Systematic correlation of the Ce anomaly with the Co/(Ni+Cu) ratio and Y fractionation from Ho in distinct types of Pacific deep-sea nodules

Geochemical Journal

Volumn 33, Issue 6, 1999, Pages 399-417

  Ohta, Atsuyuki ^a,d   Ishii, Satoru ^b   Sakakibara, Masayuki ^c   Mizuno, Atsuyuki ^d   Kawabe, Iwao ^a  

^a NAGOYA UNIVERSITY   (Japan)

^b EHIME UNIVERSITY   (Japan)

^c MITSUBISHI MATERIALS CORPORATION   (Japan)

^d NONE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CERIUM; DEEP SEA; DIAGENESIS; FERROMANGANESE DEPOSIT; YTTRIUM;

PACIFIC OCEAN;

EID: 0033373045     PISSN: 00167002     EISSN: None     Source Type: Journal    
DOI: 10.2343/geochemj.33.399     Document Type: Article

References (58)

1. Anders, E. and Grevesse, N. (1989) Abundances of the elements: Meteoritic and Solar. Geochim. Cosmochim. Acta 53, 197-214.
2. Balistrieri, L. S. and Murray, J. W. (1984) Marine scavenging: Trace metal adsorption by interfacial sediment from MANOP Site H. Geochim. Cosmochim. Acta 48, 921-929.
3. Barrett, T. J. and Jarvis, I. (1988) Rare-earth element geochemistry of metalliferous sediments from DSDP Leg 92: The East Pacific Rise transect. Chem. Geol. 67, 243-259.
4. Barrett, T. J., Talor, P. N. and Lugowski, J. (1987) Metalliferous sediments from DSDP Leg 92: The East Pacific Rise transect. Geochim. Cosmochim. Acta 51, 2241-2253.
5. Bau, M., Dulski, P. and Möller, P. (1995) Yttrium and holmium in south Pacific seawater: Vertical distribution and possible fractionation mechanisms. Chem. Erde 55, 1-15.
6. Bau, M., Koschinsky, A., Dulski, P. and Hein, J. R. (1996) Comparison of the partitioning behaviors of yttrium, rare earth elements, and titanium between hydrogenetic marine ferromanganese crusts and seawater. Geochim. Cosmochim. Acta 60, 1709-1725.
7. Bender, M. L. and Heggie, D. T. (1984) Fate of organic carbon reaching the deep sea floor: a status report. Geochim. Cosmochim. Acta 48, 997-986.
8. Bonatti, E., Kraemer, T. and Rydell, H. (1972) Classification and genesis of submarine iron-manganese deposits. Ferromanganese Deposits on the Ocean Floor (Horn, D., ed.), 149 pp., IDOE Publ.
9. Bruland, K. W. (1980) Oceanographic distributions of cadmium, zinc, nickel, and copper in the North Pacific. Earth Planet. Sei. Lett. 47, 176-198.
10. Burns, R. G. (1976) The uptake of cobalt into ferromanganese nodules, solid, and synthetic manganese(IV) oxides. Geochim. Cosmochim. Acta 40, 95-102.
11. Calvert, S. E. and Piper, D. Z. (1984) Geochemistry of ferromanganese nodules from DOMES site A, northern equatorial Pacific: Multiple diagenetic metal sources in the deep sea. Geochim. Cosmochim. Acta 48, 1913-1928.
12. Calvert, S. E. and Price, N. B. (1977) Geochemical variation in ferromanganese nodules and associated sediments from the Pacific Ocean. Mar. Chem. S, 43-74.
13. Calvert, S. E., Piper, D. Z. and Baedecker, P. A. (1987) Geochemistry of the rare earth elements in ferromanganese nodules from DOMES Site A, northern equatorial Pacific. Geochim. Cosmochim. Acta 51,2331-2338.
14. Chester, R. (1990) Marine Geochemistry. Unwin Hyman, London, 698 pp.
15. De Baar, H. J. W., German, C. R., Elderfield, H. and van Gaans, P. (1988) Rare earth elements distributions in anoxic waters of Cariaco Trench. Geochim. Costnochim. Acta 52, 1203-1219.
16. Dillard, J. G., Crowther, D. and Murray, J. W. (1982) The oxidation states of cobalt and selected metals in Pacific ferromanganese nodules. Geochim. Cosmochim. Acta 46, 755-759.
17. Dymond, J., Lyle, M., Finney, B., Piper, D. Z., Murphy, K., Conard, R. and Pisias, N. (1984) Ferromanganese nodules from MANOP Sites H, S, and R-Control of mineralogical and chemical composition by multiple accretional process. Geochim. Cosmochim. Acta 48,931-949.
18. Elderfield, H. and Greaves, M. J. (1981) Negative cerium anomalies in the rare earth element patterns of oceanic ferromanganese nodules. Earth Planet. Sei. Lett. 55, 163-170.
19. Elderfield, H. and Greaves, M. J. ( 1982) The rare earth elements in seawater. Nature 296, 214-219.
20. Elderfield, E., Hasvkensworth, C. J., Greaves, M. J. and Calvert, S. E. (1981) Rare earth element geochemistry of oceanic ferromanganese nodules and associated sediments. Geochim. Cosmochim. Acta 45, 513-528.
21. Elderfield, H., Upstill-Goddard, R. and Sholkovitz, E. R. (1990) The rare earth elements in rivers, estuaries and coastal sea waters: processes affecting crustal input of elements to the ocean and their significance to the composition of sea water. Geochim. Cosmochim. Acta 54, 971-991.
22. Fischer, K., Dymond, J. and Lyle, M. (1986) The benthic cycle of copper: Evidence from sediment trap experiments in the eastern tropical North Pacific Ocean. Geochim. Cosmochim. Acta 50, 1535-1543.
23. German, C. R. and Elderfield, H. (1990) Rare earth elements in the NW Indian Ocean. Geochim. Cosmochim. Acta 54, 1929-1940.
24. Glasby G. P. and Thijssen, T. (1982) Control of the mineralogy and composition of marine manganese nodules by the supply of divalent transition metal ions. Neues. Jahrb. Mineral. Abh. 145. 291-307.
25. Glasby, G. P., Gvvozdz, R., Kunzendorf, H., Friedrich, G. and Thijssen, T. (1987) The distribution of rare earth and minor elements in manganese nodules and sediments from the equatorial and S.W. Pacific. Lithos 20, 97-113.
26. Goldstein, S. J. and Jacobsen, S. B. (1988) Rare earth elements in river waters. Earth Planet. Sei. Lett. 89, 35-47.
27. Gromet, L. P., Dymek, R. F., Haskin, L. A. and Korotev, R. L. ( 1984) The "North American shale composite": Its composition, major and trace element characteristics. Geochim. Cosmochim. Acta 48, 2469-2482.
28. Guo, S. and Sun, W. (1992) Rare earth elements in manganese nodules from the Central Pacific Ocean. Acta Ceol. Sinica 66, 135-146.
29. Halbach, P. (1986) Processes controlling the heavy metal distribution in Pacific ferromanganese nodules and crusts. Ceol. Rundschau 75, 235-247.
30. Halbach, P., Scherhag, C., Hebisch, U. and Marchig, V. (1981) Geochemical and mineralogical control of different genetic types of deep-sea nodules from the Pacific Ocean. Mineral. Deposita 16, 59-84.
31. Halbach, P., Giovanoli, R. and Borstel, D. V. (1982) Geochemical processes controlling the relationship between Co, Mn, and Fe in early diagenetic deepsea nodules. Earth Planet. Sei. Lett. 60, 226-236.
32. Haskin, L. A., Frey, F. A., Schmitt, R. A. and Smith, R. H. (1966) Meteoritic, solar, and terrestrial rare-earth distributions. Phys. Chein.7, 167-321.
33. Kalhorn, S. and Emerson, S. (1984) The oxidation state of manganese in surface sediments of the deep sea. Geochim. Cosmochim. Acta 48, 890-902.
34. Kavvabe, I. (1995) Tetrad effect and fine structures of REE abundance patterns of granitic and rhyolitic rocks: ICP-AES determinations of REE and Y in eight GSJ reference rocks. Geochem. J. 29, 213-230.
35. Kawabe, I., Kitahara, Y. and Naito, K. (1991) Nonchondritic yttrium/holmium ratio and lanthanide tetrad effect observed in pre-Cenozoic limestones. Geochem. J. 25, 31-44.
36. Kawabe, I., Toriumi, T., Ohta, A. and Miura, N. (1998) Monoisotopic REE abundances in seawater and the origin of seawater tetrad effect. Geochem. J. 32,213-229.
37. Kawabe, I., Ohta, A., Ishii, S., Tokumura, M. and Miyauchi, K. (1999) REE partitioning between FeMn oxyhydroxide precipitates and weakly acid NaCl solutions: Convex tetrad effect and fractionation of Y and Sc from heavy lanthanides. Geochem. J. 33, 167-179.
38. Knauer, G. A., Martin, J. H. and Gordon, R. M. (1982) Cobalt in north-east Pacific waters. Nature 297, 49-51.
39. Li, Y. H. (1991) Distribution patterns of the elements in the ocean: A synthesis. Geochim. Cosmochim. Acta 55, 3223-3240.
40. 3. Deep-Sea Res. 30,411-425.
41. Martin, J. M., HOgdahl, O. and Philippot, J. C. (1976) Rare earth element supply to the ocean. J. Geophys. Res. 81,3119-3124.
42. Möller, P., Dulski, P. and Bau, M. (1994) Rare-earth element adsorption in a seawater profile above the East Pacific Rise. Chem. Erde 54, 129-149.
43. Murphy, K. and Dymond, J. (1984) Rare earth element fluxes and geochemical budget in the eastern equatorial Pacific. Nature 307, 444-447.
44. Murray, J. W. and Dillard, J. G. (1979) The oxidation of cobalt(II) adsorbed on manganese dioxide. Ceochim. Cosmocliini. Acta 57, 4141-4163.
45. Nakao, S., Onodera, K., Tamaki, K., Joshima, M., Usui, A., Nishimura, A. and Tsurusaki, K. (1984) Outline of the GH80-5 cruise. Geol. Sun: Jpn. Cruise Rept. No. 20, 1-19.
46. Nohara, M., Usui, A., Nishimura, A., Tanahashi, M., Yamazaki, T., Ikehara, K. and Watanabe, K. (1992) Outline of the GH82-4 cruise. Geol. Surv. Jpn. Cruise Rept. No. 22, 1-17.
47. Palmer, M. R. (1985) Rare earth elements in foraminifera tests. Earth Planet. Sei. Lett. 73, 285-298.
48. Piepgras, D. J. and Jacobsen, S. B. (1992) The behavior of rare earth elements in seawater: precise determinations of variations in the North Pacific water column. Geochim. Cosmochim. Acta 56, 1851-1862.
49. Piper, D. Z. (1974) Rare earth elements in ferromanganese nodules and other marine phases. Geochim. Cosmochim. Acta 38, 1007-1022.
50. Piper, D. Z. and Williamson, M. E. (1981) Mineralogy and composition of concentric layers within a manganese nodule from the north Pacific ocean. Marine Geol. 40, 255-268.
51. Sholkovitz, E. R., Landing, W. M. and Lewis, B. L. (1994) Ocean particle chemistry: The fractionation of rare earth elements between suspended particulates and seawater. Geochim. Cosmochim. Acta 58, 1567-1579.
52. Takematsu, N., Sato, Y. and Okabe, S. (1984) The formation of todorokite and birnessite in sea water pumped from underground. Geochim. Cosmochim. Acta 48, 1099-1106.
53. Taylor, S. R. and McLennan, S. M. (1988) The significance of the rare earths in geochemistry and cosmochemistry. Handbook on the Physics and Chemistry of Rare Earths (Gschneidner, K. A., Jr. and Eyring, L., eds.), Vol. 11, 485-578, Elsevier, Amsterdam.
54. Tsunogai, S., Uematsu, M., Noriki, S., Tanaka, N. and Yamada, M. (1982) Sediment trap experiment in the northern North Pacific: Undulation of settling particles. Geochem. J. 16, 129-147.
55. Usui, A. (1983/84) Regional variation of manganese nodule faces on the Wake-Tahiti transect: Morphological, chemical and mineralogical study. Marine Geol. 54, 27-51.
56. Usui, A., Mizuno, A., Moritani, T. and Nakano, S. (1987) Manganese nodules in the northern and central parts of the Central Pacific Basin - Results of "Basic Study on Exploration of Deep Sea Mineral Resources". Bull. Geol. Sun: Jpn. 38, 539-585.
57. Usui, A., Nohara, M., Okuda, Y., Nishimura, A., Yamazaki, T., Saito, Y., Miyazaki, J., Turusaki, K., Yamazaki, T., Harada, K., Lee, C. W. and Fleming, P. (1994) Outline of the cruise GH83-3 in the Penrhyn basin, south Pacific. Geol. Surv. Jpn. Cruise Kept. No. 23, 1-17.
58. Zhang, J., Amakawa, H. and Nozaki, Y. (I994) The comparative behaviors of yttrium and lanthanides in seawater of the North Pacific. Geophys. Res. Lett. 21, 2677-2680.