Models for homogeneous deep hydrodesulfurization. Intramolecular CO substitution by the sulfur in [(η6-2-methylbenzothiophene)Mn(CO)3]+ and [(η6-dibenzothiophene)Mn(CO)3]+ after regiospecific insertion of platinum into a C-S bond

Organometallics

Volumn 19, Issue 10, 2000, Pages 1823-1825

  Li, Huazhi ^a   Carpenter, Gene B ^a   Sweigart, Dwight A ^a  

^a BROWN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001237667     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000100d     Document Type: Article

References (35)

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30. 4. The latter nucleophile, which gives the same product as the former, was subsequently found to be more generally useful in reactions of thiophenic complexes.
31. 4: C, 52.97; H, 3.56. Found: C, 52.70; H, 3.63.
32. -1, θ range 1.88-27.88°, 533 variables refined with 10 243 independent reflections to final R indices (I > 2σ(I)) of R1 = 0.0392 and wR2 = 0.0922, and GOF = 1.080.
33. Watson, E. J.; Li, H.; Sweigart, D. A. Unpublished results.
34. -1, θ range 1.62-26.45°, 385 variables refined with 6636 independent reflections to final R indices (I > 2σ(I) of R1 = 0.0590 and wR2 = 0.1500, and GOF = 1.117.
35. +).