REE partitioning between Fe-Mn oxyhydroxide precipitates and weakly acid NaCl solutions: Convex tetrad effect and fractionation of Y and Sc from heavy lanthanides

Geochemical Journal

Volumn 33, Issue 3, 1999, Pages 167-179

  Kawabe, Iwao ^a   Ohta, Atsuyuki ^a   Ishii, Satoru ^b   Tokumura, Maki ^b   Miyauchi, Kazue ^b  

^a NAGOYA UNIVERSITY   (Japan)

^b EHIME UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTION; PARTITIONING; RARE EARTH ELEMENT; SODIUM CHLORIDE;

EID: 0032766613     PISSN: 00167002     EISSN: None     Source Type: Journal    
DOI: 10.2343/geochemj.33.167     Document Type: Article

References (33)

1. Alibert, C. and McCulloch, M. T. (1993) Rare earth element and neodymium isotopic compositions of the banded iron-formations and associated shales from Hamersley, western Australia. Geochim. Cosmochim. Acta 57, 187-204.
2. Bau, M., Koschinsky, A., Dulski, P. and Hein, J. P. (1996) Comparison of the partitioning behaviors of yttrium, rare earth elements, and titanium between hydrogenetic marine ferromanganese crust and seawater. Geochim. Cosmochim. Acta 60, 1709-1725.
3. Byrne, R. H. and Sholkovitz, E. R. (1996) Marine chemistry and geochemistry of the lanthanides. Handbook on the Physics and Chemistry of Rare Earths, Vol. 23 (Gschneider, K. A. and Eyring, L., eds.), 497-593, Elsevier Science B. V.
4. Byrne, R. H., Kump, L. R. and Cantrell, K. J. (1988) The influence of temperature and pH on trace metal speciation in seawater. Mar. Chem. 25, 163-181.
5. 2O (Ln = terres rares). C. R. Acad. Sc. Paris, Ser. C 269, 687-690.
6. Choppin, G. R. (1989) Soluble rare earth and actinide species in seawater. Mar. Chem. 28, 19-26.
7. Derry, L. A. and Jacobsen, S. B. (1990) The chemical evolution of Precambrian seawater: Evidence from REEs in banded iron formations. Geochim. Cosmochim. Acta 54, 2965-2977.
8. Elderfield, H., Hawkensworth, C. J., Greaves, M. J. and Calvert, S. E. (1981a) Rare earth element geochemistry of oceanic ferromanganese nodules and associated sediments. Geochim. Cosmochim. Acta 45, 513-528.
9. Elderfield, H., Hawkensworth, C. J., Greaves, M. J. and Calvert, S. E. (1981b) Rare earth element zonation in Pacific ferromanganese nodules. Geochim. Cosmochim. Acta 45, 1231-1234.
10. Elderfield, H., Updtill-Goddard, R., Sholkovitz, E. R. (1990) The rare earth elements in river, estuaries, and coastal seas and their significance to the composition of ocean waters. Geochim. Cosmochim. Acta 54, 971-991.
11. Fryer, B. J. (1977) Rare earth evidence in iron-formations for changing Precambrian oxidation states. Geochim. Cosmochim. Acta 41, 361-367.
12. Glasby, G. P., Gwondz, R., Kunzendorf, H., Friedrich, G. and Thijssen, T. (1987) Distribution of rare earth and minor elements in manganese nodules and sediments from the equatorial and SW Pacific. Lithos 20, 97-113.
13. Goldberg, E. D., Koide, M., Schmitt, R. A. and Smith, R. H. (1963) Rare earth distribution in the marine environment. J. Geophys. Res. 68, 4009-4217.
14. Goldstein, S. J. and Jacobsen, S. B. (1988) Rare earth elements in river waters. Earth Planet. Sci. Lett. 89, 35-47.
15. Hem, J. D. (1981) Rates of manganese oxidation in aqueous systems. Geochim. Cosmochim. Acta 45, 1369-1374.
16. Högfeldt, E. (1982) Stability Constants of Metal-Ion Complexes, Part A: Inorganic Ligands. IUPAC Chemical Data Series, No. 21, Pergamon, Oxford, 310 pp.
17. Jørgensen, C. K. (1979) Theoretical chemistry of rare earths. Handbook on the Physics and Chemistry of Rare Earths, Vol. 3 (Gschneider, K. A., Jr. and Eyring, L., eds.), 111-169, North-Holland, Amsterdam.
18. 3+ ionic radii and refined spin-pairing energy theory. Geochem. J. 26, 309-335.
19. Kawabe, I. (1995) Tetrad effects and fine structures of REE abundance patterns of granitic and rhyolitic rocks: ICP-AES determinations of REE and Y in eight GSJ reference rocks. Geochem. J. 29, 213-230.
20. 3+ ion series. Submitted to Geochem. J.
21. Kawabe, I. (1998b) Hydration change of aqueous lanthanide ions and tetrad effects in lanthanide(III)-carbonate complexation. Submitted to Geochem. J.
22. Kawabe, I., Y. Kitahara and K. Naito (1991) Nonchondritic yttrium/holmium ratio and lanthanide tetrad effect observed in pre-Cenozoic limestones. Geochem. J. 25, 31-44.
23. Kawabe, I., T. Inoue and S. Kitamura (1994) Comparison of REE analyses of GSJ carbonate reference rocks by ICP-AES and INAA: Fission and spectral interferences in INAA determination of REE in geochemical samples with high U/REE ratios. Geochem. J. 28, 19-29.
24. Kawabe, I., Ohta, A. and Miura, N. (1999) Distribution coefficients of REE between Fe oxyhydroxie precipitates and NaCl solutions affected by REE-carbonate complexation. Geochem. J. (in press).
25. McLennan, S. M. (1994) Rare earth element geochemistry and the "tetrad" effect. Geochim. Cosmochim. Acta 58, 2025-2033.
26. 3+ in carbonate solutions. J. Alloys. Compounds 194, 93-99.
27. Millero, F. J. (1992) Stability constants for formation of rare earth inorganic complexes as a function of ionic strength. Geochim. Cosmochim. Acta 56, 3123-3132.
28. Moeller, T., Martin, D. F., Thompson, L. C., Ferrus, R., Feisstel, G. R. and Randall, W. J. (1965) The coordination chemistry of yttrium and the rare earth metal ions. Chem. Rev. 65, 1-50.
29. 3. J. Inorg. Nucl. Chem. 42, 223-227.
30. Shimizu, H., Umemoto, N., Masuda, A. and Appel, P. W. U. (1990) Sources of iron-formations in the Archean Isua and Malene supracrustals, West Greenland: Evidence from La-Ce and Sm-Nd isotopic data and REE abundances. Geochim. Cosmochim. Acta 54, 1147-1154.
31. Travers, J. G., Dellien, I. and Hepler, L. G. (1976) Scandium: Thermochemical properties, chemical equilibria, and standard potentials. Thermochim. Acta 15, 89-104.
32. Wood, S. A. (1990) The aqueous geochemistry of the rare-earth elements and yttrium. 1. Review of available low T data for inorganic REE speciation of natural water. Chem. Geol. 82, 159-186.
33. Zhang, J., Amakawa, H. and Nozaki, Y. (1994) The comparative behaviors of yttrium and lanthanides in seawater of the North Pacific. Geophys. Res. Lett. 21, 2677-2680.