkov, R. Duchateau, Organometallics 2006, 25, 715.
19. S. Kuhlmann, J. T. Dixon, M. Haumann, D. H. Morgan, J. Ofili, O. Spuhl, N. Taccardi, P. Wasserscheid, Adv. Svnth. Catal. 2006, 348, 1200.
20. R. Walsh, D. H. Morgan, A. Bollmann, J. T. Dixon, Appl. Catal A 2006, 306, 184.
21. S. Kuhlmann, K. Blann, A. Bollmann, J. T Dixon, E. Killian, M. C. Maumela, H. Maumela, D. H. Morgan, M. Pretorius, N. Taccardi, P. Wasserscheid, J. Catal. 2007, 245, 279.
22. R. L. J. Coetzer, D. H. Morgan, H. Maumela, J. Appl. Statistics 2008, 35, 131.
23. J. Skupiftska, Chem. Rev. 1991, 91, 613.
24. S. M. Pillai, M. Ravindranathan, S. Sivaram, Chem. Rev. 1986, 86, 353.
25. A. M. Al-Jarallah, J. A. Anabtawi, M. A. B. Siddiqui, A. M. Aitani, A. W Al-Sa'doun, Catal. Today 1992, 14, 1;
26. A. W AlSa'doun, Appl. Catal. A 1993, 105, 1.
27. N. Le Quan, D. Cruypelinck, D. Commereuc, Y. Chauvin, G. Léger, Patent EP0135441B1,1985;
28. D. Commereuc, Y Chauvin, J. Gaillard, J. Léonard, J. Andrews, Hydrocarbon Processing 1984, 118.
29. P. J. W. Deckers, B. Hessen, J. H. Teuben, Angew. Chem. Int. Ed. 2001, 40, 2516.
30. P. J. W. Deckers, B. Hessen, J. H. Teuben, Organometallics 2002, 21, 5122.
31. B. Hessen, J. Mol. Catal, A 2004, 213, 129.
32. A. N. J. Blok, P. H. M. Budzelaar, A. W Gal, Organometallics 2003, 22, 2564.
33. T J. M. de Bruin, L. Magna, P. Raybaud, H. Toulhoat, Organometallics 2003, 22, 3404.
34. S. Tobisch, T. Ziegler, J. Am. Chem. Soc. 2004, 126, 9059.
35. S. Tobisch, T Ziegler, Organometallics 2004, 23, 4077.
36. J. Huang, T Wu, Y Qian, Chem. Commun. 2003, 2816.
37. T Wu, Y Qian, J. Huang, J. Mol. Catal. A 2004, 214, 227.
38. G. J. R Britovsek, V. C. Gibson, D. F. Wass, Angew. Chem. Int. Ed. 1999, 38, 428.
39. S. D. Ittel, L. K. Johnnson, M. Brookhart, Chem. Rev. 2000, 100, 1169.
40. V. C. Gibson, S. K. Spitzmesser, Chem. Rev. 2003, 103, 283.
41. D. C. Bradley, R. C. Mehrotra, I. P. Rothwell, A. Singh, Alkoxo and Aryloxo Derivatives of Metals, Academic Press, London, 2001.
42. Y Suzuki, H. Terao, T. Fujita, Buli. Chem. Soc. Jpn. 2003, 76, 1493.
43. [4I]S. Matsui, T Fujita, Catal Today 2001, 66, 63;
44. R. Furayama, J. Saito, S. Ishii, M. Mitani, S. Matsui, Y Tohi, H. Makio, N. Matsukawa, H. Tanaka, T Fujita, J. Mol. Catal. A 2003, 200, 31;
45. T Matsugi, T Fujita, Chem. Soc Rev. 2008, 37, 1264.
46. J Tian, G. W Coates, Angew. Chem. Int. Ed. 2000, 39, 3626.
47. D. C. H. Oakes, B. S. Kimberley, V. C. Gibson, D. J. Jones, A. J. R White, D. J. Williams, Chem. Commun. 2004, 2174.
48. A. R. F. Cox, V. C. Gibson, E. L. Marshall, A. J. P. White, D. Yeldon, Dalton Trans. 2006, 5014.
49. R. J. Long, V. C. Gibson, A. J. R White, D. J. Williams, Inorg. Chem. 2006, 45, 511.
50. L. Matilainen, M. Klinga, M. Leskela, J. Chem. Soc, Dalton Trans. 1996, 219.
51. T. A. Manz, K. Phomphrai, G. Medvedev, B. B. Krishnamurthy, S. Sharma, J. Haq, K. A. Novstrup, K. T. Thomson, W. N. Delgass, J. M. Caruthers, M. M. Abu-Omar, J. Am. Chem. Soc. 2007, 129, 3776-3777.
52. F-W Küpper, Appl, Catal A 2004, 264, 253.
53. T. Maki, Y Araki, Y. Ishida, O. Onomura, Y. Matsumura, J. Am. Chem. Soc. 2001, 123, 3371.
54. S. Fokken, T P. Spaniol, H. C. Rang, W Massa, J. Okuda, Organometallics 1996, 15, 5069.
55. D. R. Mulford, P. E. Fanwick, I. P. Rothwell, Polyhedron 2000, 19, 35.
56. S. Groysman, E. Sergeeva, I. Goldberg, M. Kol, Inorg. Chem. 2005, 44, 8188.
57. D. A. Pennington, W Clegg, S. J. Coles, R. W Harrington, M. B. Hursthouse, D. L. Hughes, M. E. Light, M. Schormann, M. Bochmann, S. J. Lancaster, Dalton Trans. 2005, 561.
58. P. Braunstein, F. Naud, Angew. Chem. Int, Ed. 2001, 40, 680;
59. L. Annunziata, D. Pappalardo, C. Tedesco, C. Pellechia, Organometallics 2009, 28, 688-697.
60. C. Floriáni, F. Corazza, W Lesueur, A. Chiesi-Villa, C. Guastini, Angew. Chem. Int. Ed. Engl. 1989, 28, 66.
61. c = 273 K).
62. A. Bre, Y Chauvin, D. Commereuc, New J. Chem. 1986, 10, 34.
63. H. Makio, T Fujita, Macromol, Symp. 2004, 213, 221.
64. 2AlCl (Al/Ti = 15). For each preliminary test, more than 80% of polyethylene was produced. Results are not presented in detail because of reaction conditions not optimized for polymerization.
65. Bruker-Nonius, Kappa CCD Reference Manual, Nonius BV, The Netherlands, 1998.
66. G. M. Sheldrick, SHELXL-97: Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.