Coordination study of rare earth elements on Fe oxyhydroxide and Mn dioxides: Part ii. Correspondence of structural change to irregular variations of partitioning coeffcients and tetrad effect variations appearing in interatomic distances

American Mineralogist

Volumn 94, Issue 4, 2009, Pages 476-486

  Ohta, Atsuyuki ^a   Kagi, Hiroyuki ^b   Nomura, Masaharu ^c   Shitsuno, Hiro ^d   Kawabe, Iwao ^e  

^a GEOLOGICAL SURVEY OF JAPAN   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

^c INSTITUTE OF MATERIALS STRUCTURE SCIENCE   (Japan)

^d YOKOHAMA NATIONAL UNIVERSITY   (Japan)

^e NAGOYA UNIVERSITY   (Japan)

Author keywords

Iron oxyhydroxide; Manganese dioxide; Rare earth elements; Structural change; Tetrad effect; X ray absorption spectra; Y fractionation from Ho

Indexed keywords

ERBIUM ALLOYS; EXTENDED X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; RARE EARTH ELEMENTS; RARE EARTHS; THULIUM ALLOYS; X RAY ABSORPTION;

DISTRIBUTION COEFFICIENT; EXTENDED XRAY ABSORPTION FINE STRUCTURE (EXAFS) SPECTROSCOPIES; INTER-ATOMIC DISTANCES; IRON OXYHYDROXIDES; MANGANESE DIOXIDE; RARE EARTH ELEMENTS (REES); STRUCTURAL CHANGE; TETRAD EFFECTS;

MANGANESE OXIDE;

CRYSTAL STRUCTURE; FRACTIONATION; IRON HYDROXIDE; MANGANESE OXIDE; PARTITION COEFFICIENT; RARE EARTH ELEMENT; X-RAY SPECTROSCOPY;

EID: 67650287917     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2009.2987     Document Type: Article

References (66)

1. Allen, P. G., Bucher, J. J., Shuh, D. K., Edelstein, N. M., and Craig, I. (2000) Coordination chemistry of trivalent lanthanide and actinide ions in dilute and concentrated chloride solutions. Inorganic Chemistry, 39, 595-601.
2. 3+ up to 300 °C and 1600 bars. American Mineralogist, 87, 262-268.
3. Ankudinov, A. L., Bouldin, C. E., Rehr, J. J., Sims, J., and Hung, H. (2002) Parallel calculation of electron multiple scattering using Lanczos algorithms. Physical Review B., 65, 104107.1-104107.11.
4. Bau, M. (1999) Scavenging of dissolved yttrium and rare earths by precipitating iron oxyhydroxide: Experimental evidence for Ce oxidation, Y-Ho fractionation, and lanthanide tetrad effect. Geochimica et Cosmochimica Acta, 63, 67-77.
5. Bau, M., Dulski, P., and Möller, P. (1995) Yttrium and holmium in south Pacific seawater: Vertical-distribution and possible fractionation mechanisms. Chemie der Erde-Geochemistry, 55, 1-16.
6. Bau, M., Koschinsky, A., Dulski, P., and Hein, J. R. (1996) Comparison of the partitioning behaviours of yttrium, rare earth elements, and titanium between hydrogenetic marine ferromanganese crusts and seawater. Geochimica et Cosmochimica Acta, 60, 1709-1725.
7. Beall, G. W., Milligan, W. A., and Wolcott, H. A. (1977) Structural trends in the lanthanide trihydroxides. Journal of Inorganic and Nuclear Chemistry, 39, 65-70.
8. Bratsch, S. and Silber, H. B. (1982) Lanthanide thermodynamic predictions. Polyhedron, 1, 219-223.
9. Brown, I. D. and Shannon, R. D. (1973) Empirical bond-strength-bond- length curves for oxides. Acta Crystallographica A: Crystal Physics, Diffraction, Theoretical and General Crystallography, A29, 266-282.
10. Caro, P., Derouet, J., Beaury, L., de Sagey, G. T., Chaminade, J. P., Aride, J., and Pouchard, M. (1981) Interpretation of the optical absorption spectrum and of the paramagnetic susceptibility of neodymium trifluoride. The Journal of Chemical Physics, 74, 2698-2704.
11. 4, 5-edge transitions. Physical Review B., 49, 5869-5875.
12. Chaboy, J., Marcelli, A., and Tyson, T. A. (1994) Influence of double-electron transitions on the EXAFS L edges of rare-earth systems. Physical Review B., 49, 11652-11661.
13. Combes, J. M., Manceau, A., Calas, G., and Bottero, J. Y. (1989) Formation of ferric oxides from aqueous-solutions: A polyhedral approach by X-ray absorptionspectroscopy. I. Hydrolysis and formation of ferric gels. Geochimica et Cosmochimica Acta, 53, 583-594.
14. Dardenne, K., Schafer, T., Denecke, M. A., Rothe, J., and Kim, J. I. (2001) Identification and characterization of sorbed lutetium species on 2-line ferrihydrite by sorption data modeling, TRLFS and EXAFS. Radiochimica Acta, 89, 469-479.
15. Dardenne, K., Schafer, T., Lindqvist-Reis, P., Denecke, M. A., Plaschke, M., Rothe, J., and Kim, J. I. (2002) Low temperature XAFS investigation on the lutetium binding changes during the 2-line ferrihydrite alteration process. Environmental Science and Technology, 36, 5092-5099.
16. 2O. Koordinatsionnaia Khimiia, 11, 680-683.
17. Elderfield, H., Hawkesworth, C. J., Greaves, M. J., and Calvert, S. E. (1981) Rare earth element geochemistry of oceanic ferromanganese nodules and associated sediments. Geochimica et Cosmochimica Acta, 45, 513-528.
18. Elzinga, E. J., Reeder, R. J., Withers, S. H., Peale, R. E., Mason, R. A., Beck, K. M., and Hess, W. P. (2002) EXAFS study of rare-earth element coordination in calcite. Geochimica et Cosmochimica Acta, 66, 2875-2885.
19. 2O. Crystal Structure Communications, 5, 349-352.
20. 2O from X-ray powder diffraction. Journal of Solid State Chemistry, 126, 127-134.
21. 3. The Journal of Chemical Physics, 70, 2797-2806
22. 3. The Journal of Chemical Physics, 70, 3758-3763
23. 3, and series behavior. The Journal of Chemical Physics, 73, 442-450.
24. Jørgensen, C. K. (1979) Theoretical chemistry of rare earths. In K. A. Gschneidner Jr. and L. Eyring, Eds., Handbook on the Physics and Chemistry of Rare Earths, 3, p. 111-169. Elsevier, Amsterdam.
25. Junk, P. C., Kepert, D. L., Skelton, B. W., and White, A. H. (1999) Structural systematics of rare earth complexes. XIII (Maximally) hydrated (heavy) rare earth nitrates. Australian Journal of Chemistry, 52, 497-505.
26. Kanno, J. and Hiraishi, J. (1980) Raman spectroscopic evidence for a discrete change in coordination number of rare earth aquo-ions in the middle of the series. Chemical Physics Letters, 75, 553-556.
27. 3+ ionic-radii and refined spinpairing energy theory. Geochemical Journal, 26, 309-335.
28. 3+ ion series. Geochemical Journal, 33, 249-265.
29. Kawabe, I., Kitahara, Y., and Naito, K. (1991) Non-chondritic yttrium holmium ratio and lanthanide tetrad effect observed in pre-Cenozoic limestones. Geochemical Journal, 25, 31-44.
30. Kawabe, I., Ohta, A., Ishii, S., Tokumura, M., and Miyauchi, K. (1999) REE partitioning between Fe-Mn oxyhydroxide precipitates and weakly acid NaCl solutions: Convex tetrad effect and fractionation of Y and Sc from heavy lanthanides. Geochemical Journal, 33, 167-179.
31. 3+aq series-I: An important constraint on REE (III) partitioning and complex formation reactions in low-temperature to hydrothermal condition. The Journal of Earth and Planetary Sciences, Nagoya University, 53, 33-50.
32. 2 distances. The Journal of Earth and Planetary Sciences, Nagoya University, 53, 51-71.
33. 3+ in aqueous solution including water polarization. Change in coordination number from 9 to 8 along the series. Journal of the American Chemical Society, 117, 3790-3799.
34. -3 ionic strength. Marine Chemistry, 51, 213-221.
35. Manceau, A., Kersten, M., Marcus, M. A., Geoffroy, N., and Granina, L. (2007) Ba and Ni speciation in a nodule of binary Mn oxide phase composition from Lake Baikal. Geochimica et Cosmochimica Acta, 71, 1967-1981.
36. 3+ aquo ion and chloro complexes in aqueous solutions at up to 500 °C and 270 MPa. Journal of Physical Chemistry A., 106, 6591-6599.
37. 3) 3. Crystal Structure Communications, 11, 1241-1244.
38. Mioduski, T. and Siekierski, S. (1975) The application of the double-double effect to the determination of the lanthanide aquo-ion structures. Journal of Inorganic and Nuclear Chemistry, 37, 1647-1651.
39. Moret, E., Bunzli, J. C. G., and Schenk, K. J. (1990) Structural and luminescence study of europium and terbium nitrate hexahydrates. Inorganica Chimica Acta, 178, 83-88.
40. 3. Journal of Inorganic and Nuclear Chemistry, 42, 223-227.
41. 3. Journal of Inorganic and Nuclear Chemistry, 41, 525-532.
42. Nomura, M. (1998) Design and performance of a multi-element SSD for fluorescent XAFS. KEK Report, 98, 1-28.
43. Nomura, M. and Koyama, A. (1996) Design and performance of a new XAFS beamline at the Photon Factory: BL-12C. KEK Report, 95, 1-21.
44. 3: Determinations of rare earth element complexation constants with carbonate ions. Geochemical Journal, 34, 439-454.
45. 2) and Fe oxyhydroxide: Ce (III) oxidation by δ-MnO2. Geochimica et Cosmochimica Acta, 65, 695-703.
46. Ohta, A., Ishii, S., Sakakibara, M., Mizuno, A., and Kawabe, I. (1999) Systematic correlation of the Ce anomaly with the Co/(Ni + Cu) ratio and Y fractionation from Ho in distinct types of Pacific deep-sea nodules. Geochemical Journal, 33, 399-417.
47. Ohta, A., Kagi, H., Tsuno, H., Nomura, M. and Kawabe, I. (2008) Influence of multi-electron excitation on EXAFS spectroscopy of trivalent rare earth ions and elucidation of change in hydration number through the series. American Mineralogist, 93, 1384-1392.
48. Ohta, A., Kagi, H., Nomura, M., Tsuno, H., and Kawabe, I. (2009) Coordination study of rare earth elements on Fe oxyhydroxide and Mn dioxides. Part I: Influence of a multi-electron excitation on EXAFS analyses for La, Pr, Nd, and Sm samples. American Mineralogist, 94, 467-475.
49. Ohtaki, H. and Radnai, T. (1993) Structure and dynamics of hydrated ions. Chemical Reviews, 93, 1157-1204.
50. Ribár, B., Kapor, A., Argay, G., and Kálmán, A. (1986) Tetraaquatrinitratoeuropium (III) monohydrate. Acta Crystallographica Section C: Crystal Structure Communications, 42, 1450-1452.
51. Rizkalla, E. N. and Choppin, G. R. (1991) Hydration and hydrolysis of lanthanides. In K. A. Gschneidner Jr. and L. Eyring, Eds., Handbook on the Physics and Chemistry of Rare Earths, 15, p. 393-442. Elsevier Sciences Publishers, New York.
52. 2O. Acta Crystallographica Section C: Crystal Structure Communications, 39, 939-941.
53. 2O. Kristallographiia, 9, 642-654.
54. Shannon, R. D. and Prewitt, C. T. (1969) Effective ionic radii in oxides and fluorides. Acta Crystallographica, 25, 925-946.
55. Shinn, D. B. and Eick, H. A. (1968) Crystal structure of lanthanum carbonate octahydrate. Inorganic Chemistry, 7, 1340-1345.
56. Solera, J. A., García, J., and Proietti, M. G. (1995) Multielectron excitations at the L edges in rare-earth ionic aqueous solutions. Physical Review B., 51, 2678-2686.
57. 2O. Zeitschrift für Kristallographie-New Crystal Structures, 212, 315-315.
58. Stouff, P. and Boulègue, J. (1988) Synthetic 10 and 7 Å phyllomanganates: Their structures as determined by EXAFS. American Mineralogist, 73, 1162-1169.
59. Stumpf, S., Stumpf, T., Dardenne, K., Hennig, C., Foerstendorf, H., Klenze, R., and Fanghanel, T. (2006) Sorption of Am (III) onto 6-line- ferrihydrite and its alteration products: Investigations by EXAFS. Environmental Science and Technology, 40, 3522-3528.
60. Takahashi, Y., Manceau, A., Geoffroy, N., Marcus, M. A., and Usui, A. (2007) Chemical and structural control of the partitioning of Co, Ce, and Pb in marine ferromanganese oxides. Geochimica et Cosmochimica Acta, 71, 984-1008.
61. Tanaka, K., Miura, N., Asahara, Y., and Kawabe, I. (2003) Rare earth element and strontium isotopic study of seamount-type limestones in Mesozoic accretionary complex of Southern Chichibu Terrane, central Japan: Implication for incorporation process of seawater REE into limestones. Geochemical Journal, 37, 163-180.
62. Tanaka, K., Ohta, A., and Kawabe, I. (2004) Experimental REE partitioning between calcite and aqueous solution at 25 °C and 1 atm: Constraints on the incorporation of seawater REE into seamount-type limestones. Geochemical Journal, 38, 19-32.
63. Tanaka, K., Takahashi, Y., and Shimizu, H. (2008) Local structure of Y and Ho in calcite and its relevance to Y fractionation from Ho in partitioning between calcite and aqueous solution. Chemical Geology, 248, 104-113.
64. Tsuno, H., Kagi, H., Takahashi, Y., Akagi, T., and Nomura, M. (2003) Spontaneously induced reduction of trivalent ytterbium in synthesized crystal of calcite. Chemistry Letters, 32, 500-501.
65. Yamaguchi, T., Nomura, M., Wakita, H., and Ohtaki, H. (1988) An extended X-ray absorption fine structure study of aqueous rare earth perchlorate solutions in liquid and glassy states. The Journal of Chemical Physics, 89, 5153-5159.
66. Zhang, J., Amakawa, H., and Nozaki, Y. (1994) The comparative behaviors of yttrium and lanthanides in the seawater of the North Pacific. Geophysical Research Letters, 21, 2677-2680.